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    • 2. 发明授权
    • Method for production of rare-earth element/cobalt type magnetic powder
for resin magnet
    • 用于树脂磁体的稀土元素/钴型磁粉的制造方法
    • US4689073A
    • 1987-08-25
    • US834420
    • 1986-02-28
    • Tatsuo NateKoichi OkaTakehiko Sato
    • Tatsuo NateKoichi OkaTakehiko Sato
    • H01F1/055H01F1/06H01F1/33
    • H01F1/06H01F1/0553
    • A rare earth-element/cobalt type magnetic powder which possesses outstanding magnetic properties and which is useful for making a resin magnet is produced by a method which comprises thermally reducing a mixture consisting of oxide of samarium, oxide of praseodymium, optionally oxide of neodymium, and cobalt powder, thereby causing diffusion of consequently produced samarium, praseodymium, and/or neodymium in the cobalt powder, subjecting the resultant reaction product to a heat-treatment involving standing at 600.degree. to 900.degree. C. for 30 minutes to 5 hours and subsequent quenching from this temperature at a rate of not less than 10.degree. C./minute, adding the product of the heat-treatment to water, thereby converting the product into a slurry, treating the slurry with water and an aqueous acid solution, and comminuting the resulting powder into particles of an average diameter of 3 to 10 .mu.m thereby obtaining a magnetic powder having a composition represented by Sm.sub.1-x Pr.sub.x Co.sub.z or Sm.sub.1-x Pr.sub.x-y Nd.sub.y Co.sub.z (wherein x, y, and z satisfy the relations 0.05.ltoreq.x.ltoreq.0.40, 0.01.ltoreq.y.ltoreq.0.39, 0.01.ltoreq.x-y.ltoreq.0.39 and 4.7.ltoreq.z.ltoreq.5.3).
    • 具有突出的磁特性并且可用于制备树脂磁体的稀土元素/钴型磁性粉末是通过以下方法制造的:包括热还原由钐氧化物,镨氧化物,任选的钕氧化物组成的混合物, 钴钴粉末,由此引起钴粉末中所产生的钐,镨和/或钕的扩散,使得到的反应产物进行热处理,包括在600-900℃静置30分钟至5小时, 随后从该温度以不低于10℃/分钟的速度淬火,将热处理产物加入水中,从而将产物转化为浆液,用水和酸水溶液处理浆料,以及 将所得粉末粉碎成平均粒径为3〜10μm的颗粒,得到具有由Sm1-xPrxCoz或Sm1-xPrx表示的成分的磁性粉末 -yNdyCoz(其中x,y和z满足0.05≤x≤0.40,0.01≤y≤0.39,0.01≤x≤0.39和4.7≤x≤0.33, = 5.3)。