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    • 1. 发明授权
    • Process for the extracting oxygen and iron from iron oxide-containing
ores
    • 从含氧化铁的矿石中提取氧和铁的工艺
    • US4997533A
    • 1991-03-05
    • US389955
    • 1989-08-07
    • Surendra K. KawatraTimothy C. Eisele
    • Surendra K. KawatraTimothy C. Eisele
    • C22B3/10C25C1/06
    • C22B3/10C25C1/06Y02P10/234
    • Oxygen and metallic iron are produced from an iron oxide-containing mineral, such as ilmenite, by extracting iron from the mineral with hydrochloric acid, separating solid residue from the resulting solution and drying same, electrolyzing the separated, iron chloride-containing solution to produce electrolytic iron and chlorine gas, combining the chlorine gas with water recovered from the drying and/or iron chloride-containing solution electrolysis steps of regenerate hydrochloric acid and recycling the hydrochloric acid to the extraction step. In an alternate embodiment, the chlorine gas is reacted with recovered water in the presence of a catalyst to produce hydrochloric acid which is recycled to the extraction step, thereby eliminating the need for water electrolysis and a separate hydrochloric acid regeneration step. In another alternate embodiment, electrolysis of the iron chloride-containing solution is operated to produce oxygen instead of chlorine gas at the anode and hydrochloric acid is generated concurrently with plating of iron at the cathode. This hydrochloric acid is recycled to the extraction step, thereby eliminating the need for water electrolysis and a separate hydrochloric acid regeneration step.
    • 氧化铁和金属铁由含铁氧化物的矿物如钛铁矿生产,通过用盐酸从矿物中提取铁,从所得溶液中分离固体残渣并干燥,电解分离的含氯化铁溶液以产生 电解铁和氯气,将氯气与从干燥和/或含铁氯化物溶液中回收的水混合,电解再生盐酸并将盐酸再循环到萃取步骤。 在一个替代实施方案中,氯气在催化剂存在下与回收的水反应以产生盐酸,其被再循环到萃取步骤,从而不需要水电解和单独的盐酸再生步骤。 在另一个替代实施例中,操作含氯化铁溶液的电解以在阳极产生氧而不是氯气,并且在阴极处与铁电镀同时产生盐酸。 将该盐酸再循环至提取步骤,从而不需要水电解和单独的盐酸再生步骤。
    • 5. 发明申请
    • Production of iron using environmentally-benign renewable or recycled reducing agents
    • 使用环保型可再生或回收还原剂生产铁
    • US20070209480A1
    • 2007-09-13
    • US11716352
    • 2007-03-09
    • Timothy C. EiseleSurendra Komar Kawatra
    • Timothy C. EiseleSurendra Komar Kawatra
    • C21C7/04
    • C21B13/0066C21B13/0006C21B13/008C21B13/04C21C2007/0031C22B1/244C22B1/245C22B5/10Y02P10/136Y02P10/216
    • To produce metallic iron from iron ore, a composition comprising a mass of material formed from a mixture of iron ore particles and particles of a reductant that is either a biomass material in particulate form or a plastic resinous material in particulate form is used. The reductant can also be a mixture of biomass material and resin in any proportions. The mass of material comprises at least one body having a shape adapted for smelting such as pellets, briquettes, pieces or lumps. The pellets have sufficient cohesion to maintain the shape into which they have been formed. The invention also provides a new method for smelting iron from its ore which comprises subdividing the ore into particles of a selected size, mixing the subdivided ore particles with particles of a biomass material or particles of a plastic resinous material or with mixtures thereof, forming a mass of the mixture into at least one body with a shape that is suited for smelting in a furnace and placing the body in a furnace and exposing it to sufficient heat to bring the iron therein to smelting temperature within the furnace to thereby produce metallic iron directly from the ore.
    • 为了从铁矿石生产金属铁,使用包含由铁矿石颗粒和作为颗粒形式的生物质材料的还原剂颗粒或颗粒形式的塑料树脂材料的混合物的混合物形成的大量材料的组合物。 还原剂也可以是任何比例的生物质材料和树脂的混合物。 材料的质量包括至少一个具有适于冶炼的形状的主体,例如颗粒,团块,块或块。 颗粒具有足够的内聚力以保持它们已经形成的形状。 本发明还提供了一种从其矿石中熔炼铁的新方法,其中包括将矿石细分成选定尺寸的颗粒,将细分矿石颗粒与生物质材料或塑料树脂材料颗粒或其混合物混合,形成 混合物的质量至少一个具有适于在炉中冶炼的形状并将本体放置在炉中并使其暴露于足够的热量以将铁中的铁熔化到炉内的熔炼温度的至少一个主体中,从而直接产生金属铁 从矿石。
    • 6. 发明授权
    • Production of iron using environmentally-benign renewable or recycled reducing agents
    • 使用环保型可再生或回收还原剂生产铁
    • US07632330B2
    • 2009-12-15
    • US11716352
    • 2007-03-09
    • Timothy C. EiseleSurendra Komar Kawatra
    • Timothy C. EiseleSurendra Komar Kawatra
    • C21B13/00
    • C21B13/0066C21B13/0006C21B13/008C21B13/04C21C2007/0031C22B1/244C22B1/245C22B5/10Y02P10/136Y02P10/216
    • To produce metallic iron from iron ore, a composition comprising a mass of material formed from a mixture of iron ore particles and particles of a reductant that is either a biomass material in particulate form or a plastic resinous material in particulate form is used. The reductant can also be a mixture of biomass material and resin in any proportions. The mass of material comprises at least one body having a shape adapted for smelting such as pellets, briquettes, pieces or lumps. The pellets have sufficient cohesion to maintain the shape into which they have been formed. The invention also provides a new method for smelting iron from its ore which comprises subdividing the ore into particles of a selected size, mixing the subdivided ore particles with particles of a biomass material or particles of a plastic resinous material or with mixtures thereof, forming a mass of the mixture into at least one body with a shape that is suited for smelting in a furnace and placing the body in a furnace and exposing it to sufficient heat to bring the iron therein to smelting temperature within the furnace to thereby produce metallic iron directly from the ore.
    • 为了从铁矿石生产金属铁,使用包含由铁矿石颗粒和作为颗粒形式的生物质材料的还原剂颗粒或颗粒形式的塑料树脂材料的混合物的混合物形成的大量材料的组合物。 还原剂也可以是任何比例的生物质材料和树脂的混合物。 材料的质量包括至少一个具有适于冶炼的形状的主体,例如颗粒,团块,块或块。 颗粒具有足够的内聚力以保持它们已经形成的形状。 本发明还提供了一种从其矿石中熔炼铁的新方法,其中包括将矿石细分成选定尺寸的颗粒,将细分矿石颗粒与生物质材料或塑料树脂材料颗粒或其混合物混合,形成 混合物的质量至少一个具有适于在炉中冶炼的形状并将本体放置在炉中并使其暴露于足够的热量以将铁中的铁熔化到炉内的熔炼温度的至少一个主体中,从而直接产生金属铁 从矿石。
    • 8. 发明授权
    • Flotation column with adjustable supported baffles
    • 浮选柱,带可调支撑挡板
    • US5335785A
    • 1994-08-09
    • US64825
    • 1993-05-19
    • Surendra K. KawatraTimothy C. Eisele
    • Surendra K. KawatraTimothy C. Eisele
    • B03D1/24B03D1/14
    • B03D1/24B03D1/082B03D1/1481B01J2219/00777B01J2219/185
    • An apparatus for separating by froth flotation hydrophobic and hydrophilic particles contained in an aqueous slurry, the apparatus comprising a generally vertical tubular column having an upper froth zone, an upper separation zone, a lower separation zone, an air inlet zone, and an intermediate feed inlet zone; a feed inlet, air inlet, froth outlet and a tailings outlet; an upper baffle unit comprising a plurality of horizontally extending upper baffle plates, a vertical upper support member including an upper end portion, and first upper apparatus for removably mounting the upper baffle plates on the upper support member at predetermined vertically spaced positions; each of the upper baffle plates comprising a mounting aperture and a plurality of flow apertures; and a second upper apparatus for removably supporting the upper support member in the column with the upper baffle plates in the upper separation zone. The apparatus can include a lower baffle unit. The open area of each baffle plate and the vertical space between adjacent baffle plates can vary between different baffle plates in dependence upon the position of a baffle plate in the column, or in dependence upon one or more of the following: a solids flow rate at the position, a liquid flow rate at the position, and a gas flow rate at the position. The invention also provides a method for improving the operating performance of an unbaffled column.
    • 一种用于通过泡沫浮选将包含在水性浆液中的疏水性和亲水性颗粒分离的装置,该装置包括具有上部泡沫区域,上部分离区域,下部分离区域,空气入口区域和中间进料的大致垂直的管状塔 入口区; 进料口,进气口,泡沫出口和尾矿出口; 上部挡板单元,包括多个水平延伸的上部挡板,包括上端部的垂直上部支撑构件和用于以预定的垂直间隔位置可拆卸地将上部挡板固定在上部支撑构件上的第一上部装置; 每个上挡板包括安装孔和多个流动孔; 以及第二上部装置,用于将上部支撑构件可拆卸地支撑在上部隔离区中的上部挡板上。 该装置可包括下挡板单元。 每个挡板的开口面积和相邻挡板之间的垂直间隔可以根据挡板在柱中的位置或根据以下一个或多个而在不同挡板之间变化:固体流速 位置,位置处的液体流量以及位置处的气体流量。 本发明还提供了一种用于改善无色柱的操作性能的方法。
    • 9. 发明授权
    • On-line analysis of ash containing slurries
    • 含灰浆的在线分析
    • US4916719A
    • 1990-04-10
    • US203323
    • 1988-06-07
    • Surendra K. KawatraLawrence L. SutterTimothy C. Eisele
    • Surendra K. KawatraLawrence L. SutterTimothy C. Eisele
    • G01N23/12
    • G01N23/12
    • The ash content of coal suspended in a slurry is determined by bombarding a sample of the slurry flowing past a window of a measuring chamber with radiation from an annular nucleonic source, such as Cm-244, for emitting radiation within the range of about 7 to about 30 KeV and causing the sample to emit both backscattered and iron fluorescent x-rays. These x-rays are detected by a radiation detector which produces first and second electrical signals representative of the intensity of each. The density of the sample flowing from the measuring chamber is measured, such as by a nucelonic density gauge, to produce an electrical signal representative of the density and the ash content is determined from the detected intensities of the backscattered and iron fluorescent x-rays and the sample density.
    • 悬浮在浆料中的煤的灰分含量通过用来自环形核子源(例如Cm-244)的辐射轰击流过测量室的窗口的浆料样品来确定,以将辐射辐射在约7至 约30KeV,并使样品发射反向散射和铁荧光X射线。 这些X射线由辐射检测器检测,辐射检测器产生代表每个X射线强度的第一和第二电信号。 测量从测量室流出的样品的密度,例如通过纳米密度计,以产生代表密度的电信号,并根据检测到的背散射和铁荧光X射线的强度确定灰分含量, 样品密度。