专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明授权

US4552970A Solvated salts of dinitrophenylcyanamides, and a process for the preparation thereof 失效
标题翻译：二硝基苯基氰胺的溶剂化盐及其制备方法
公开(公告)号：US4552970A
公开(公告)日：1985-11-12
申请号：US576168
申请日：1984-02-01
申请人： Otto Arndt , Theodor Papenfuhs , Wolfgang Tronich
发明人： Otto Arndt , Theodor Papenfuhs , Wolfgang Tronich
IPC分类号： C07C261/04 , C07C261/00 , C07C273/06 , C07C275/30 , C07C125/08 , C07C127/19
CPC分类号： C07C275/30
摘要： Compounds of the formula I ##STR1## in which X denotes hydrogen, fluorine, chlorine or bromine, Y and Z denote hydrogen, lower alkyl or lower alkoxy, M denotes sodium, potassium or one equivalent of calcium and L denotes a dipolar aprotic solvent, are obtained from compounds of the formula II ##STR2## in which X, Y and Z have the abovementioned meanings, and a metal cyanamide of the formula IIIM.sub.2 N--CNin which M has the abovementioned meaning, in a dipolar aprotic solvent, which after the reaction is substantially removed, whereupon a lower molecular weight aliphatic alcohol is added to the residue and the product precipitated is isolated. Nitrophenylureas of the formula IV ##STR3## in which X, Y and Z have the abovementioned meanings, are obtained from the compounds of the formula I by acid hydrolysis.
摘要翻译：其中X表示氢，氟，氯或溴的式I“IMA”的化合物，Y和Z表示氢，低级烷基或低级烷氧基，M表示钠，钾或1当量的钙，L表示偶极非质子溶剂，由其中X，Y和Z具有上述含义的式II“IMAGE”的化合物和其中M具有上述含义的式IIIM2N-CN的金属氨基氰在偶极非质子传递溶剂中得到，后者为基本上除去反应物，然后向残余物中加入较低分子量的脂族醇，分离析出的产物。其中X，Y和Z具有上述含义的式IV“IMAGE”的硝基苯基脲通过酸水解得自式I化合物。

2. 发明授权

US4316861A N-Nitroaryl-N-halosulfonyl ureas 失效
标题翻译： N-硝基芳基-N-卤代磺酰脲
公开(公告)号：US4316861A
公开(公告)日：1982-02-23
申请号：US105560
申请日：1979-12-20
申请人： Otto Arndt , Wolfgang Tronich
发明人： Otto Arndt , Wolfgang Tronich
IPC分类号： C07C301/00 , C07C67/00 , C07C275/30 , C07C275/34 , C07C275/42 , C07C303/00 , C07C303/34 , C07C307/00 , C07C307/02 , C07C311/00 , C07C143/70
CPC分类号： C07C275/42 , C07C275/30 , C07C275/34 , C07C307/02
摘要： N-o-nitro-phenyl- or -naphthyl-N'-halogensulfonyl ureas which may be substituted in their aromatic rings by a further nitro group (and the phenyl ureas also by fluoro, chloro, bromo, lower alkyl, lower alkoxy, trifluoromethyl, cyano or phenyl) are obtained by reacting the corresponding o-nitraniline with fluoro- or chlorosulfonylisocyanate. The products can be hydrolyzed to yield the corresponding nitroaryl ureas.
摘要翻译：硝基 - 苯基 - 或 - 萘基-N'-卤代磺酰基脲，其可以在其芳环中被另外的硝基取代（苯基脲也可以被氟，氯，溴，低级烷基，低级烷氧基，三氟甲基，氰基或苯基）通过使相应的邻硝基苯胺与氟代或氯代磺酰基异氰酸酯反应而获得。可以将产物水解，得到相应的硝基芳基脲。

3. 发明授权

US4246196A Diaminophenyl ureas 失效
标题翻译：二氨基苯脲
公开(公告)号：US4246196A
公开(公告)日：1981-01-20
申请号：US105500
申请日：1979-12-20
申请人： Otto Arndt , Theodor Papenfuhs , Peter Bohme , Wolfgang Tronich , Bernhard Mees
发明人： Otto Arndt , Theodor Papenfuhs , Peter Bohme , Wolfgang Tronich , Bernhard Mees
IPC分类号： C07B61/00 , C07C67/00 , C07C239/00 , C07C275/40 , C07D235/02 , C07D235/26 , C07C127/19
CPC分类号： C07C275/40 , C07D235/26
摘要： Diaminophenyl ureas of the formula ##STR1## in which R is an inert substituent, are obtained from the corresponding dinitrophenyl urea by way of reduction, especially catalytic hydrogenation. Through a cyclization process, while splitting off ammonia, these ureas yield the corresponding aminobenzimidazolones, advantageously without an intermediate isolation of the diaminophenyl ureas.
摘要翻译：其中R为惰性取代基的式“IMAGE”的二氨基苯脲通过还原，特别是催化氢化由相应的二硝基苯脲获得。通过环化过程，在分解氨时，这些脲产生相应的氨基苯并咪唑酮，有利地不用二氨基苯脲的中间分离。

4. 发明授权

US5539114A Process for the preparation of substituted quinazoline-2,4,-diones 失效
标题翻译：制备取代喹唑啉-2,4'-二酮的方法
公开(公告)号：US5539114A
公开(公告)日：1996-07-23
申请号：US339948
申请日：1994-11-15
申请人： Robert Cosmo , Wolfgang Tronich
发明人： Robert Cosmo , Wolfgang Tronich
IPC分类号： C07B37/10 , C07D239/96
CPC分类号： C07D239/96
摘要： A process for the preparation of quinazoline-2,4-diones of the formula (I) ##STR1## in which R.sup.1 is aryl and R.sub.2, R.sup.3, R.sup.4, and R.sup.5 independently of one another are halogen, alkyl, alkoxy or hydrogen, by reacting anthranilic acid esters of the formula (II) ##STR2## in an aprotic reaction medium with aryl isocyanates R.sup.1 --N.dbd.C.dbd.O to give N-arylcarbamoyl-anthranilic acid esters of the formula (III) ##STR3## and cyclizing these in the presence of a base selected from the group of alkali metal or alkaline earth metal alkoxides, amides, hydrides or tetraalkylammonium hydroxides.
摘要翻译：制备式（I）的喹唑啉-2,4-二酮的方法其中R 1是芳基且R 2，R 3，R 4和R 5彼此独立地是卤素，烷基，烷氧基或通过使非质子反应介质中的式（II）的邻氨基苯甲酸酯与芳基异氰酸酯R 1 -N = C = O反应，得到式（III）的N-芳基氨基甲酰基 - 邻氨基苯甲酸酯（III）并在选自碱金属或碱土金属醇盐，酰胺，氢化物或四烷基氢氧化铵的碱的存在下环化它们。

5. 发明授权

US5446190A Process for the preparation of alkyl fluorobenzoates in high purity and high yield 失效
标题翻译：以高纯度和高产率制备氟代苯甲酸烷基酯的方法
公开(公告)号：US5446190A
公开(公告)日：1995-08-29
申请号：US339761
申请日：1994-11-15
申请人： Gilbert Billeb , Wolfgang Tronich
发明人： Gilbert Billeb , Wolfgang Tronich
IPC分类号： C07D239/96 , C07B37/10 , C07C67/14 , C07C69/62 , C07C69/78 , C07C275/42 , C07C69/76
CPC分类号： C07C67/14
摘要： Process for the preparation of alcohol fluorobenzoates of the formula (I) ##STR1## in which R is an alkyl radical and F.sub.n is 1 to 4 fluorine atoms which, independently of one another, are bonded to the aromatic ring, by reacting a fluorobenzyl chloride of the formula (II) ##STR2## in which F.sub.n is as defined above, with an at least stoichiometric amount of an alkali metal alcoholate ROM in which R is as defined above and M is an alkali metal from the group consisting of Li, Na and K, in the corresponding alcohol ROH at temperatures from -10.degree. C. to 150.degree. C., the solvent is distilled off, if appropriate, and the alkali metal chloride formed is separated off by treating the mixture with water or by filtration.
摘要翻译：制备式（I）的醇氟代苯甲酸的方法其中R是烷基，Fn是1-4个氟原子，它们彼此独立地通过与芳环结合，通过使其中Fn如上定义的式（II）的氟苄基氯与至少化学计量量的碱金属醇化物ROM，其中R如上所定义，M是来自由Li，Na和K组成的组中，在-10℃至150℃的温度下在相应的醇ROH中，如果合适，则蒸出溶剂，通过处理混合物分离形成的碱金属氯化物用水或过滤。

6. 发明授权

US3984433A Process for preparing copper phthalocyanine pigments of the .alpha.-modification 失效
标题翻译：制备{60-改性的铜酞菁颜料的方法
公开(公告)号：US3984433A
公开(公告)日：1976-10-05
申请号：US427314
申请日：1973-12-21
申请人： Ernst Spietschka , Siegfried Schiebler , Wolfgang Tronich
发明人： Ernst Spietschka , Siegfried Schiebler , Wolfgang Tronich
IPC分类号： C09B67/16 , C09B67/50 , C09B67/54 , C09B47/08
CPC分类号： C09B67/0026 , C09B67/0019 , Y10S8/919 , Y10T428/31678
摘要： A process for preparing very pure copper phthalocyanine pigments of the .alpha.-modification, wherein substituted or unsubstituted copper phthalocyanines having different degrees of purity are converted into copper phthalocyanine salts capable of being isolated, with the aid of suitable acids which dissolve the impurities contained in the dyestuff, wherein these salts are separated from the acid, the copper phthalocyanines of the .alpha.-modification are set free in a pure form from the copper phthalocyanine salts by the action of water and wherein the isolated copper phthalocyanine is subject in an aqueous suspension to a mechanical fine division. This process yields copper phthalocyanines of the .alpha.-modification in a very pure form without causing problems with respect to the waste water.
摘要翻译：一种制备α-纯化的非常纯的铜酞菁颜料的方法，其中具有不同纯度的取代或未取代的铜酞菁转化为能够分离的铜酞菁盐，借助于溶解包含在染料，其中这些盐与酸分离，α-修饰的铜酞菁通过水的作用从铜酞菁盐中以纯形式游离，并且其中分离的铜酞菁以水性悬浮液的形式存在于机械细分。该方法以非常纯的形式产生α-修饰的铜酞菁，而不会对废水造成问题。

7. 发明授权

US5559257A Process for the preparation of tetrachloro-1,4-benzoquinone 失效
标题翻译：制备四氯-1,4-苯醌的方法
公开(公告)号：US5559257A
公开(公告)日：1996-09-24
申请号：US392469
申请日：1995-02-22
申请人： Otto Arndt , Wolfgang Tronich
发明人： Otto Arndt , Wolfgang Tronich
IPC分类号： B01J27/128 , C07B61/00 , C07C46/00 , C07C46/06 , C07C50/24 , C07C50/20
CPC分类号： C07C46/06
摘要： The invention relates to a process for the preparation of tetrachloro-1,4-benzoquinone of high purity by the action of chlorine and concentrated hydrochloric acid on hydroquinone, which involves introducing a portion of the hydroquinone to be employed into initially introduced hydrochloric acid containing catalytic amounts of iron(III) ions and an anionic dispersant, introducing chlorine gas into this solution at a temperature from 20.degree. to 107.degree. C., then adding the residual quantity of hydroquinone as a solid or in solution, raising the temperature to from 80.degree. to 107.degree. C. while continuing to pass in gaseous chlorine, adding, after the introduction of gaseous chlorine has ended, a relatively high-boiling organic solvent which is not miscible with hydrochloric acid, and subsequently subjecting the reaction mixture to thermal aftertreatment.
摘要翻译：本发明涉及通过氯和浓盐酸对氢醌的作用制备高纯度的四氯-1,4-苯醌的方法，其包括将待使用的一部分氢醌引入含有催化剂的初始引入的盐酸中量的铁（III）离子和阴离子分散剂，在20至107℃的温度下将氯气引入该溶液中，然后加入残留量的氢醌作为固体或溶液，将温度升至80 在继续通入气态氯的同时，在气态氯引入结束后，加入与盐酸不混溶的相对高沸点的有机溶剂，随后使反应混合物进行热后处理。

8. 发明授权

US4990673A Process for the preparation of 4,4'-dinitrodiphenylamine 失效
标题翻译：制备4,4'-二硝基二苯胺的方法
公开(公告)号：US4990673A
公开(公告)日：1991-02-05
申请号：US437685
申请日：1989-11-16
申请人： Wolfgang Tronich , Peter Hess
发明人： Wolfgang Tronich , Peter Hess
IPC分类号： C07C209/22 , C07C209/10 , C07C211/56
CPC分类号： C07C209/10 , C07C211/56
摘要： Process for the preparation of 4,4'-dinitrodiphenylamine which comprises reacting 1 mole of 4-halonitrobenzene with about 1 to about 3 moles of an alkali metal cyanate in the presence of about 0.5 to about 5 moles of water in dimethylsulfoxide at temperatures of about 150.degree. to about 170.degree. C.
摘要翻译：制备4,4'-二硝基二苯胺的方法，其包括在约0.5至约5摩尔水的二甲基亚砜存在下，将约1至约3摩尔碱金属氰酸盐与约1至约3摩尔碱金属氰酸盐反应， 150℃至约170℃

9. 发明授权

US4507491A Process for preparing 1-nitrobenzene-2-alkyloxycarbonyl-5-carboxylic acids 失效
标题翻译：制备1-硝基苯-2-烷氧基羰基-5-羧酸的方法
公开(公告)号：US4507491A
公开(公告)日：1985-03-26
申请号：US445008
申请日：1982-11-29
申请人： Werner Wykypiel , Wolfgang Tronich
发明人： Werner Wykypiel , Wolfgang Tronich
IPC分类号： C07B61/00 , B01J31/00 , B01J31/02 , C07C67/00 , C07C201/00 , C07C201/08 , C07C201/12 , C07C205/57 , C07C79/46 , C07C76/02
CPC分类号： C07C201/14
摘要： To prepare a 1-nitrobenzene-2-alkyloxycarbonyl-5-carboxylic acid, a dialkyl benzene-1,4-dicarboxylate is first nitrated in a customary manner and the dialkyl 1-nitrobenzene-2,5-dicarboxylate compound obtained is subjected to a partial acidic ester hydrolysis without isolating the nitro compound prepared as an intermediate. The acidic ester hydrolysis is carried out in the presence of a catalytic amount of an organic solvent which is completely or partially miscible with water and has a boiling point of above 90.degree. C. and/or of an emulsifier; it is preferably carried out at a temperature between 65.degree. and 110.degree. C.
摘要翻译：为了制备1-硝基苯-2-烷氧基羰基-5-羧酸，以常规方式首先硝化二苯基-1,4-二羧酸二烷基酯，将得到的1-硝基苯-2,5-二羧酸二烷基酯化合物不分离作为中间体制备的硝基化合物的部分酸性酯水解。酸性酯水解在催化量的与水完全或部分混溶并且沸点高于90℃的有机溶剂和/或乳化剂的存在下进行; 优选在65℃〜110℃的温度下进行。

10. 发明授权

US4410707A Process for the manufacture of 3-amino-1-phenylpyrazol-5-one 失效
标题翻译： 3-氨基-1-苯基吡唑-5-酮的制备方法
公开(公告)号：US4410707A
公开(公告)日：1983-10-18
申请号：US285469
申请日：1981-07-21
申请人： Wolfgang Tronich , Wolfgang Rieper , Peter Bohme
发明人： Wolfgang Tronich , Wolfgang Rieper , Peter Bohme
IPC分类号： C07D231/22 , C07D231/38 , C07D231/52
CPC分类号： C07D231/52
摘要： The preparation of 3-amino-1-phenylpyrazol-5-one by heating phenylhydrazine and a lower cyanoacetic acid alkyl ester in a polar solvent, using a lower alcoholate of an alkali metal as the condensation agent, leads to particularly high yields and quality, if the phenylhydrazine and 1 to 1.2 moles of the alcoholate are initially taken, the cyanoacetic ester is metered in and the reaction is carried out at 105.degree. to 140.degree. C., volatile alcohols which have been liberated from the ester and, if appropriate, from the alcoholate being distilled off at the reaction temperature. It is advantageous to employ the phenylhydrazine in an excess of up to about 200 mole % and to select, as the polar solvent, an alcohol or ether having a boiling point above 105.degree. C.
摘要翻译：使用碱金属的低级醇化物作为缩合剂，通过在极性溶剂中加热苯肼和低级氰基乙酸烷基酯来制备3-氨基-1-苯基吡唑-5-酮导致特别高的产率和质量，如果最初采用苯肼和1至1.2摩尔醇化物，则将氰乙酸酯计量并在105至140℃进行反应，从酯中释放的挥发性醇，如果合适的话，从醇化物在反应温度下蒸馏掉。使用过量高达约200摩尔％的苯肼是有利的，并且选择沸点高于105℃的醇或醚作为极性溶剂。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式