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    • 2. 发明授权
    • Slurry removal process
    • 清除泥浆的过程
    • US4236896A
    • 1980-12-02
    • US876254
    • 1978-02-09
    • Alan J. MorrisTheodore A. Rado
    • Alan J. MorrisTheodore A. Rado
    • B01J3/02C10G1/00C10G1/04F17D1/16
    • B01J3/02C10G1/00C10G1/04Y10T137/0391Y10T137/0396
    • In a process for the removal and pressure reduction of a high pressure, high temperature slurry from a process vessel, the slurry is mixed with a make-up liquid in a temperature treatment vessel to form a diluted slurry, which is passed through a cooling apparatus, and a recycle portion of the diluted slurry is recycled to the temperature treatment vessel. Another portion of the cooled diluted slurry solution is flashed to a preselected reduced pressure through a pressure reducing valve, and this portion is passed to a stripping vessel for concentrating and producing a slurry product. In operation, plural slurry gravity settling vessels may be connected to a single heat treatment vessel, thereby effectuating slurry pressure reduction across a single pressure reducing valve.
    • 在从处理容器中除去和减压高压高温浆料的方法中,将浆料与补充液体在温度处理容器中混合,形成稀释的浆料,将其通过冷却装置 ,并将稀释的浆料的再循环部分再循环到温度处理容器中。 冷却的稀释浆液的另一部分通过减压阀被闪蒸至预选的减压,并将该部分送入汽提容器中以浓缩和生产浆液产物。 在操作中,多个浆料重力沉降容器可以连接到单个热处理容器,从而通过单个减压阀实现浆料压力降低。
    • 3. 发明授权
    • Method for processing gaseous effluent streams recovered from the vapor
phase oxidation of metal halides
    • 从金属卤化物的气相氧化中回收的气态流出物流的处理方法
    • US4578090A
    • 1986-03-25
    • US660875
    • 1984-10-15
    • Theodore A. Rado
    • Theodore A. Rado
    • B01D47/05C01B33/18C01G23/07C01G49/02
    • C01G49/02B01D47/05C01B33/183C01G23/075
    • In the manufacture of particulated metal oxides by the vapor phase oxidation of volatile metal halides, hot gaseous effluent streams are produced which, after separation of the desired particulated metal oxide therefrom, contain residual amounts of the particulated metal oxide as well as unreacted, volatile metal halide and halogen gas. The method of this invention provides for the recovery of these materials, individually, through a succession of contacting and separating steps utilizing a recycle stream of previously recovered, unreacted, liquid metal halide. Utilization of the recycle stream of metal halide provides for both evaporative cooling of the hot gaseous effluent stream to permit recovery of the residual particulated metal oxide therein and scrubbing of the resulting off-gas to recover the unreacted volatile metal halide therein as a liquid and provide a gas phase containing the by-product halogen gas. The recovered unreacted volatile metal halide liquid constitutes the recycle stream of liquid metal halide used in the process. The gas phase is subjected to a further scrubbing to separate and recover therefrom any remaining unreacted, volatile metal halide.
    • 在通过挥发性金属卤化物的气相氧化制造颗粒状金属氧化物时,产生热的气态流出物流,其中所需的颗粒状金属氧化物从其中分离后,含有残留量的微粒金属氧化物以及未反应的挥发性金属 卤化物和卤素气体。 本发明的方法通过使用先前回收的未反应的液态金属卤化物的再循环流通过一系列接触和分离步骤分别回收这些材料。 使用金属卤化物的再循环流提供热气态流出物流的蒸发冷却,以允许其中残留的微粒金属氧化物回收并洗涤所得到的废气以回收其中的未反应的挥发性金属卤化物作为液体,并提供 含有副产物卤素气体的气相。 回收的未反应的挥发性金属卤化物液体构成在该方法中使用的液态金属卤化物的再循环流。 对气相进行进一步的洗涤以分离并从其中回收剩余的未反应的挥发性金属卤化物。
    • 6. 发明授权
    • Process for the production of aluminum chloride and related products
    • 生产氯化铝及相关产品的工艺
    • US4283371A
    • 1981-08-11
    • US116302
    • 1980-01-28
    • Theodore A. Rado
    • Theodore A. Rado
    • C01F7/62
    • C01F7/62
    • A continuous process for recovering substantially pure aluminum chloride from chlorination products of aluminum ore. The chlorination products are contacted with a first selective solvent to dissolve a substantial portion of the aluminum chloride and some ferric chloride. The solvent is separated from the chlorides which then are treated to produce a ferric chloride-rich stream and an aluminum chloride-rich stream in which the aluminum chloride to ferric chloride ratio is higher than the ratio prior to solvent separation. The aluminum chloride-rich stream is contacted with a second solvent to dissolve any ferric chloride present and saturate the solution with aluminum chloride. Aluminum chloride in excess of that soluble in the second solvent separates as a substantially pure solid phase. The solution is separated from solid phase and recycled in process to recover additional aluminum chloride.
    • 用于从铝矿石的氯化产物回收基本上纯的氯化铝的连续方法。 将氯化产物与第一选择性溶剂接触以溶解大部分氯化铝和一些氯化铁。 将溶剂与氯化物分离,然后将其处理以产生富氯化铁流和富氯化铝流,其中氯化铝与氯化铁的比例高于溶剂分离前的比例。 将富含氯化铝的物流与第二溶剂接触以溶解所存在的氯化铁并用氯化铝使该溶液饱和。 超过可溶于第二溶剂的氯化铝作为基本上纯的固相分离。 将溶液与固相分离并在工艺中再循环以回收另外的氯化铝。
    • 10. 发明授权
    • Process for the production of synthetic rutile
    • 合成金红石的生产工艺
    • US4199552A
    • 1980-04-22
    • US910051
    • 1978-05-26
    • Theodore A. Rado
    • Theodore A. Rado
    • C22B34/12C01G23/04
    • C22B34/1227C22B34/1204Y02P10/23
    • An improved process for the production of synthetic rutile from ore containing titanium and iron, such as ilmenite ore, by a multi-step procedure employing controlled reduction, controlled oxidation and acid leaching. More specifically, the ilmenite ore first is reduced thermally such that substantially all of the iron (III) present has been converted to iron (II) and some metallic iron. The reduced ore then is oxidized with an oxidizing gas substantially free of elemental oxygen to convert the metallic iron to iron (II) without the substantial formation of iron (III). The oxidized ore then is leached to remove the iron (II) and calcined to produce synthetic rutile. The synthetic rutile so produced contains in excess of 92 percent titanium dioxide and less than 2 percent iron (III), by weight. Often, the synthetic rutile contains less than 1 percent total iron by weight.
    • 通过使用受控还原,受控氧化和酸浸的多步法,从含有钛和铁的矿石如钛铁矿生产合成金红石的改进方法。 更具体地,钛铁矿矿石首先被热降解,使得存在的铁(III)基本上全部已经转化为铁(II)和一些金属铁。 然后,还原的矿石用基本上不含元素氧的氧化气体氧化,以将金属铁转化成铁(II)而不大量形成铁(III)。 然后将氧化的矿石浸出以除去铁(II)并煅烧以产生合成金红石。 如此生产的合成金红石含有超过92%的二氧化钛和小于2%的铁(III)重量比。 通常,合成金红石含有少于1重量%的铁。