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    • 3. 发明授权
    • Polyethylene composition and process for producing same
    • 聚乙烯组合物及其制备方法
    • US07678866B2
    • 2010-03-16
    • US10832342
    • 2004-04-27
    • Satoru YamadaMasayuki YamaguchiAkihiro YanoYasutake WakabayashiKei Inatomi
    • Satoru YamadaMasayuki YamaguchiAkihiro YanoYasutake WakabayashiKei Inatomi
    • C08L23/06C08L23/00C08F255/00
    • C08L23/06C08F290/042C08L23/08C08L2205/02C08L2314/06Y10S526/903C08L2666/06C08F210/02
    • A polyethylene composition prepared by polymerizing ethylene and an optional olefin with ≧3 carbon atoms in the presence of a macromonomer, is provided. The macromonomer is a vinyl-terminated ethylene polymer prepared by polymerizing ethylene and an optional olefin with ≧3 carbon atoms, and the macromonomer has (A) Mn≧5,000, and Mw/Mn=2-5. The polyethylene composition comprises (C) branched polyethylene prepared by copolymerizing ethylene, the macromonomer and an optional olefin with ≧3 carbon atoms, and the macromonomer. The polyethylene composition has (D) a density of 0.890-0.980 g/cm3, (E) Mw=30,000-10,000,000, (F) Mw/Mn=2-30, (G) a long chain branch frequency of 0.01-3 per 1,000 C atoms, and (H) a shrinking factor (g′ value) of 0.1-0.9 as measured by GPC/intrinsic-viscosity. The polyethylene composition can be finely divided particles having (P) a powder bulk density of 0.15-0.50 g/cm3.
    • 提供了通过在大分子单体的存在下聚合乙烯和具有≥3个碳原子的任选的烯烃制备的聚乙烯组合物。 大分子单体是通过聚合乙烯和具有≥3个碳原子的任选烯烃制备的乙烯基封端的乙烯聚合物,并且大分子单体具有(A)Mn≥5000,Mw / Mn = 2-5。 聚乙烯组合物包含(C)通过共聚乙烯,大分子单体和任选的具有≥3个碳原子的烯烃制备的支链聚乙烯和大分子单体。 聚乙烯组合物具有(D)密度为0.890-0.980g / cm 3,(E)Mw = 30,000-10,000,000,(F)Mw / Mn = 2-30,(G)长链支化频率为0.01-3 1000个C原子,(H)通过GPC /固有粘度测定的收缩因子(g'值)为0.1-0.9。 聚乙烯组合物可以是具有(P)粉末堆积密度为0.15-0.50g / cm 3的细碎颗粒。