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1. 发明授权

US06720404B2 Polycarbonates for optical use, and their applications 有权
标题翻译：用于光学用途的聚碳酸酯及其应用
公开(公告)号：US06720404B2
公开(公告)日：2004-04-13
申请号：US10116843
申请日：2002-04-05
申请人： Kazushige Inoue , Tomoaki Shimoda
发明人： Kazushige Inoue , Tomoaki Shimoda
IPC分类号： C08G6402
CPC分类号： G11B7/2534 , C08G64/307 , G11B7/2433 , G11B7/2467 , G11B7/2472 , G11B7/248 , G11B7/2585 , G11B7/259 , G11B7/2595 , G11B2007/24316
摘要： This specification discloses polycarbonates for optical use. These polycarbonates are prepared by reacting a bisphenol and carbonic diester in the presence of an alkaline compound catalyst. These polycarbonates have: (i) an intrinsic viscosity (IV) as determined at 20° C. in methylene chloride of between 0.34 and 0.38; (ii) a glass transition temperature (Tg) as determined by DSC of between 143 and 147° C.; and (iii) an intrinsic viscosity (IV) and glass transition temperature (Tg) ratio complying with the following general formula (A): IV×95.888+107.9
摘要翻译：本说明书公开了用于光学用途的聚碳酸酯。这些聚碳酸酯通过在碱性化合物催化剂的存在下使双酚和碳酸二酯反应来制备。这些聚碳酸酯具有：（i）在20℃下在二氯甲烷中测定的在0.34和0.38之间的特性粘度（IV）;（ii）通过DSC测定的玻璃化转变温度（Tg）为143-147℃ 。和（iii）符合以下通式（A）的特性粘度（IV）和玻璃化转变温度（Tg）比：

2. 发明授权

US06562433B1 Method for the preparation of polycarbonate with reduced levels of fries 有权
标题翻译：制备具有降低油炸薯片的聚碳酸酯的方法
公开(公告)号：US06562433B1
公开(公告)日：2003-05-13
申请号：US09663857
申请日：2000-09-18
申请人： Hiromi Ishida , Kenichi Ishiwa , Mitsuyasu Okamura , Tomoaki Shimoda , Theodorus L. Hoeks , Henricus H. M. van Hout , Monica M. Marugan , Patrick J. McCloskey , Joseph A. King, Jr. , Paul M. Smigelski, Jr.
发明人： Hiromi Ishida , Kenichi Ishiwa , Mitsuyasu Okamura , Tomoaki Shimoda , Theodorus L. Hoeks , Henricus H. M. van Hout , Monica M. Marugan , Patrick J. McCloskey , Joseph A. King, Jr. , Paul M. Smigelski, Jr.
IPC分类号： C08G6430
CPC分类号： G11B7/2534 , C08G64/06 , C08G64/307 , G11B7/2533 , G11B7/26
摘要： The present invention provides a composition comprising polycarbonate wherein the polycarbonate has a very low Fries content (e.g., above 5 ppm and below 360 ppm). The present invention also provides a polycarbonate having a very low Fries content which is made by the melt process. This polycarbonate has high ductility and high impact strength. The invention also provides a method for making these compositions. Another aspect of the invention is an optical disk comprising polycarbonate having a very low Fries content which is made by the melt process. Such optical disks resist breakage due to bending.
摘要翻译：本发明提供包含聚碳酸酯的组合物，其中聚碳酸酯具有非常低的薯条含量（例如高于5ppm和低于360ppm）。本发明还提供了通过熔融法制造的具有非常低的薯条含量的聚碳酸酯。该聚碳酸酯具有高延展性和高冲击强度。本发明还提供了制备这些组合物的方法。本发明的另一方面是包括通过熔融法制造的具有非常低的薯条含量的聚碳酸酯的光盘。这种光盘由于弯曲而抵抗破损。

3. 发明授权

US06294642B1 Continuous method for manufacturing polycarbonate 有权
公开(公告)号：US06294642B1
公开(公告)日：2001-09-25
申请号：US09464138
申请日：1999-12-16
申请人： Tomoaki Shimoda , Takeshi Sakashita
发明人： Tomoaki Shimoda , Takeshi Sakashita
IPC分类号： C08G6400
CPC分类号： C08G64/307 , C08G64/205
摘要： To provide a method with which a polycarbonate can be manufactured efficiently without any pipe clogging or foreign material admixture in the course of the continuous manufacture of a polycarbonate. A continuous method for manufacturing a polycarbonate, characterized in that, in the continuous manufacture of a polycarbonate by transesterification from a dihydroxy compound and a carbonic diester, the crystallization of a polycarbonate lower polycondensate produced in the intermediate stage of a polycondensation reaction whose intrinsic viscosity (IV) measured at 20° C. in methylene chloride is between 0.1 and 0.4 dL/g is suppressed by setting the temperature to be at least 230° C. on the surface of the reactor equipment in contact with the polycarbonate lower polycondensate.

4. 发明授权

US06277946B1 Method for preparation of polycarbonates 有权
标题翻译：聚碳酸酯的制备方法
公开(公告)号：US06277946B1
公开(公告)日：2001-08-21
申请号：US09567826
申请日：2000-05-09
申请人： Johannes Jacobus van Heijkant , Christopher Poirier , Tomoaki Shimoda , Akio Kanezawa , Carlos Godinez Seoane
发明人： Johannes Jacobus van Heijkant , Christopher Poirier , Tomoaki Shimoda , Akio Kanezawa , Carlos Godinez Seoane
IPC分类号： C08G6400
CPC分类号： C08G64/307 , G11B7/253
摘要： A method is provided for the preparation of polycarbonates by the reaction of a diaryl carbonate, such as DPC and a dihydric phenol, such as BPA. The method utilizes the steps of successively processing the diaryl carbonate and the dihydric phenol in a melt in a first reaction stage, a second reaction stage and at least a first polymerization stage, and shifts the processing conditions such that the desired low viscosity/high end-cap product is obtained. This is achieved by having the ratio of diaryl carbonate to dihydric phenol in the melt prior to the first reaction stage greater than 1.08; and by controlling the temperature and residence time in the first polymerization stage to provide a polycarbonate product having a melt flow rate at 250° C. of greater than 10 g/min and an end-cap level of at least 90%. The method of the invention can be used in a linear manufacturing process, in which there is one product produced. The method of the invention can also be incorporated into a multi-line manufacturing process for the simultaneous production of more than one product. Thus, a stream of product produced from the first polymerization stage may be split into two or more lines which are further processed to produce, for example, a low viscosity, high end-cap product and a medium viscosity, moderate end-cap product.
摘要翻译：提供了通过碳酸二芳基酯如DPC和二元酚如BPA的反应来制备聚碳酸酯的方法。该方法采用在第一反应阶段，第二反应阶段和至少第一聚合阶段中在熔体中连续加工碳酸二芳基酯和二元酚的步骤，并使加工条件转变为所需的低粘度/高端 -cap产品。这通过在第一反应阶段之前使熔体中的碳酸二芳基酯与二元酚的比率大于1.08来实现; 并且通过控制在第一聚合阶段中的温度和停留时间被选择以提供熔体流动速率在250℃下大于10g / 10分钟且端帽水平至少为90％的聚碳酸酯产品。本发明的方法可以用于生产一种产品的线性制造过程中。本发明的方法还可以并入用于同时生产多于一种产品的多线制造工艺中。因此，从第一聚合阶段生产的产品流可以分成两行或更多行，其进一步加工以产生例如低粘度，高端帽产品和中等粘度的适中的端帽产品。

5. 发明授权

US6022943A Optical quality polycarbonates with reduced static charge and method for making same 有权
标题翻译：具有降低静电荷的光学质量聚碳酸酯及其制造方法
公开(公告)号：US6022943A
公开(公告)日：2000-02-08
申请号：US287668
申请日：1999-04-07
申请人： Kazushige Inoue , Hiromi Ishida , Tomoaki Shimoda , Theodorus L. Hoeks , Henricus H. M. van Hout , Monica M. Marugan , David M. Dardaris , Patrick J. McCloskey
发明人： Kazushige Inoue , Hiromi Ishida , Tomoaki Shimoda , Theodorus L. Hoeks , Henricus H. M. van Hout , Monica M. Marugan , David M. Dardaris , Patrick J. McCloskey
IPC分类号： C08L69/00 , C08G64/14 , C08G64/30 , G11B7/253 , G11B11/105 , C08G64/00
CPC分类号： C08G64/14 , C08G64/307 , G11B7/2534
摘要： Increasing the endcap level to a level greater than about 90% for Optical Quality (OQ) Melt Polycarbonate significantly reduces the as-molded static charge for injection molded parts for Optical Disc applications. The use of resins with higher endcap levels in combination with antistatic additives provides a highly robust formulation suitable for even the most demanding emerging formats as Digital Versatile Disc (DVD) and in all commercial Optical media molding machines. Thus, optical quality polycarbonates are prepared by performing a base-catalyzed polymerization of a diaryl carbonate and a dihydric phenol under conditions effective to produce a polycarbonate product having an endcap level of 90% or greater.
摘要翻译：将端盖水平提高到光学质量（OQ）的大约90％以上熔融聚碳酸酯显着降低了用于光盘应用的注塑部件的模制静电荷。使用具有更高端帽水平的树脂与抗静电添加剂相结合提供了高度鲁棒的配方，适用于甚至最苛刻的新兴格式，如数字多功能光盘（DVD）和所有商业光学介质成型机。因此，通过在有效地制备端帽水平为90％以上的聚碳酸酯制品的条件下进行碳酸二芳基酯和二元酚的碱催化聚合来制备光学质量的聚碳酸酯。

6. 发明授权

US5859172A Polycarbonate, copolycarbonate resin compositions and preparing method thereof 失效
标题翻译：聚碳酸酯，共聚碳酸酯树脂组合物及其制备方法
公开(公告)号：US5859172A
公开(公告)日：1999-01-12
申请号：US820872
申请日：1997-03-20
申请人： Takeshi Sakashita , Tomoaki Shimoda , Takashi Nagai
发明人： Takeshi Sakashita , Tomoaki Shimoda , Takashi Nagai
IPC分类号： C08K3/18 , C08G64/00 , C08G64/04 , C08G64/20 , C08G64/30 , C08K3/00 , C08K3/30 , C08K5/00 , C08K5/04 , C08K5/36 , C08K5/42 , C08L69/00 , C08G63/64
CPC分类号： C08G64/307 , C08G64/04 , C08L69/00
摘要： A copolycarbonate and a copolycarbonate composition having oustanding hardness and a method for their manufacture.A copolycarbonate containing the component units shown in Formula �I!below in the amount of 50-99 mole %: ##STR1## X is ##STR2## R1 and R2 are hydrogen atoms or monovalent hydrocarbon groups, and R3 is a bivalent hydrocarbon group.) The Rockwell hardness (M scale) of this polycarbonate should preferably be 45-90.
摘要翻译：一种共聚碳酸酯和具有高硬度硬度的共聚碳酸酯组合物及其制造方法。含有下式[I]所示组分单元的共聚碳酸酯的量为50-99摩尔％：其中R1和R2是氢原子或一价烃基，R3是二价烃基。）该聚碳酸酯的洛氏硬度（M比例）应优选为45-90。

7. 发明授权

US5760156A Manufacturing method for polycarbonate 失效
标题翻译：聚碳酸酯的制造方法
公开(公告)号：US5760156A
公开(公告)日：1998-06-02
申请号：US764816
申请日：1996-12-12
申请人： Satoshi Inoki , Yoshio Motoyama , Hideto Matsuoka , Hajime Oyoshi , Michio Tanaka , Tomoaki Shimoda , Akio Kanezawa , Kazutoyo Uno
发明人： Satoshi Inoki , Yoshio Motoyama , Hideto Matsuoka , Hajime Oyoshi , Michio Tanaka , Tomoaki Shimoda , Akio Kanezawa , Kazutoyo Uno
IPC分类号： C08G64/20 , C08G64/30 , C08G18/70
CPC分类号： C08G64/307
摘要： A manufacturing method for polycarbonate comprising �I! a process for manufacturing diaryl carbonate from an aromatic hydroxy compound and an aromatic hydroxy compound, �II! a process for manufacturing polycarbonate by solution polymerization of the diaryl carbonate obtained in �II! and an aromatic dihydroxy compound in the presence of a catalyst comprising a nitrogen-containing basic compound, and �III! a process for separating and removing the nitrogen-containing compound from the aromatic hydroxy by-products in �II! and returning the resultant aromatic hydroxy compounds to process �I! effectively reuses aromatic hydroxy by-products (e.g., phenols) of polycarbonate manufacturing to manufacture diaryl carbonate, while suppressing the production of alkyl aromatic ethers and then uses this diaryl carbonate to manufacture polycarbonate with good productivity.
摘要翻译：一种聚碳酸酯的制造方法，其包含：[I]由芳香族羟基化合物和芳香族羟基化合物制造碳酸二芳基酯的方法，[II]通过在[II]中得到的碳酸二芳基酯的溶液聚合制造聚碳酸酯的方法和芳香族二羟基在含有含氮碱性化合物的催化剂存在下的化合物，和[III]从[II]中的芳族羟基副产物中分离除去含氮化合物并将所得芳族羟基化合物返回到方法 [I]有效地重复使用制造碳酸二甲酯的聚碳酸酯的芳族羟基副产物（例如酚），同时抑制烷基芳族醚的生产，然后使用该碳酸二芳基酯以高生产率制造聚碳酸酯。

8. 发明授权

US5717057A Method of manufacturing polycarbonate 失效
标题翻译：制造聚碳酸酯的方法
公开(公告)号：US5717057A
公开(公告)日：1998-02-10
申请号：US581639
申请日：1995-12-28
申请人： Takeshi Sakashita , Tomoaki Shimoda , Takashi Nagai
发明人： Takeshi Sakashita , Tomoaki Shimoda , Takashi Nagai
IPC分类号： C08G64/30 , C08G64/40 , C08G64/00
CPC分类号： C08G64/307
摘要： A method for manufacturing polycarbonate in which an aromatic dihydroxy compound and a carbonic acid diester can be effectively subjected to melt polycondensation using a small amount of a catalyst, making it possible to manufacture polycarbonate having outstanding color matching, outstanding thermal stability, color-matching stability, etc., during molding, and outstanding water resistance is characterized in that when an aromatic dihydroxy compound and a carbonic acid diester are subjected to melt polycondensation in the presence of a catalyst, the catalyst is dissolved or dispersed as a catalyst solution, this catalyst solution is added to the melt polycondensation reaction system, and the aromatic dihydroxy compound and carbonic acid diester are subjected to melt polycondensation.
摘要翻译：可以使用少量催化剂将芳族二羟基化合物和碳酸二酯有效地进行熔融缩聚的聚碳酸酯的制造方法，能够制造出色的匹配性，突出的热稳定性，色匹配稳定性的聚碳酸酯等等，并且优异的耐水性的特征在于当芳族二羟基化合物和碳酸二酯在催化剂存在下进行熔融缩聚时，催化剂作为催化剂溶液溶解或分散，该催化剂将溶液加入到熔融缩聚反应体系中，芳族二羟基化合物和碳酸二酯进行熔融缩聚反应。

9. 发明授权

US5646233A Polycarbonate copolycarbonate resin compositions and preparing method thereof 失效
标题翻译：聚碳酸酯共聚碳酸酯树脂组合物及其制备方法
公开(公告)号：US5646233A
公开(公告)日：1997-07-08
申请号：US555100
申请日：1995-12-01
申请人： Takeshi Sakashita , Tomoaki Shimoda , Takashi Nagai
发明人： Takeshi Sakashita , Tomoaki Shimoda , Takashi Nagai
IPC分类号： C08K3/18 , C08G64/00 , C08G64/04 , C08G64/20 , C08G64/30 , C08K3/00 , C08K3/30 , C08K5/00 , C08K5/04 , C08K5/36 , C08K5/42 , C08L69/00 , C08G63/64
CPC分类号： C08G64/307 , C08G64/04 , C08L69/00
摘要： A copolycarbonate and a copolycarbonate composition having oustanding hardness and a method for their manufacture.A copolycarbonate containing the component units shown in Formula [I]below in the amount of 50-99 mole %: ##STR1## X is ##STR2## R1 and R2 are hydrogen atoms or monovalent hydrocarbon groups, and R3 is a bivalent hydrocarbon group.) The Rockwell hardness (M scale) of this polycarbonate should preferably be 45-90.
摘要翻译：一种共聚碳酸酯和具有高硬度硬度的共聚碳酸酯组合物及其制造方法。含有下式[I]所示组分单元的共聚碳酸酯的量为50-99摩尔％：其中R1和R2是氢原子或一价烃基，R3是二价烃基。）该聚碳酸酯的洛氏硬度（M比例）应优选为45-90。

10. 发明授权

US5606008A Preparation method of polycarbonate resin 失效
标题翻译：聚碳酸酯树脂的制备方法
公开(公告)号：US5606008A
公开(公告)日：1997-02-25
申请号：US506280
申请日：1995-07-21
申请人： Takeshi Sakashita , Tomoaki Shimoda , Takashi Nagai
发明人： Takeshi Sakashita , Tomoaki Shimoda , Takashi Nagai
IPC分类号： C08G59/40 , C08G64/20 , C08G64/30 , C08G64/40 , C08G64/42 , C08G64/00 , B01J27/24 , B01J31/00
CPC分类号： C08G64/307
摘要： The purpose of the present invention is to provide a method for manufacturing polycarbonate in which polycarbonate having outstanding color matching, outstanding thermal properties, particularly retention stability during molding, and outstanding water resistance can be effectively and easily manufactured.In the method for manufacturing polycarbonate of the present invention, an aromatic dihydroxy compound and a carbonic acid ester are subjected to melt condensation polymerization in the presence of a catalyst composed of(a) an aliphatic amine with 24-60 carbon atoms, and (b) an alkali metal compound and/or alkaline earth metal compound.The (a) aliphatic amine having 24-60 carbon atoms should preferably be an aliphatic tertiary amine and be used in the amount of 1.times.6.sup.-6 -1.times.10.sup.-1 moles for each mole of the aromatic dihydroxy compound, and the (b) alkali metal compound and/or alkaline earth metal compound should be used in an extremely minute specified amount.
摘要翻译：本发明的目的是提供一种制造聚碳酸酯的方法，其中可以有效且容易地制造其中具有优异的颜色匹配，优异的热性能，特别是成型时的保持稳定性和优异的耐水性的聚碳酸酯。在本发明的聚碳酸酯的制造方法中，在（a）具有24-60个碳原子的脂族胺和（b）的催化剂的存在下，使芳族二羟基化合物和碳酸酯进行熔融缩聚）碱金属化合物和/或碱土金属化合物。（a）具有24-60个碳原子的脂族胺应优选为脂族叔胺，并且每摩尔芳族二羟基化合物的用量为1x6-6-1×10-1摩尔，而（b）碱金属化合物和/或碱土金属化合物应以极微小的指定量使用。

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