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    • 2. 发明授权
    • Method and device for separating polar from non-polar liquids using
membranes
    • 使用膜将极性与非极性液体分离的方法和装置
    • US4846977A
    • 1989-07-11
    • US921940
    • 1986-10-21
    • Robert DeVellisLawrence R. SchroederH. Hunter PaalmanCurtis M. TongTerrence L. CaskeyCharles W. Martin
    • Robert DeVellisLawrence R. SchroederH. Hunter PaalmanCurtis M. TongTerrence L. CaskeyCharles W. Martin
    • B01D61/14B01D61/24B01D63/02C10G31/11G01N1/10
    • B01D61/362B01D17/085B01D61/24B01D63/02B01D63/022B01D63/023B01D71/32B01D71/68C10G31/11
    • The invention is a method for separating one or more polar liquids from one or more non-polar liquids which comprises the following steps. First, contacting a mixture comprising one or more polar liquids and one or more non-polar liquids with one side of a membrane comprising a polymer of a perfluorosulfonic acid, or metal salt thereof, which is adapted for selective permeation of the polar liquids over the non-polar liquids under conditions such that the polar liquids selectively permeate through the membrane. Second, passing a desiccant fluid by, pulling a vacuum on, or a combination thereof, the other side of the membrane, under conditions such that the polar liquids which have permeated through the membrane are carried away from the membrane. Third, removing the fluid desiccant containing the permeated polar liquids or the permeated polar liquids wherein a vacuum is used, from the vicinity of the membrane. Fourth, removing the non-polar liquids from the vicinity of the membrane.Another aspect of this invention is a novel hollow fiber membrane device useful for performing a preferred mode of the above-described method.This method allows the removal of one or more polar liquids which are dissolved in or entrained in one or more non-polar liquids in a continuous manner which no shoft-term changeout required.
    • 本发明是从一种或多种非极性液体中分离一种或多种极性液体的方法,包括以下步骤。 首先,将包含一种或多种极性液体和一种或多种非极性液体的混合物与包含全氟磺酸的聚合物或其金属盐的膜的一侧接触,其适于极性液体在 非极性液体在极性液体选择性渗透膜的条件下。 第二,在使透过膜的极性液体从膜上移出的条件下,通过干燥剂流体,将真空或其组合通过膜的另一侧。 第三,从膜附近去除含有渗透的极性液体或其中使用真空的透过极性液体的流体干燥剂。 第四,从膜附近去除非极性液体。 本发明的另一方面是用于进行上述方法的优选方式的新颖的中空纤维膜装置。 该方法允许以连续的方式去除溶解在或夹带在一种或多种非极性液体中的一种或多种极性液体,这不需要任何短期改变。