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    • 3. 发明申请
    • METHOD OF MANUFACTURING ACTIVE MATERIAL
    • 制造活性材料的方法
    • US20110052473A1
    • 2011-03-03
    • US12854572
    • 2010-08-11
    • Atsushi SANOKeitaro OTSUKIYosuke MIYAKITakeshi TAKAHASHIAkiji HIGUCHI
    • Atsushi SANOKeitaro OTSUKIYosuke MIYAKITakeshi TAKAHASHIAkiji HIGUCHI
    • C01B25/30
    • C01B25/45H01M4/5825
    • Methods of manufacturing an active material capable of improving the discharge capacity of a lithium-ion secondary battery are provided. The first method of manufacturing an active material comprises a hydrothermal synthesis step of heating a mixture containing a lithium source, a phosphate source, a vanadium source, water, and a reducing agent to 100 to 195° C. under pressure; and a heat treatment step of heating the mixture to 500 to 700° C. after the hydrothermal synthesis step. The hydrothermal synthesis step adjusts the ratio [P]/[V] of the number of moles of phosphorus [P] contained in the mixture before heating to the number of moles of vanadium [V] contained in the mixture before heating to 0.9 to 1.2. The second method of manufacturing an active material comprises a hydrothermal synthesis step of heating a mixture containing a lithium source, a phosphate source, a vanadium source, water, and a reducing agent to 200 to 300° C. under pressure and adjusts the ratio [P]/[V] of the number of moles of phosphorus [P] contained in the mixture before heating to the number of moles of vanadium [V] contained in the mixture before heating to 0.9 to 1.5.
    • 提供了能够提高锂离子二次电池的放电容量的活性物质的制造方法。 制造活性物质的第一种方法包括在压力下将含有锂源,磷酸盐源,钒源,水和还原剂的混合物加热至100至195℃的水热合成步骤; 以及在水热合成步骤之后将混合物加热至500-700℃的热处理步骤。 水热合成步骤调节加热前混合物中所含的磷[P]的摩尔数[P] / [V]至加热前混合物中所含的钒[V]的摩尔数为0.9至1.2 。 制造活性物质的第二种方法包括在压力下将含有锂源,磷酸盐源,钒源,水和还原剂的混合物加热至200-300℃的水热合成步骤, 加热前的混合物中含有的磷[P]的摩尔数P / / V [V]为加热前的混合物中所含的钒[V]的摩尔数为0.9〜1.5。