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    • 6. 发明授权
    • Method and device for separating polar from non-polar liquids using
membranes
    • 使用膜将极性与非极性液体分离的方法和装置
    • US4846977A
    • 1989-07-11
    • US921940
    • 1986-10-21
    • Robert DeVellisLawrence R. SchroederH. Hunter PaalmanCurtis M. TongTerrence L. CaskeyCharles W. Martin
    • Robert DeVellisLawrence R. SchroederH. Hunter PaalmanCurtis M. TongTerrence L. CaskeyCharles W. Martin
    • B01D61/14B01D61/24B01D63/02C10G31/11G01N1/10
    • B01D61/362B01D17/085B01D61/24B01D63/02B01D63/022B01D63/023B01D71/32B01D71/68C10G31/11
    • The invention is a method for separating one or more polar liquids from one or more non-polar liquids which comprises the following steps. First, contacting a mixture comprising one or more polar liquids and one or more non-polar liquids with one side of a membrane comprising a polymer of a perfluorosulfonic acid, or metal salt thereof, which is adapted for selective permeation of the polar liquids over the non-polar liquids under conditions such that the polar liquids selectively permeate through the membrane. Second, passing a desiccant fluid by, pulling a vacuum on, or a combination thereof, the other side of the membrane, under conditions such that the polar liquids which have permeated through the membrane are carried away from the membrane. Third, removing the fluid desiccant containing the permeated polar liquids or the permeated polar liquids wherein a vacuum is used, from the vicinity of the membrane. Fourth, removing the non-polar liquids from the vicinity of the membrane.Another aspect of this invention is a novel hollow fiber membrane device useful for performing a preferred mode of the above-described method.This method allows the removal of one or more polar liquids which are dissolved in or entrained in one or more non-polar liquids in a continuous manner which no shoft-term changeout required.
    • 本发明是从一种或多种非极性液体中分离一种或多种极性液体的方法,包括以下步骤。 首先,将包含一种或多种极性液体和一种或多种非极性液体的混合物与包含全氟磺酸的聚合物或其金属盐的膜的一侧接触,其适于极性液体在 非极性液体在极性液体选择性渗透膜的条件下。 第二,在使透过膜的极性液体从膜上移出的条件下,通过干燥剂流体,将真空或其组合通过膜的另一侧。 第三,从膜附近去除含有渗透的极性液体或其中使用真空的透过极性液体的流体干燥剂。 第四,从膜附近去除非极性液体。 本发明的另一方面是用于进行上述方法的优选方式的新颖的中空纤维膜装置。 该方法允许以连续的方式去除溶解在或夹带在一种或多种非极性液体中的一种或多种极性液体,这不需要任何短期改变。
    • 7. 发明授权
    • Assembly of water wet hollow fibers and a tubesheet derived from a
diglycidyl ether of a dihydroxy benzene
    • 水湿中空纤维的组装和源自二羟基苯的二缩水甘油醚的管片
    • US4842910A
    • 1989-06-27
    • US185172
    • 1988-04-22
    • Terrence L. Caskey
    • Terrence L. Caskey
    • B01D63/02C08G59/24
    • C08G59/245B01D63/023Y10T428/2911Y10T428/2938Y10T428/2975
    • The invention is a hollow fiber and tubesheet assembly which comprises(A) a non-random fiber bundle comprising water wet cellulose ester hollow fibers wherein the fiber is water wet when the assembly is fabricated, wherein any of said fibers processed using plasticizers have been leached to remove the plasticizer; and(B) a tubesheet which comprises the reaction product of:(i) an epoxy resin comprising about(a) between about 10 and 100 percent by weight of a diglycidyl ether of a dihydroxy benzene;(b) between about 0 and about 90 percent by weight of a polyglycidyl ether of a polyhydric phenol which is not a diglycidyl ether of dihydroxy benzene;(ii) a curing agent in sufficient amount to cure the epoxy resin composition; wherein a portion of the hollow fibers are embedded in the tubesheet.
    • 本发明是一种中空纤维和管板组件,其包括(A)包含水湿纤维素酯中空纤维的非随机纤维束,其中当制造组件时纤维是水湿的,其中使用增塑剂处理的任何所述纤维已经被浸出 去除增塑剂; 和(B)管板,其包含以下反应产物:(i)包含约(a)约10至100重量%的二羟基苯的二缩水甘油醚的环氧树脂; (b)约0至约90重量%的不是二羟基苯的二缩水甘油醚的多元酚的聚缩水甘油醚; (ii)足够固化环氧树脂组合物的固化剂; 其中一部分中空纤维嵌入管板中。