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    • 1. 发明申请
    • POLYPROPYLENE RESIN COMPOSITION AND PROCESS FOR PRODUCING THE SAME
    • 聚丙烯树脂组合物及其制造方法
    • US20110060075A1
    • 2011-03-10
    • US12873468
    • 2010-09-01
    • Yoshiaki OOBAYASHI
    • Yoshiaki OOBAYASHI
    • C08J3/22C08K5/098
    • C08L23/10C08K5/098C08L23/04C08L2666/06
    • A polypropylene resin composition comprising (a) 100 parts by weight of a resin composition, which contains 51 to 99% by weight of a propylene polymer and 1 to 49% by weight of an ethylene polymer having a density of 0.85 to 0.93 g/cm3, and (b) 0.001 to 0.5 part by weight of a metal salt defined by a specific chemical formula; and a process for producing such a polypropylene resin composition, comprising the steps of (1) mixing 1 to 100 parts by weight of the metal salt with 100 parts by weight of the propylene polymer and/or the ethylene polymer, thereby producing a master batch, and (2) mixing the master batch with a mixture containing the propylene polymer and the ethylene polymer.
    • 一种聚丙烯树脂组合物,其包含(a)100重量份的树脂组合物,其含有51至99重量%的丙烯聚合物和1至49重量%的密度为0.85至0.93g / cm 3的乙烯聚合物 ,和(b)0.001〜0.5重量份由特定化学式定义的金属盐; 以及制造这种聚丙烯树脂组合物的方法,包括以下步骤:(1)将1至100重量份的金属盐与100重量份的丙烯聚合物和/或乙烯聚合物混合,由此制备母料 ,和(2)将母料与含有丙烯聚合物和乙烯聚合物的混合物混合。
    • 2. 发明授权
    • Propylene/ethylene-&agr;-olefin block copolymer and process for producing the same
    • 丙烯/乙烯-α-烯烃嵌段共聚物及其制备方法
    • US06613845B1
    • 2003-09-02
    • US09337502
    • 1999-06-22
    • Naofumi NagaYoshiaki OobayashiMasatada TasakaKouji Mizunuma
    • Naofumi NagaYoshiaki OobayashiMasatada TasakaKouji Mizunuma
    • C08F29300
    • C08F297/08
    • A propylene/ethylene-&agr;-olefin block copolymer obtained by block-copolymerizing a polypropylene component with an ethylene-&agr;-olefin random copolymer component, which satisfies conditions of the following terms (I) to (III): (I) the content of the polypropylene component having an intrinsic viscosity ([&eegr;]) measured in tetralin at 135° C. of from 0.5 to 5.0 dl/g is from 5 to 95% by weight; (II) the content of the &agr;-olefin in the random copolymer component is from 5 to 40 mol %, and the content of the ethylene-&agr;-olefin random copolymer component whose &rgr; value represented by the following equation: &rgr;=2[E]·[A]/[EA] (wherein [E] represents a molar fraction of ethylene, [A] represents a molar fraction of the &agr;-olefin and [EA] represents a molar fraction of a diad chain of ethylene and the &agr;-olefin) is within the range from 0.5 to 1.5 is from 5 to 95% by weight; and (III) the intrinsic viscosity ([&eegr;]) of the propylene/ethylene-&agr;-olefin block copolymer measured in tetralin at 135° C. is from 0.5 to 5.0 dl/g, and a process for producing the above propylene/ethylene-&agr;-olefin block copolymer.
    • 通过将聚丙烯组分与乙烯-α-烯烃无规共聚物组分嵌段共聚获得的丙烯/乙烯-α-烯烃嵌段共聚物,其满足下列条件(I)至(III):( I)的条件: 在135℃下在四氢化萘中测得的特性粘度(η)为0.5-5.0dl / g的聚丙烯组分为5-95重量%;(II)随机的α-烯烃含量 共聚物成分为5〜40摩尔%,rho值由下式表示的乙烯-α-烯烃无规共聚物成分的含量:[其中[E]表示乙烯的摩尔分数,[A]表示摩尔 α-烯烃的分数和[EA]表示乙烯和α-烯烃的二价链的摩尔分数在0.5至1.5的范围内为5至95重量%; 和(III)在135℃下在四氢化萘中测得的丙烯/乙烯-α-烯烃嵌段共聚物的特性粘度(η)为0.5-5.0dl / g,制备上述丙烯/乙烯 α-烯烃嵌段共聚物。
    • 3. 发明申请
    • POLYPROPYLENE RESIN COMPOSITION AND MOLDED ARTICLE
    • 聚丙烯树脂组合物和成型品
    • US20100292371A1
    • 2010-11-18
    • US12808534
    • 2008-12-19
    • Takeshi MaruyamaTsuyoshi WatanabeYoshiaki Oobayashi
    • Takeshi MaruyamaTsuyoshi WatanabeYoshiaki Oobayashi
    • C08K5/3435
    • C08L23/10C08K5/34C08L23/0815C08L23/12C08L23/16C08L53/00C08L2666/02C08L2666/06
    • Provided are a polypropylene resin composition which produces only a little mold staining at the time of molding, which is excellent in the stability against light and the molding processability, which has good balance between high rigidity and impact resistance, and which can give a molded article excellent in flow mark appearance and weld appearance when being processed into a molded article, and a molded article produced therefrom. The polypropylene resin composition of the present invention contains 99 to 60 parts by weight of propylene-based polymer (A), 1 to 40 parts by weight of inorganic filler (B) having an average particle diameter of 0.01 to 100 μm, and 0.05 to 5 parts by weight, per 100 parts by weight of the resin composition (I), of an hindered amine-type light stabilizer (C) which satisfies the specified requirements (a), (b) and (c), provided that the combined amount of the propylene-based polymer (A) and the inorganic filler (B) is 100 parts by weight.
    • 本发明提供一种聚丙烯树脂组合物,其在成型时仅产生少许模具污染,其耐光稳定性和成型加工性优异,其在高刚性和耐冲击性之间具有良好的平衡,并且可以得到模制品 加工成成形品时的流痕外观和焊接外观优异,以及由其制造的成型体。 本发明的聚丙烯树脂组合物含有99〜60重量份的丙烯系聚合物(A),1〜40重量份的平均粒径为0.01〜100μm的无机填料(B),0.05〜 5重量份,相对于树脂组合物(I)100重量份,满足规定的要求(a),(b)和(c)的受阻胺型稳定剂(C) 丙烯类聚合物(A)和无机填料(B)的含量为100重量份。
    • 6. 发明授权
    • Polypropylene-based resin composition and molding made from the same
    • 聚丙烯基树脂组合物和由其制成的模制品
    • US07923502B2
    • 2011-04-12
    • US12219224
    • 2008-07-17
    • Yoshiaki Oobayashi
    • Yoshiaki Oobayashi
    • C08K3/34
    • C08K3/34C08K5/005C08L53/00
    • An object of the present invention is to provide a polypropylene-based resin composition which is excellent in mechanical characteristics and molding processability, and is also capable of suppressing emission of a volatile organic compound.Disclosed is a polypropylene-based resin composition comprising a propylene-based block copolymer (A) which satisfies features (a), (b) and (c) shown below, and a zeolite (B) having a molar ratio SiO2/Al2O3 of 10 to 60 in an amount of 0.01 to 0.4 part by weight based on 100 parts by weight of the propylene-based block copolymer (A):Feature (a): the propylene-based block copolymer (A) is a propylene-based block copolymer containing a polymer component (I) and a polymer component (II);Feature (b): the polymer component (II) has a content of the units derived from at least one kind of comonomer selected from the group consisting of ethylene and α-olefins having 4 to 12 carbon atoms of from 1 to 80% by weight; andFeature (c): the propylene-based block copolymer (A) has a content of the polymer component (II) of from 5 to 70% by weight.
    • 本发明的目的是提供一种机械特性和成型加工性优异的聚丙烯系树脂组合物,能够抑制挥发性有机化合物的排出。 公开了一种聚丙烯系树脂组合物,其含有满足下述特征(a),(b)和(c)的丙烯类嵌段共聚物(A)和SiO 2 / Al 2 O 3摩尔比为10的沸石(B) 相对于丙烯系嵌段共聚物(A)100重量份,为0.01〜0.4重量份。特征(a):丙烯系嵌段共聚物(A)为丙烯系嵌段共聚物 含有聚合物组分(I)和聚合物组分(II); 特征(b):聚合物组分(II)具有衍生自至少一种选自乙烯和碳原子数为4至12的α-烯烃中的至少一种共聚单体的含量为1至80重量% ; 特征(c):丙烯系嵌段共聚物(A)的聚合物成分(II)的含量为5〜70重量%。
    • 8. 发明授权
    • Propylene/ethylene-.alpha.-olefin block copolymer and process for
processing the same
    • 丙烯/乙烯-α-烯烃嵌段共聚物及其加工方法
    • US5990242A
    • 1999-11-23
    • US863395
    • 1997-05-27
    • Naofumi NagaYoshiaki OobayashiMasatada TasakaKouji Mizunuma
    • Naofumi NagaYoshiaki OobayashiMasatada TasakaKouji Mizunuma
    • C08F297/08C08F297/00
    • C08F297/08
    • A propylene/ethylene-.alpha.-olefin block copolymer obtained by block-copolymerizing a polypropylene component with an ethylene-.alpha.-olefin random copolymer component, which satisfies conditions of the following terms (I) to (III):(I) the content of the polypropylene component having an intrinsic viscosity ([.eta.]) measured in tetralin at 135.degree. C. of from 0.5 to 5.0 dl/g is from 5 to 95% by weight;(II) the content of the .alpha.-olefin in the random copolymer component is from 5 to 40 mol %, and the content of the ethylene-.alpha.-olefin random copolymer component whose .rho. value represented by the following equation:.rho.=2[E].multidot.[A]/[EA](wherein [E] represents a molar fraction of ethylene, [A] represents a molar fraction of the .alpha.-olefin and [EA] represents a molar fraction of a diad chain of ethylene and the .alpha.-olefin) is within the range from 0.5 to 1.5 is from 5 to 95% by weight; and(III) the intrinsic viscosity ([.eta.]) of the propylene/ethylene-.alpha.-olefin block copolymer measured in tetralin at 135.degree. C. is from 0.5 to 5.0 dl/g, and a process for producing the above propylene/ethylene-.alpha.-olefin block copolymer.
    • 通过将聚丙烯组分与乙烯-α-烯烃无规共聚物组分嵌段共聚获得的丙烯/乙烯-α-烯烃嵌段共聚物,其满足以下(I)至(III)的条件:(I) 在135℃下在四氢化萘中测得的特性粘度(η)为0.5-5.0dl / g的聚丙烯组分为5-95重量% (II)中,无规共聚物成分中的α-烯烃的含量为5〜40摩尔%,rho值由下式表示的乙烯-α-烯烃无规共聚物成分的含量:rho = 2 [E ] x [A] / [EA](其中[E]表示乙烯的摩尔分数,[A]表示α-烯烃的摩尔分数,[EA]表示乙烯的二元链的摩尔分数, α-烯烃)在0.5〜1.5的范围内为5〜95重量% 和(III)在135℃下在四氢化萘中测得的丙烯/乙烯-α-烯烃嵌段共聚物的特性粘度(η)为0.5-5.0dl / g,以及制备上述丙烯/乙烯 α-烯烃嵌段共聚物。
    • 10. 发明授权
    • Polypropylene resin composition and process for producing the same
    • 聚丙烯树脂组合物及其制备方法
    • US08431634B2
    • 2013-04-30
    • US12873468
    • 2010-09-01
    • Yoshiaki Oobayashi
    • Yoshiaki Oobayashi
    • C08J3/22
    • C08L23/10C08K5/098C08L23/04C08L2666/06
    • A polypropylene resin composition comprising (a) 100 parts by weight of a resin composition, which contains 51 to 99% by weight of a propylene polymer and 1 to 49% by weight of an ethylene polymer having a density of 0.85 to 0.93 g/cm3, and (b) 0.001 to 0.5 part by weight of a metal salt defined by a specific chemical formula; and a process for producing such a polypropylene resin composition, comprising the steps of (1) mixing 1 to 100 parts by weight of the metal salt with 100 parts by weight of the propylene polymer and/or the ethylene polymer, thereby producing a master batch, and (2) mixing the master batch with a mixture containing the propylene polymer and the ethylene polymer.
    • 一种聚丙烯树脂组合物,其包含(a)100重量份的树脂组合物,其含有51至99重量%的丙烯聚合物和1至49重量%的密度为0.85至0.93g / cm 3的乙烯聚合物 ,和(b)0.001〜0.5重量份由特定化学式定义的金属盐; 以及制造这种聚丙烯树脂组合物的方法,包括以下步骤:(1)将1至100重量份的金属盐与100重量份的丙烯聚合物和/或乙烯聚合物混合,由此制备母料 ,和(2)将母料与含有丙烯聚合物和乙烯聚合物的混合物混合。