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1. 发明授权

US11981629B2 Method for reducing heavy end formation and catalyst loss in a hydroformylation process 有权
公开(公告)号：US11981629B2
公开(公告)日：2024-05-14
申请号：US17624862
申请日：2020-06-23
申请人： PERSTORP AB
发明人： Matias Kangas , Stefan Nilsson
IPC分类号： B01D3/14 , B01D3/42 , B01J31/18 , C07C45/86
CPC分类号： C07C45/86 , B01D3/148 , B01D3/42 , B01J31/185 , B01J2231/321 , B01J2531/822
摘要： The present invention refers to a method for reducing heavy end formation and catalyst loss in a continuous hydroformylation process, where an olefin or an olefin mixture is reacted with carbon monoxide and hydrogen in a reactor assembly (1) in the presence of a rhodium complex catalyst, comprising at least one organobisphosphite ligand, in order to produce an aldehyde. Said method comprising the addition of an epoxide to the reaction mixture and the continuous or discontinuous removal of early heavy ends.

2. 发明申请

US20220251015A1 A METHOD FOR REDUCING HEAVY END FORMATION AND CATALYST LOSS IN A HYDROFORMYLATION PROCESS 有权
公开(公告)号：US20220251015A1
公开(公告)日：2022-08-11
申请号：US17624862
申请日：2020-06-23
申请人： PERSTORP AB
发明人： Matias KANGAS , Stefan NILSSON
IPC分类号： C07C45/86 , B01D3/14 , B01D3/42 , B01J31/18
摘要： The present invention refers to a method for reducing heavy end formation and catalyst loss in a continuous hydroformylation process, where an olefin or an olefin mixture is reacted with carbon monoxide and hydrogen in a reactor assembly (1) in the presence of a rhodium complex catalyst, comprising at least one organobisphosphite ligand, in order to produce an aldehyde. Said method comprising the addition of an epoxide to the reaction mixture and the continuous or discontinuous removal of early heavy ends.

3. 发明申请

US20210230090A1 METAL COMPLEXES OF B-DIKETONES AND/OR POLYPHENOLS BY GREEN CHEMISTRY, PREPARATION METHOD THEREOF, SUNSCREEN THEREOF, SKIN OR HAIR TONE CONCEALER THEREOF, HAIR DYEING THEREOF AND OTHER USES THEREOF 有权
公开(公告)号：US20210230090A1
公开(公告)日：2021-07-29
申请号：US16973256
申请日：2019-06-04
申请人： Liliana Patricia Ramirez Rios
发明人： Liliana Patricia Ramirez Rios
IPC分类号： C07C49/92 , C07C45/86 , C07C45/77 , A61K8/35 , A61K8/29 , A61K8/28 , A61K8/27 , A61K8/26 , A61K8/25 , A61K8/19 , A61Q17/04 , A61Q19/08 , A61Q1/12 , A61Q1/02 , A61K8/11 , C09B61/00
摘要： The present invention relates to a method to synthesize with high yield a colored metal complex of β-diketones and/or polyphenols by mechanochemistry without using aqueous or organic solvents and covers new complexes obtained therefrom. In an embodiment, only the reactants, a metal alkoxide and a β-diketone and/or a polyphenol, are present and react at different molar ratios to form a metal complex in the form of a homogeneous colored material (i.e. powder) with high yield. If curcumin is used, the color of the final metal complex dye depends on several factors such as the curcuminoids, the metal, the type of alkoxide used, the stoichiometric molar ratio of both reactants and the additives used. If titanium alkoxide and any additive is used, a red or violet colored titanium curcumin complex in powder form is produced. The production process of the metal complex in powder form is characterized by facility of scale up. The entire product is ready to be used in several applications. If polyphenols such as ferulic acid, quercetin, ellagic acid or lignin are used instead of curcumin, other colored complexes are obtained using mechanochemistry. In addition, the product comprising metal complexes of β-diketones and/or polyphenols is characterized by green chemistry manufacture. Besides, these metal complexes of β-diketones and/or polyphenols in several formulations are characterized by improved stability under storage conditions and improved sun protection against UV rays for human skin and human hair. The product is ready to be used alone or in combination with other additives or active ingredients in different formulations. The invention also covers the use of these metal β-diketones/polyphenol complexes in food, cosmetics, the pharmaceutical field and in the creativity field, as sunscreen, skin and hair concealer or foundation in powder form or cream, keratinous dye, textile dye, food dye, dye emulsions, miniemulsions, polymer colloids and catalysts.
The production process of these novel metal-complex dyes is also characterized by rapid production of colored compounds without using solvents and, thus, ecofriendliness. The process of the production of metal β-diketone and/or polyphenol complexes is characterized by the non-formation of toxic by-products and high yield.
In addition, the present invention comprises a hair dyeing molecule or formulation and procedure combining excellent dyeing properties with reduced risk of development cancer or allergies, while being ecological and of the natural origin.

4. 发明申请

US20170197899A1 Method for Improving Preservation Stability of 2,2-Difluoroacetoaldehyde 有权
公开(公告)号：US20170197899A1
公开(公告)日：2017-07-13
申请号：US15326808
申请日：2015-06-19
申请人： Central Glass Company, Limited
发明人： Masaaki TAKEDA , Shinya AKIBA , Ryo NADANO
IPC分类号： C07C45/86 , C07C41/50
CPC分类号： C07C45/86 , C07C41/50 , C07C43/313 , C07C47/14
摘要： A method for improving preservation stability of 2,2-difluoroacetaldehyde according to the present invention include at least: a first step of forming a “2,2-difluoroacetaldehyde-alcohol composite system” in which a 2,2-difluoroacetaldehyde hemiacetal coexists with an excess alcohol, wherein the total molar amount of the alcohol is 1.15 to 4.00 times the total molar amount of 2,2-difluoroacetaldehyde; and a second step of storing, in a storage container, the “2,2-difluoroacetaldehyde-alcohol composite system” formed in the first step. It is possible by this method to suppress the conversion of the 2,2-difluoroacetaldehyde hemiacetal to a dimer and maintain the original aldehyde activity of the target compound with less composition change over a long term.

5. 发明申请

US20160152540A1 NEW PROCESS FOR THE MAINTAINING OF A RATIO OF ISOMERS OF CAROTENOID COMPOUNDS 审中-公开
标题翻译：维持化合物化合物异构体比例的新方法
公开(公告)号：US20160152540A1
公开(公告)日：2016-06-02
申请号：US14900331
申请日：2014-06-18
申请人： DSM IP ASSETS B.V.
发明人： Basel ULRICH , Christian SCHAEFER , Franziska KREISSIG
IPC分类号： C07C45/86 , C07B63/04
CPC分类号： C07C45/86 , A23K20/105 , A23K20/179 , A23L5/44 , A23L33/10 , A23V2002/00 , C07B63/04 , C07B2200/09 , C07C7/20 , C07C403/02 , C07C403/16 , C07C403/24 , C07C2601/08 , C07C2601/16 , C07C13/28 , C07C13/20 , C07C11/21
摘要： The present invention relates to process for the maintaining of a ratio stereoisomers of carotenoid compounds by using at least one alkali and/or earth alkali metal salt of an organic acid, to specific formulations and to the use of such specific formulations.
摘要翻译：本发明涉及通过使用至少一种有机酸的碱金属和/或碱土金属盐来保持类胡萝卜素化合物的比例立体异构体的方法，以及特定制剂的使用。

6. 发明申请

US20150105589A1 Process for preparing cyclohexanol and cycohexanone from cyclohexane 审中-公开
标题翻译：从环己烷制备环己醇和环己酮的方法
公开(公告)号：US20150105589A1
公开(公告)日：2015-04-16
申请号：US14381210
申请日：2012-05-17
申请人： Zaosheng Xiao
发明人： Zaosheng Xiao
IPC分类号： C07C407/00 , C07C29/94 , C07C45/86 , C07C29/00 , C07C45/53
CPC分类号： C07C407/00 , C07C29/00 , C07C29/132 , C07C29/50 , C07C29/80 , C07C29/94 , C07C45/53 , C07C45/82 , C07C45/86 , C07C2601/14 , C07C49/403 , C07C409/14 , C07C35/08
摘要： A process for preparing cyclohexanol and cyclohexanone from cyclohexane includes steps of: (1) non-catalyticly oxidizing cyclohexane with molecular oxygen to obtain an oxidized mixture liquid containing cyclohexyl hydroperoxide (CHHP) as a main product; (2) performing a homogenous catalytic decomposition with an oil-soluble transitional metal compound serving as a catalyst, and serving as a scale inhibitor by 1-hydroxy ethidene-1,1-diphosphonic acid (di)octyl ester, or a combination of 1-hydroxy ethidene-1,1-diphosphonic acid (di)octyl ester and phosphoric acid octyl ester, to decompose the CHHP in the oxidized mixture liquid into cyclohexanol and cyclohexanone; and (3) rectifying to obtain products of the cyclohexanol and the cyclohexanone.
摘要翻译：从环己烷制备环己醇和环己酮的方法包括以下步骤：（1）用分子氧对环己烷进行非催化氧化，得到含环己基氢过氧化物（CHHP）为主要产物的氧化混合液; （2）用作为催化剂的油溶性过渡金属化合物进行均相催化分解，作为1-羟基亚乙基-1,1-二膦酸（二）辛酯等的防垢剂，或者1 - 羟基亚乙基-1,1-二膦酸（二）辛酯和磷酸辛酯，将氧化混合液中的CHHP分解成环己醇和环己酮; （3）整流得到环己醇和环己酮的产物。

7. 发明申请

US20140303338A1 PROCESS FOR PRODUCING ACROLEIN, ACRYLIC ACID AND DERIVATIVES THEREOF 有权
标题翻译：生产丙烯酸，丙烯酸及其衍生物的方法
公开(公告)号：US20140303338A1
公开(公告)日：2014-10-09
申请号：US14346072
申请日：2012-09-25
申请人： Nippon Shokubai Co., Ltd.
发明人： Hideaki Tsuneki , Masanori Nonoguchi , Koji Nishi
IPC分类号： C08F20/10 , C08F20/06 , C07C67/05 , C07C45/86 , C07C51/25
CPC分类号： C08F20/10 , C07C45/52 , C07C45/78 , C07C45/86 , C07C51/235 , C07C51/252 , C07C67/05 , C08F20/06 , C07C57/04 , C07C47/22
摘要： A process for producing acrolein, comprising: a glycerin dehydration step of conducting dehydration reaction of glycerin to obtain an acrolein-containing gas; a partial-condensation step of cooling the acrolein-containing gas to condense a part of acrolein, water and a high-boiling substance contained in the acrolein-containing gas, thereby obtaining a purified gas and a condensate; and a separation step of separating the purified gas from the condensate; wherein a polymerization inhibitor is added to the acrolein-containing gas or the condensate in the partial-condensation step.
摘要翻译：一种制备丙烯醛的方法，包括：甘油脱水步骤，进行甘油的脱水反应以获得含丙烯醛的气体; 冷凝含有丙烯醛的气体以冷凝含有丙烯醛的气体中的一部分丙烯醛，水和高沸点物质的部分缩合步骤，从而获得纯化气体和冷凝物; 以及从所述冷凝物分离净化气体的分离步骤; 其中在部分缩合步骤中将聚合抑制剂加入到含丙烯醛的气体或冷凝物中。

8. 依法登记的发明

USH2211H Stabilization of fluorinated ketones 有权
标题翻译：氟化酮的稳定化
公开(公告)号：USH2211H
公开(公告)日：2008-03-04
申请号：US68777407
申请日：2007-03-19
申请人： HALOCARBON PROD CORP
发明人： PAVRI NEVILLE , GRAHAM DANNY , HARRIS MARK , MAZZELL PAUL
IPC分类号： C07C45/86
CPC分类号： C07C45/86 , C07C49/167
摘要： Fluorinated ketones, for example, 1,1,1-trifluoroacetone, can be stabilized against storage degradation by combining with a content of hexafluoroisopropanol (HFIP). Containers containing the stabilized mixture show prolonged storage times compared to containers containing the fluorinated ketones alone. The stabilized mixture can be used as a starting material for reactions requiring fluorinated ketones, for example, 1,1,1-trifluoroacetone, as a starting material.
摘要翻译：氟化酮，例如1,1,1-三氟丙酮，可通过与六氟异丙醇（HFIP）的组合结合来稳定防止储存降解。含有稳定化混合物的容器比单独含有氟化酮的容器显示延长的储存时间。稳定的混合物可以用作需要氟化酮的反应的原料，例如1,1,1-三氟丙酮作为起始原料。

9. 发明授权

US5874631A Method and composition to increase the life of Liquid hydroxy-and alkoxyalkyl ketones 失效
标题翻译：提高液体羟基和烷氧基烷基酮寿命的方法和组成
公开(公告)号：US5874631A
公开(公告)日：1999-02-23
申请号：US716599
申请日：1996-09-18
申请人： Karl-Heinz Ross , Ludwig Wambach , Harro Wache
发明人： Karl-Heinz Ross , Ludwig Wambach , Harro Wache
IPC分类号： C07C45/86 , C07C49/17 , C07C49/175
CPC分类号： C07C45/86
摘要： A method for increasing the shelf life of liquid hydroxy- and alkoxyalkyl ketones by adding from 0.0001 to 1% by weight of a base is described.
摘要翻译：描述了通过添加0.0001至1重量％的碱来提高液体羟基和烷氧基烷基酮的保质期的方法。

10. 发明授权

US5618520A Photostable filtering cosmetic composition containing a UV-A filter and a filtering polymer of the benzotriazole silcone type 失效
标题翻译：含有UV-A过滤器和苯并三唑硅酮型过滤聚合物的光稳定性过滤化妆品组合物
公开(公告)号：US5618520A
公开(公告)日：1997-04-08
申请号：US382310
申请日：1995-05-04
申请人： Isabelle Hansenne , Serge Forestier , Andre Deflandre
发明人： Isabelle Hansenne , Serge Forestier , Andre Deflandre
IPC分类号： A61K8/00 , A61K8/04 , A61K8/11 , A61K8/35 , A61K8/46 , A61K8/49 , A61K8/89 , A61K8/891 , A61K8/898 , A61Q1/00 , A61Q1/10 , A61Q5/00 , A61Q5/02 , A61Q5/10 , A61Q7/00 , A61Q17/04 , C07C45/86 , C07C49/82 , C07C49/84 , C08G77/00 , C08G77/04 , C08G77/26 , C08L83/08 , A61K7/42
CPC分类号： A61K8/898 , A61K8/35 , A61K8/496 , A61Q17/04 , A61K2800/52 , A61K2800/57 , Y10S514/938
摘要： A photostable, filtering cosmetic composition for protecting human epidermis and hair against UV rays comprises, in a cosmetically acceptable carrier having at least one fatty phase 0.5 to 4% by weight of 4-(tert.-butyl) 4'-methoxy dibenzoylmethane and 0.1 to 20% by weight of a filtering polymer of the benzotriazole silicone type containing at least one unit of formula (1), where R' is a C.sub.1 -C.sub.30 hydrocarbon group, a C.sub.1 -C.sub.8 halogenated hydrocarbon group or a trimethylsilyloxy group; a is 1 or 2; X=--A--Y where A is an aliphatic or aromatic bivalent hydrocarbon radical having at least 2 carbon atoms and optionally containing one or more oxygen atoms; Y is a 2-(2'-hydroxyphenyl)benzotriazole residue optionally containing one or more C.sub.1 -C.sub.8 alkyl, C.sub.2 -C.sub.8 alkenyl, halogen, alkoxy, carboxy, hydroxy or amino substituents, the weight ratio of the benzotriazole silicone to the 4-(tert.-butyl) 4'-methoxy dibenzoylmethane being between 1 and 10.
摘要翻译： PCT No.PCT / FR93 / 00886 Sec。 371日期：1995年5月4日 102（e）日期1995年5月4日PCT 1993年9月15日PCT公布。出版物WO94 / 06404 日期1994年3月31日一种用于保护人类表皮和头发免受紫外线影响的过敏化妆品组合物在具有至少一种脂肪相的化妆品可接受的载体中包含0.5至4重量％的4-（叔丁基）4' - 甲氧基二苯甲酰甲烷和0.1至20重量％的含有至少一个式（1）单元的苯并三唑硅氧烷型过滤聚合物，其中R'是C 1 -C 30烃基，C 1 -C 8卤代烃基或三甲基甲硅烷氧基 a是1或2; X = -A-Y其中A是具有至少2个碳原子并且任选地含有一个或多个氧原子的脂族或芳族二价烃基; Y是任选含有一个或多个C 1 -C 8烷基，C 2 -C 8烯基，卤素，烷氧基，羧基，羟基或氨基取代基的2-（2'-羟基苯基）苯并三唑残基，苯并三唑硅酮与4- （叔丁基）4'-甲氧基二苯甲酰甲烷在1和10之间。

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