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1. 发明授权

US4954497A Acrylic acid morpholides and fungicidal compositions 失效
标题翻译：丙烯酸吗啉和杀真菌组合物
公开(公告)号：US4954497A
公开(公告)日：1990-09-04
申请号：US310926
申请日：1989-02-16
申请人： Toshiya Kamikado , Yasuyuki Kando , Kazuho Matsuura , Junji Yamada
发明人： Toshiya Kamikado , Yasuyuki Kando , Kazuho Matsuura , Junji Yamada
IPC分类号： A01N43/84 , C07D213/56 , C07D213/64 , C07D213/643 , C07D213/65 , C07D213/70 , C07D213/71 , C07D213/74 , C07D405/12 , C07D409/12 , C07D417/12
CPC分类号： C07D213/64 , C07D213/56 , C07D213/643 , C07D213/65 , C07D213/70 , C07D213/71 , C07D213/74 , C07D405/12 , C07D409/12 , C07D417/12
摘要： This invention relates to a compound of the formula: ##STR1## wherein R.sup.1 is hydrogen, a halogen or a lower alkyl group; R.sup.2 and R.sup.33 independently are a lower alkoxyl group; and Py is an optionally substituted pyridyl group or a salt thereof.The compound or a salt thereof exerts excellent fungicidal effects against plant disease and is used as fungicide for agricultural use.

2. 发明授权

US5696256A Process for preparing and using guanidine derivatives 失效
标题翻译：制备和使用胍衍生物的方法
公开(公告)号：US5696256A
公开(公告)日：1997-12-09
申请号：US439790
申请日：1995-05-12
申请人： Yasuyuki Kando , Hideki Uneme , Isao Minamida
发明人： Yasuyuki Kando , Hideki Uneme , Isao Minamida
IPC分类号： A01N51/00 , C07C255/58 , C07C335/40 , C07D205/10 , C07D207/40 , C07D207/404 , C07D207/44 , C07D207/448 , C07D209/48 , C07D211/88 , C07D213/61 , C07D213/69 , C07D241/12 , C07D277/28 , C07D277/32 , C07D277/34 , C07D211/44 , C07D205/04 , C07D207/12 , C07D223/10
CPC分类号： C07D207/404 , A01N51/00 , C07C255/58 , C07C335/40 , C07D205/10 , C07D207/448 , C07D209/48 , C07D211/88 , C07D213/61 , C07D213/69 , C07D241/12 , C07D277/32 , C07D277/34
摘要： ##STR1## wherein R is a substituted or unsubstituted hydrocarbon residue or acyl group; X is an electron withdrawing group; Y
1 and Y
2 , which are the same or different, are each independently oxygen or sulfur; and A is a substituted or unsubstituted, divalent hydrocarbon residue have potent reactivity, this being useful in preparing guanidine derivatives.
摘要翻译：其中R是取代或未取代的烃残基或酰基; X是吸电子基团; Y1和Y2相同或不同，各自独立地为氧或硫; 并且A是取代或未取代的二价烃残基具有有效的反应性，这可用于制备胍衍生物。

3. 发明授权

US06630592B1 Processes for production of oxadiazoline derivatives 失效
标题翻译：恶二唑啉衍生物的制备方法
公开(公告)号：US06630592B1
公开(公告)日：2003-10-07
申请号：US10148493
申请日：2002-05-29
申请人： Yasuyuki Kando , Toshiyuki Kiji
发明人： Yasuyuki Kando , Toshiyuki Kiji
IPC分类号： C07D41304
CPC分类号： C07D413/04 , C07D413/14
摘要： A process as represented by reaction scheme: which permits industrial mass production of &Dgr;2-1,2,4-oxadiazoline derivatives having excellent insecticidal effects or salts thereof in high yield with advantage, [wherein X1 is halogeno; R1 is optionally substituted alkyl, optionally substituted acyl, or ClCO; R2 is (1) halogeno, (2) C1-6 haloalkyl, (3) C1-6 haloalkoxy, or (4) phenyl optionally substituted with C1-6 haloalkyl; A is nitrogen or ═CR3— (wherein R3 is Cl or CN); R4 is C1-6 alkyl or C1-6 haloalkyl; n is 0, 1 or 2; and X2 is halogeno].
摘要翻译：以反应方案为代表的方法：其中X 1为卤素;其中X 1为卤素;其中X 1为卤素;其中X 1为卤素;其中X 1为卤素; R 1是任选取代的烷基，任选取代的酰基或ClCO; R 2是（1）卤代，（2）C 1-6卤代烷基，（3）C 1-6卤代烷氧基或（4）任选被C 1-6卤代烷基取代的苯基; A是氮或= CR 3 - （其中R 3是Cl或CN）; R 4是C 1-6烷基或C 1-6卤代烷基; n为0,1或2; X 2为卤代]。

4. 发明授权

US6160126A Synthetic Intermediates for the preparation of N, N'-Di-substituted isothiourea derivatives and N-cyclic(methyl)-N'-Substituted isothiourea derivatives 失效
标题翻译：用于制备N，N'-二取代异硫脲衍生物和N-环（甲基）-N'-取代的异硫脲衍生物的合成中间体
公开(公告)号：US6160126A
公开(公告)日：2000-12-12
申请号：US682247
申请日：1991-04-09
申请人： Yasuyuki Kando , Hideki Uneme , Isao Minamida
发明人： Yasuyuki Kando , Hideki Uneme , Isao Minamida
IPC分类号： A01N51/00 , C07C255/58 , C07C335/40 , C07D205/10 , C07D207/40 , C07D207/404 , C07D207/44 , C07D207/448 , C07D209/48 , C07D211/88 , C07D213/61 , C07D213/69 , C07D241/12 , C07D277/28 , C07D277/32 , C07D277/34 , C07D205/09 , C07D207/12 , C07D211/36
CPC分类号： C07D207/404 , A01N51/00 , C07C255/58 , C07C335/40 , C07D205/10 , C07D207/448 , C07D209/48 , C07D211/88 , C07D213/61 , C07D213/69 , C07D241/12 , C07D277/32 , C07D277/34
摘要： Novel Intermediates ##STR1## wherein R is a substituted or unsubstituted hydrocarbon residue or acyl group; X is an electron withdrawing group; Y.sup.1 and Y.sup.2, which are the same or different, are each independently oxygen or sulfur; and A is a substituted or unsubstituted, divalent hydrocarbon residue have potent reactivity, this being useful in preparing guanidine derivatives.
摘要翻译：新型中间体，其中R是取代或未取代的烃残基或酰基; X是吸电子基团; Y1和Y2相同或不同，各自独立地为氧或硫; 并且A是取代或未取代的二价烃残基具有有效的反应性，这可用于制备胍衍生物。

5. 发明授权

US06316477B1 Arylpyrazole insecticides 失效
标题翻译：吡唑类杀虫剂
公开(公告)号：US06316477B1
公开(公告)日：2001-11-13
申请号：US09117231
申请日：1998-07-24
申请人： Yasuyuki Kando , Toshiyuki Kiji , Atsuo Akayama , Makoto Noguchi
发明人： Yasuyuki Kando , Toshiyuki Kiji , Atsuo Akayama , Makoto Noguchi
IPC分类号： A61K314155
CPC分类号： C07D403/04 , A01N43/56 , A01N43/82 , A01N47/02 , A01N47/18 , A01N47/24 , A01N47/36 , C07D231/44 , C07D413/04
摘要： A compound of the formula: wherein Ar is an optionally substituted aromatic hydrocarbon or aromatic heterocyclic group, R is H, halogen or a group bonded through C, N, O, S or P, W is halogen or a group bonded through C, N, O, S or P, X is H or a group bonded through C, N, O or S, Y is H or a group bonded through C, N, O, S or P, or X and Y together with the adjacent nitrogen atom to Y may form an optionally substituted nitrogen-containing heterocyclic group which may further have N, O, S and/or P, or a salt thereof, a method of production thereof and agrochemicals containing the above compound [I]. The compound [I] and their salts are effective in preventing sanitary or horticultural insect pests and animal and plant parasites and can exert potent insecticidal activities when they are applied to harmed living animals or plants. Moreover, the compounds [I] and their salts possess safe and advantageous properties as agents for preventing sanitary, horticultural or agricultural injurious insects, such as no substantial damage on plants and less toxicity against fishes.
摘要翻译：下式的化合物：其中Ar是任选取代的芳族烃或芳族杂环基，R是H，卤素或通过C，N，O，S或P键合的基团，W是卤素或通过C，N ，O，S或P，X为H或通过C，N，O或S键合的基团，Y为H或通过C，N，O，S或P键合的基团，或X和Y与相邻氮原子与Y可以形成可以进一步具有N，O，S和/或P或其盐的任选取代的含氮杂环基，其制备方法和含有上述化合物[I]的农用化学品。化合物[I]及其盐可有效预防卫生或园艺害虫及动植物寄生虫，并可在施用于有害生物的动物或植物时施用有效的杀虫活性。此外，化合物[I]及其盐具有作为用于防止卫生，园艺或农业害虫的药剂的安全和有利的性质，例如对植物没有实质的损害和对鱼的毒性较小。

6. 发明授权

US06288088B1 Oxadiazoline derivative and their use as insecticides 失效
标题翻译：恶二唑啉衍生物及其作为杀虫剂的用途
公开(公告)号：US06288088B1
公开(公告)日：2001-09-11
申请号：US09701544
申请日：2000-11-30
申请人： Yasuyuki Kando , Makota Noguchi , Akayama Atsuo , Shinichi Masada , Toshiyuki Kiji
发明人： Yasuyuki Kando , Makota Noguchi , Akayama Atsuo , Shinichi Masada , Toshiyuki Kiji
IPC分类号： A61K314245
CPC分类号： C07D413/04 , A01N47/02 , A01N47/14 , A01N47/38 , C07D413/14
摘要： The present invention relates to a compound of the formula [I]: wherein R1 is C1-6 alkyl or C1-6 haloalkyl; n is 0, 1 or 2; X is (1) group of —NR2R3 wherein R2 and R3 independently represent (i) hydrogen or (ii) C1-6 alkyl which may optionally be substituted with pyridyl, (2) group of —N═CHOR4 wherein R4 represents C1-6 alkyl, (3) group of —N═CHNR6R7 wherein R6 and R7 independently represent (i) hydrogen or (ii) C1-6 alkyl, (4) group of —N═CHAr wherein Ar represents phenyl which may optionally be substituted with substituents selected from the group consisting of hydroxy and C1-3 alkoxy, or (5) pyrrolyl; R5 is optionally substituted alkyl or optionally substituted acyl; R8 is (1) halogen, (2) C1-6 haloalkyl, (3) C1-6 haloalkoxy or (4) phenyl which may optionally be substituted with C1-6 haloalkyl; A is (1) nitrogen atom or (2) group of wherein R9 is chlorine atom or cyano; and B is nitrogen atom or or a salt thereof. The compounds [I] or their salts have excellent insecticidal activities and less toxicity against fishes. Therefore, the agrochemical compositions containing the compound [I] or a salt thereof can protect crops, etc. from harmful pests so as to contribute to an agricultural success.
摘要翻译：本发明涉及式[I]的化合物：其中R 1是C 1-6烷基或C 1-6卤代烷基; n为0,1或2; X是（1）-NR2R3基团，其中R2和R3独立地表示（i）氢或（ii）可任选被吡啶基取代的C 1-6烷基，（2）-N = CHOR 4基团，其中R 4表示C 1-6 烷基，（3）-N = CHNR 6 R 7基团，其中R 6和R 7独立地表示（i）氢或（ii）C 1-6烷基，（4）-N = CHAr基团，其中Ar表示可以被取代基取代的苯基选自羟基和C 1-3烷氧基，或（5）吡咯基; R5是任选取代的烷基或任选取代的酰基; R 8是（1）卤素，（2）C 1-6卤代烷基，（3）C 1-6卤代烷氧基或（4）可任选地被C 1-6卤代烷基取代的苯基; A是（1）氮原子或（2）其中R9为氯原子或氰基; 并且B是氮原子或其盐。化合物[I]或其盐具有优良的杀虫活性和对鱼的毒性较小。因此，含有化合物[I]或其盐的农药组合物可以保护作物等不受有害害虫的影响，从而有助于农业的成功。

7. 发明授权

US5256679A Substituted guanidine derivatives, their preparation and use 失效
标题翻译：取代的胍衍生物，其制备和用途
公开(公告)号：US5256679A
公开(公告)日：1993-10-26
申请号：US745245
申请日：1991-08-14
申请人： Isao Minamida , Yasuyuki Kando , Hitoshi Ishizuka , Tetsuo Okauchi , Hideki Uneme
发明人： Isao Minamida , Yasuyuki Kando , Hitoshi Ishizuka , Tetsuo Okauchi , Hideki Uneme
IPC分类号： A01N51/00 , A01N43/40 , A01N43/78 , A01N43/84 , A01N47/44 , C07C255/58 , C07C277/08 , C07C279/34 , C07C335/40 , C07D205/10 , C07D207/40 , C07D207/404 , C07D207/44 , C07D207/448 , C07D209/48 , C07D211/88 , C07D213/16 , C07D213/36 , C07D213/61 , C07D213/69 , C07D213/75 , C07D241/12 , C07D277/12 , C07D277/20 , C07D277/28 , C07D277/32 , C07D277/34 , C07D277/38 , C07D277/48 , C07D417/12 , C07D213/26 , C07D277/30
CPC分类号： C07D207/404 , A01N51/00 , C07C255/58 , C07C335/40 , C07D205/10 , C07D207/448 , C07D209/48 , C07D211/88 , C07D213/61 , C07D213/69 , C07D241/12 , C07D277/32 , C07D277/34 , C07D417/12
摘要： Novel substituted nitroguanidine derivatives and salts thereof having the following formula: ##STR1## wherein R.sup.1 is a substituted or unsubstituted heterocyclic group; R.sup.2 is a group attached through a sulfur atom, a group attached through a phosphorus atom, cyano, --CO--OR.sup.6 wherein R.sup.6 is a substituted or unsubstituted hydrocarbon group or a substituted or unsubstituted heterocyclic group, or --CO--NR.sup.7 R.sup.8 wherein R.sup.7 and R.sup.8, which are the same or different, are each independently hydrogen, a substituted or unsubstituted hydrocarbon group or a substituted or unsubstituted heterocyclic group, or R.sup.7 and R.sup.8, taken together with the nitrogen atom to which they are attached are a cyclic amino group; R.sup.3 is hydrogen, a substituted or unsubstituted hydrocarbon group (except for one substituted with an oxo group at the binding site), a group attached through a sulfur atom, a group attached through a phosphorus atom, cyano, --CO--R.sup.9 wherein R.sup.9 is hydrogen, a substituted or unsubstituted hydrocarbon group or a substituted or unsubstituted heterocyclic group, --CO--OR.sup.10 wherein R.sup.10 is a substituted or unsubstituted hydrocarbon group or a substituted or unsubstituted heterocyclic group, or --CO--NR.sup.11 R.sup.12 wherein R.sup.11 and R.sup.12, which are the same or different, are each independently hydrogen, a substituted or unsubstituted hydrocarbon group or a substituted or unsubstituted heterocyclic group, or R.sup.11 and R.sup.12, taken together with the nitrogen atom to which they are attached are a cyclic amino group; and R.sup.4 is hydrogen or a lower alkyl group; which have unexpectedly potent pesticidal activity and very low toxicity.

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