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    • 3. 发明授权
    • Nitride barrier layer to prevent metal (Cu) leakage issue in a dual damascene structure
    • 氮化物阻挡层,以防止双重镶嵌结构中的金属(Cu)泄漏问题
    • US07176571B2
    • 2007-02-13
    • US10753637
    • 2004-01-08
    • Yi-Lung ChengYing-Lung Wang
    • Yi-Lung ChengYing-Lung Wang
    • H01L23/48H01L23/52H01L29/40
    • H01L21/76832H01L21/76807H01L21/76826
    • A method for forming a composite barrier layer that also functions as an etch stop in a damascene process is disclosed. A SiC layer is deposited on a substrate in a CVD process chamber followed by deposition of a silicon nitride layer to complete the composite barrier layer. The SiC layer exhibits excellent adhesion to a copper layer in the substrate and is formed by a method that avoids reactive Si+4 species and thereby prevents CuSiX formation. The silicon nitride layer thickness is sufficient to provide superior barrier capability to metal ions but is kept as thin as possible to minimize the dielectric constant of the composite barrier layer. The composite barrier layer provides excellent resistance to copper oxidation during oxygen ashing steps and enables a copper layer to be fabricated with a lower leakage current than when a conventional silicon nitride barrier layer is employed.
    • 公开了一种用于形成复合阻挡层的方法,该复合阻挡层也用作镶嵌工艺中的蚀刻停止。 将SiC层沉积在CVD处理室中的衬底上,随后沉积氮化硅层以完成复合势垒层。 SiC层对衬底中的铜层表现出优异的粘附性,并且通过避免反应性Si + 4+物质并由此防止CuSi X X形成的方法形成。 氮化硅层的厚度足以为金属离子提供优异的阻挡能力,但保持尽可能的薄,以使复合阻挡层的介电常数最小化。 复合阻挡层在氧化灰化步骤期间提供优异的铜氧化性能,并且与使用常规氮化硅阻挡层相比,能够以较低的漏电流制造铜层。