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1. 发明授权

US3959220A Polymer additives comprising transition metal complexes with trivalent phosphorous compounds 失效
标题翻译：包含过渡金属络合物与三价磷化合物的聚合物添加剂
公开(公告)号：US3959220A
公开(公告)日：1976-05-25
申请号：US208927
申请日：1971-12-16
申请人： Ingenuin Hechenbleikner , Thomas G. Kugele , John F. Hussar
发明人： Ingenuin Hechenbleikner , Thomas G. Kugele , John F. Hussar
IPC分类号： C07F9/02 , C08K5/49 , C08J3/20
CPC分类号： C07F9/02 , C08K5/49
摘要： Ultraviolet light absorbers and stabilizers, particularly for monolefin polymers, are provided from metal complexes of trivalent phosphorus compounds of the formulaeMe (L).sub.n (A).sub.m (L').sub.owhere Me is preferably nickel but can be manganese, iron, copper, molybdenum or tungsten, L is P(X)(Y)(Z) where any one or all of X, Y and Z can be O hydrocarbyl, ##EQU1## where R.sub.31 and R.sub.32 are hydrocarbyl oro hydrogen, S hydrocarbyl, hydrocarbyl, 2 or 3 of X, Y and Z can form one or more heterocyclic rings with P, A is an anion such as halogen, e.g. Cl, Br, I or F, NO.sub.3, ClO.sub.4, R.sub.33 COO.sup.- where R.sub.33 is hydrocarbyl, any hydrocarbyl group can have 1 or 2 halogen substituents, m is 0 or a small whole number, e.g. 1,2,3,4, L' is CO, NO, CN, halogen, o is zero or a small whole number, e.g. 1,2,3,4, n is 1 or another small whole number, e.g. 2,3,4, o+m+n is not greater than the highest coordination number of the metal.
摘要翻译：特别是单烯烃聚合物的紫外光吸收剂和稳定剂由式Me（L）n（A）m（L'）o的三价磷化合物的金属络合物提供，其中Me优选为镍，但可以是锰，铁，铜，钼或钨，L是P（X）（Y）（Z），其中X，Y和Z中的任何一个或全部可以是O烃基，R 31 N ANGLE R 32，其中R 31和R 32是烃基或氢，S烃基，烃基，X，Y和Z的2或3可以与P形成一个或多个杂环，A是阴离子如卤素，例如 Cl，Br，I或F，NO 3，ClO 4，R 33 COO - ，其中R 33为烃基，任何烃基可具有1或2个卤素取代基，m为0或小整数，例如。 1,2,3,4，L'为CO，NO，CN，卤素，o为零或小整数，例如。 1,2,3,4，n是1或另一个小整数，例如 2,3,4，o + m + n不大于金属的最高配位数。

2. 发明授权

US4012399A Transition metal complexes with trivalent phosphorus compounds 失效
标题翻译：过渡金属络合物与三价磷化合物
公开(公告)号：US4012399A
公开(公告)日：1977-03-15
申请号：US628787
申请日：1975-11-04
申请人： Ingenuin Hechenbleikner , Thomas G. Kugele , John F. Hussar
发明人： Ingenuin Hechenbleikner , Thomas G. Kugele , John F. Hussar
IPC分类号： C08K5/00 , C07F15/04
CPC分类号： C08K5/0091
摘要： Ultraviolet light absorbers and stabilizers, particularly for monolefin polymers, are provided from metal complexes of trivalent phosphorus compounds of the formulaeMe (L).sub.n (A).sub.m (L').sub.owhere Me is preferably nickel but can be manganese, iron, copper, molybdenum or tungsten, L is P(X)(Y)(Z) where any one or all of X, Y and Z can be O hydrocarbyl, ##STR1## where R.sub.31 and R.sub.32 are hydrocarbyl or hydrogen, S hydrocarbyl, hydrocarbyl, 2 or 3 of X, Y and Z can form one or more heterocyclic rings with P, A is an anion such as halogen, e.g. Cl, Br, I or F, NO.sub.3, C104, R.sub.33 COO- where R.sub.33 is hydrocarbyl, any hydrocarbyl group can have 1 or 2 halogen substituents, m is 0 or a small whole number, e.g. 1,2,3,4, L' is CO, NO, CN, halogen, o is zero or a small whole number, e.g. 1,2,3,4, n is 1 or another small whole number, e.g. 2,3,4, o+m+n is not greater than the highest coordination number of the metal.
摘要翻译：特别是单烯烃聚合物的紫外光吸收剂和稳定剂由式Me（L）n（A）m（L'）o的三价磷化合物的金属络合物提供，其中Me优选为镍，但可以是锰，铁，铜，钼或钨，L是P（X）（Y）（Z），其中X，Y和Z中的任何一个或全部可以是O烃基，其中R 31和R 32是烃基或氢，S烃基，烃基， X，Y和Z的2或3可以与P形成一个或多个杂环，A是阴离子如卤素， Cl，Br，I或F，NO3，C104，R33COO-，其中R33是烃基，任何烃基可以具有1或2个卤素取代基，m为0或小整数，例如。 1,2,3,4，L'为CO，NO，CN，卤素，o为零或小整数，例如。 1,2,3,4，n是1或另一个小整数，例如 2,3,4，o + m + n不大于金属的最高配位数。

3. 发明授权

US4743304A Asphalt antistripping agents containing organic amines and Portland cement 失效
标题翻译：含有机胺和波特兰水泥的沥青防粘剂
公开(公告)号：US4743304A
公开(公告)日：1988-05-10
申请号：US561382
申请日：1983-12-14
申请人： Dennis W. Gilmore , Thomas G. Kugele
发明人： Dennis W. Gilmore , Thomas G. Kugele
IPC分类号： C08L95/00
CPC分类号： C08L95/00
摘要： The physical properties of bitumen/aggregate compositions are improved bya. adding an antistripping agent selected from imidazolines, polyamines, alkoxylated polyamines, aminocarboxylic esters, amide-amines and mixtures thereof to a bituminous material;b. adding Portland cement to an aggregate; andc. blending the products of steps a. and b.
摘要翻译：沥青/骨料组合物的物理性能由a改善。向烟煤中加入选自咪唑啉，多胺，烷氧基化多胺，氨基羧酸酯，酰胺 - 胺及其混合物的抗分解剂; b。将波特兰水泥添加到骨料中; 和c。混合步骤的产品a。和b。

4. 发明授权

US4711920A Stabilizers for halogen-containing polymers comprising the product of a diorganotin oxide, an ethylenically unsaturated dicarboxylic acid ester and a mercaptan 失效
标题翻译：包含二有机锡氧化物，烯键式不饱和二羧酸酯和硫醇的产物的含卤聚合物的稳定剂
公开(公告)号：US4711920A
公开(公告)日：1987-12-08
申请号：US889323
申请日：1986-07-23
申请人： Thomas G. Kugele , Keith A. Mesch , Karl R. Wursthorn , Gary M. Conroy
发明人： Thomas G. Kugele , Keith A. Mesch , Karl R. Wursthorn , Gary M. Conroy
IPC分类号： C08K5/11 , C08K5/10 , C08K5/37 , C08K5/57 , C08K5/58 , C08L27/00 , C08L27/04 , C08L67/00 , C07F7/22
CPC分类号： C08K5/58
摘要： Compositions for stabilizing halogen-containing organic polymers against the deteriorative effects of heat, light and weathering and which are non-irritating to eyes and mucous membranes, comprise the reaction product produced by combining an organotin oxide, an ethylenically unsaturated dicarboxylic acid ester and a mercaptan, wherein the chemical equivalence of the mercaptan is less than the chemical equivalence of the diorganotin oxide and the chemical equivalence of the diorganotin oxide is less than the chemical equivalence of the ester compound.
摘要翻译：用于稳定含卤素的有机聚合物的组合物抵抗热，光和风化的不良影响并且对眼睛和粘膜无刺激性的组合物包括通过将有机锡氧化物，烯键式不饱和二羧酸酯和硫醇组合而产生的反应产物其中硫醇的化学等价性小于二有机锡氧化物的化学等效性，二有机锡氧化物的化学等效性小于酯化合物的化学等效性。

5. 发明授权

US4391757A Organic antimony containing stabilizer compositions for halogenated polymers 失效
标题翻译：含有锑的卤化聚合物稳定剂组合物
公开(公告)号：US4391757A
公开(公告)日：1983-07-05
申请号：US325512
申请日：1981-11-27
申请人： Thomas G. Kugele , Dennis W. Gilmore
发明人： Thomas G. Kugele , Dennis W. Gilmore
IPC分类号： C08K5/59 , C09K15/32
CPC分类号： C09K15/326 , C08K5/59
摘要： In accordance with this invention there are provided organic antimony stabilizer compositions effective in stabilizing halogen containing organic polymers against the deteriorative effects of heat comprising (1) at least one organic antimony compound having at least one antimony to sulfur to carbon (i.e. Sb-S-C) linkage, (2) elemental sulfur, and (3) at least one 2-mercaptocarboxylic acid. Said 2-mercaptocarboxylic acid and elemental sulfur also serve to provide hydrolytic and UV light stability to the antimony compound per se. Also provided are stabilized organic polymer compositions comprising a halogen containing polymer and said organic antimony stabilizer composition.
摘要翻译：根据本发明，提供了有效稳定含卤素有机聚合物的有机锑稳定剂组合物，以防止热劣化，其包括（1）至少一种具有至少一个锑至硫的碳的有机锑化合物（即Sb-SC）连接，（2）元素硫，和（3）至少一种2-巯基羧酸。所述2-巯基羧酸和元素硫还用于为锑化合物本身提供水解和UV光稳定性。还提供了包含含卤素聚合物和所述有机锑稳定剂组合物的稳定的有机聚合物组合物。

6. 发明授权

US4665114A Stabilizer compositions and polymers containing same 失效
标题翻译：稳定剂组合物和含有它的聚合物
公开(公告)号：US4665114A
公开(公告)日：1987-05-12
申请号：US569545
申请日：1984-01-10
申请人： Thomas G. Kugele , Keith A. Mesch , Karl R. Wursthorn
发明人： Thomas G. Kugele , Keith A. Mesch , Karl R. Wursthorn
IPC分类号： C08K5/37 , C08K5/57 , C08K5/58
CPC分类号： C08K5/57 , C08K5/37 , C08K5/58
摘要： This invention relates to stabilizer compositions for polymers comprising (1) an organotin compound, or mixture of organotin compounds, (2) a mercaptan-containing organic compound or mixture of mercaptan-containing organic compounds, and, optionally, (3) a halogen-containing tin compound or mixture of halogen-containing tin compounds, said stabilizers having a total halogen content of about 0.1% to about 10% by weight based on the weight of the stabilizer composition. This invention also relates to polymer compositions containing said stabilizers, to a process for stabilizing polymer by adding thereto said stabilizers, and to articles of manufacture, e.g. pipe, comprising a polymer and said stabilizers.
摘要翻译：本发明涉及用于聚合物的稳定剂组合物，其包含（1）有机锡化合物或有机锡化合物的混合物，（2）含硫醇的有机化合物或含硫醇的有机化合物的混合物，和任选地，（3）含锡锡化合物或含卤素锡化合物的混合物，所述稳定剂的总卤素含量为稳定剂组合物重量的约0.1％至约10％。本发明还涉及含有所述稳定剂的聚合物组合物，通过向其中加入所述稳定剂和制品制备稳定聚合物的方法。管，其包含聚合物和所述稳定剂。

7. 发明授权

US4617334A Stabilizer compositions for PVC 失效
标题翻译： PVC稳定剂组合物
公开(公告)号：US4617334A
公开(公告)日：1986-10-14
申请号：US654580
申请日：1984-09-24
申请人： Thomas G. Kugele , Keith A. Mesch , Karl R. Wursthorn
发明人： Thomas G. Kugele , Keith A. Mesch , Karl R. Wursthorn
IPC分类号： C08K5/37 , C08K5/58 , C08K5/59 , C08K5/36 , C08K5/56
CPC分类号： C08K5/58 , C08K5/37 , C08K5/59
摘要： Compositions which are effective in stabilizing polymers against the deteriorative effects of heat are provided comprising (1) an organic antimony compound or mixture of organic antimony compounds, (2) a mercaptan-containing organic compound or mixture of mercaptan-containing organic compounds, and (3) a metal mercaptoalcohol or mixture of metal mercaptoalcohols. Also provided are polymer compositions containing said stabilizers, a process for stabilizing polymers, and articles of manufacture made from stabilized polymer compositions.
摘要翻译：提供了有效稳定聚合物以防止热劣化作用的组合物，其包括（1）有机锑化合物或有机锑化合物的混合物，（2）含硫醇的有机化合物或含硫醇的有机化合物的混合物和（ 3）金属巯基醇或金属巯基醇的混合物。还提供了含有所述稳定剂的聚合物组合物，稳定聚合物的方法和由稳定的聚合物组合物制成的制品。

8. 发明授权

US4558083A Stabilizer compositions and polymers containing same 失效
标题翻译：稳定剂组合物和含有它的聚合物
公开(公告)号：US4558083A
公开(公告)日：1985-12-10
申请号：US569542
申请日：1984-01-10
申请人： Thomas G. Kugele
发明人： Thomas G. Kugele
IPC分类号： C08K5/37 , C08K5/58
CPC分类号： C08K5/58 , C08K5/37
摘要： Compositions which are effective in stabilizing polymers against the deteriorative effects of heat are provided comprising (1) an organic tin compound or mixture of organic tin compounds, (2) an organic compound having an aromatic ring which is substituted with a hydroxyl (--OH) group and a mercapto (--SH) group ortho to each other, and, optionally, (3) an organotin mercaptide or mixture of organotin mercaptides. Also provided are polymer compositions containing said stabilizers and articles of manufacture made from said stabilized polymer compositions.
摘要翻译：提供了有效稳定聚合物以防止热劣化作用的组合物，其包括（1）有机锡化合物或有机锡化合物的混合物，（2）具有被羟基（-OH）取代的芳环的有机化合物，基团和巯基（-SH）基团彼此邻位，和任选地，（3）有机锡硫醇盐或有机锡硫醇盐的混合物。还提供了含有由所述稳定化聚合物组合物制成的所述稳定剂和制品的聚合物组合物。

9. 发明授权

US4305839A Hydroxybenzophenones 失效
标题翻译：羟基二苯甲酮
公开(公告)号：US4305839A
公开(公告)日：1981-12-15
申请号：US954998
申请日：1978-10-26
申请人： Kenneth R. Molt , Thomas G. Kugele , Karl R. Wursthorn
发明人： Kenneth R. Molt , Thomas G. Kugele , Karl R. Wursthorn
IPC分类号： C07C45/86 , C08K5/00 , C08K5/07 , C08K5/13 , C08K5/51 , C08L7/00 , C08L21/00 , C08L23/00 , C08L101/00 , C09K3/00
CPC分类号： C07C45/86 , C08K5/00 , C08K5/09 , C08K5/52
摘要： The storage stability of impure hydroxybenzophenones is improved by the addition thereto of an organic phosphite or organic phosphonite.
摘要翻译：通过添加有机亚磷酸酯或有机亚膦酸盐可以改善不纯的羟基二苯甲酮的储存稳定性。

10. 再颁专利

USRE30032E Carbofunctional sulfur and carboxylate bridged tin compounds 失效
标题翻译：碳官能团硫和羧基桥连锡化合物
公开(公告)号：USRE30032E
公开(公告)日：1979-06-12
申请号：US940450
申请日：1978-09-07
申请人： Thomas G. Kugele , Arthur F. Koeniger
发明人： Thomas G. Kugele , Arthur F. Koeniger
IPC分类号： C07F7/22 , C08K5/58
CPC分类号： C07F7/228 , C07F7/2268 , C08K5/58
摘要： Organotin compounds are prepared having (1) at least two tin atoms linked by a bridge through sulfur, carboxylate or both and containing at least two carbon atoms in the bridge, (2) directly attached to the tin atoms one to two alkyl groups containing one to eight carbon atoms and (3) a mercaptoalkanol or derivative thereof. The compounds are useful to stabilize halogen containing vinyl and vinylidene polymers, e.g. polyvinyl chloride.

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