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1. 发明授权

US5432208A Photocuring adhesive containing an oligo siloxanyl di(meth)acrylate 失效
标题翻译：含有二（甲基）丙烯酸二硅氧烷基硅氧烷的光固化粘合剂
公开(公告)号：US5432208A
公开(公告)日：1995-07-11
申请号：US137082
申请日：1993-12-14
申请人： Eiichi Masuhara , Shigeo Komiya , Takeyuki Sawamoto , Yumiko Satou
发明人： Eiichi Masuhara , Shigeo Komiya , Takeyuki Sawamoto , Yumiko Satou
IPC分类号： B32B3/10 , C08F299/08 , C09J4/00 , C09J4/02 , C09J4/06 , C09J183/06 , D04H1/44 , C09J183/07 , C09J133/08 , C09J133/10
CPC分类号： C09J4/00 , C09J4/06
摘要： This invention relates to a photocuring adhesive characterized in that a photoinitiator is added to a monomer composition comprising 20 to 50 wt % of the oligosiloxanyl di(meth)acrylate represented by the structural formula (1) shown below, 20 to 60 wt % of a hydrophobic mono (meth)acrylate having a hydrocarbon group containing no less than six carbon atoms in a side chain, and 1 to 80% of a hydrophilic monomer capable of undergoing free radical polymerization: ##STR1## R.sub.1 and R.sub.2 both being either hydrogen or methyl, m.sub.1 and m.sub.2 being an integer in the range 2 to 5, and n being an integer in the range 5 to 30.
摘要翻译： PCT No.PCT / JP92 / 00203 Sec。 371日期1993年12月14日第 102（e）日期1993年12月14日PCT提交1992年2月25日PCT公布。公开号WO93 / 17078 光固化粘合剂技术领域本发明涉及一种光固化粘合剂，其特征在于，将光引发剂加入到由下述结构式（1）表示的20〜50重量％的由下述结构式（1）表示的二（甲基）丙烯酸寡硅氧烷基酯的单体组合物中， 20〜60重量％的侧链中具有不少于6个碳原子的烃基的疏水性单（甲基）丙烯酸酯和1〜80％能够进行自由基聚合的亲水性单体：（1））R1和R2均为氢或甲基，m1和m2为2〜5的整数，n为5〜30的整数。

2. 发明授权

US5135686A Method and apparatus for continuous hardening of light-curing resins 失效
标题翻译：光固化树脂连续硬化的方法和装置
公开(公告)号：US5135686A
公开(公告)日：1992-08-04
申请号：US459161
申请日：1989-12-29
申请人： Eiichi Masuhara , Shigeo Komiya , Takeyuki Sawamoto , Shusuke Kimura , Koji Ozeki , Kensuke Nakajima , Kiyomi Sanbonmatsu , Noboru Nishiyama
发明人： Eiichi Masuhara , Shigeo Komiya , Takeyuki Sawamoto , Shusuke Kimura , Koji Ozeki , Kensuke Nakajima , Kiyomi Sanbonmatsu , Noboru Nishiyama
IPC分类号： A61C13/00 , A61C13/15 , B01J19/08 , B05C9/12 , B29C35/02 , B29C35/08 , B29L31/48 , H01L21/30
CPC分类号： A61C19/003 , B29C35/0277 , B29C35/08 , B29C2035/0822 , B29C2035/0833 , B29L2011/0016
摘要： A method to continuousky harden light-curable resins, by irradiating at least one shaped article made of a light-curable resin by continuously moving the article past a multiplicity of light sources while changing the flux of the irradiated light in multiple steps corresponding to the moving positions of the object and an apparatus to accomplish this method including means to continuously move the article relative to the multiple irradiation sources and means to adjust the flux density in multiple steps corresponding to the moving positions of the article. Specifically, the flux density of the light irradiated on the moving article is changed stepwide depending upon the position and the location of the article and the polymerization speed of the article and the hardening depth can be controlled in relation to its position and time.

3. 发明授权

US5008354A Contact lens 失效
标题翻译：隐形眼镜
公开(公告)号：US5008354A
公开(公告)日：1991-04-16
申请号：US343389
申请日：1989-04-26
申请人： Takeyuki Sawamoto , Masashi Nomura , Niro Tarumi
发明人： Takeyuki Sawamoto , Masashi Nomura , Niro Tarumi
IPC分类号： G02C7/04 , C08F20/28 , C08F290/06 , G02B1/04
CPC分类号： C08F20/28 , G02B1/043
摘要： The contact lens of the present invention consisting of a polymer comprising, as an essential component, at least one fluorine-containing monomer represented by the general formula ##STR1## (R.sub.1 and R.sub.2 are independently H or CH.sub.3 and may be the same or different, l is an integer of 1-5, m is an integer of 1-2, n is an integer of 4-10, p is an integer of 8 or more, q is an integer of 0 or more, and p+q=2n+1), has high transparency, improved oxygen permeability, flexibility, hydrophilicity and no water absorbability.

4. 发明授权

US4892402A Method for making contact lens hydrophilic 失效
标题翻译：使隐形眼镜亲水的方法
公开(公告)号：US4892402A
公开(公告)日：1990-01-09
申请号：US187472
申请日：1988-04-28
申请人： Takeyuki Sawamoto , Koichi Ishida , Niro Tarumi , Tetsuro Izumitani
发明人： Takeyuki Sawamoto , Koichi Ishida , Niro Tarumi , Tetsuro Izumitani
IPC分类号： G02C7/04 , B29D11/00 , G02B1/04
CPC分类号： B29D11/00038 , G02B1/043
摘要： A contact lens is made hydrophilic by contacting the lens with a treating solution containing a hydrophilic monomer, at least one photosensitizer selected from aromatic ketones or quinones, and a sovlent, and thereafter irradiating the contact lens with ultraviolet light.
摘要翻译：通过使透镜与含有亲水性单体，至少一种选自芳族酮或醌的光敏剂和溶剂的处理溶液接触而形成亲水性透镜，然后用紫外线照射隐形眼镜。

5. 发明授权

US4625009A High-hydration contact lens 失效
标题翻译：高水合隐形眼镜
公开(公告)号：US4625009A
公开(公告)日：1986-11-25
申请号：US845936
申请日：1986-03-31
申请人： Tetsuro Izumitani , Niro Tarumi , Shigeo Komiya , Takeyuki Sawamoto
发明人： Tetsuro Izumitani , Niro Tarumi , Shigeo Komiya , Takeyuki Sawamoto
IPC分类号： C08F20/10 , C08F20/52 , C08F220/00 , C08F220/10 , C08F220/12 , C08F220/18 , C08F220/28 , C08F220/54 , C08F220/56 , C08F290/00 , C08F299/02 , G02B1/04 , G02C7/04 , C08F20/54
CPC分类号： C08F220/54 , G02B1/043
摘要： A high-hydration contact lens having a high strength is disclosed which is made of a copolymer composed of (i) 40 to 90 wt. % of N,N-dimethyl acrylamide, (ii) 5 to 50 wt. % of a hydrophobic monomer, (iii) 0.1 to 10 wt. % of an unsaturated carboxylic acid having one ethylenically unsaturated bond, and (iv) 0.01 to 5.0 wt. % of a crosslinking agent, wherein the hydrophobic monomer is selected from the group consisting of phenyl acrylates, benzyl acrylates, phenyl methacrylates, benzyl methacrylates, alkyl acrylates, alkyl methacrylates, cyclohexyl acrylates and cyclohexyl methacrylates, and the crosslinking agent is selected from those represented by formula (I), (II), or (III) ##STR1## wherein X represents a hydrogen atom or a methyl group, a is an integer of 2 to 23, and b and c each is an integer of 2 to 14.
摘要翻译：公开了具有高强度的高水合隐形眼镜，其由以下组成的共聚物制成：（i）40〜90重量％％的N，N-二甲基丙烯酰胺，（ii）5〜50wt。％的疏水性单体，（iii）0.1〜10重量％％的具有一个烯属不饱和键的不饱和羧酸，和（iv）0.01〜5.0重量％％的交联剂，其中所述疏水性单体选自丙烯酸苯酯，丙烯酸苄酯，甲基丙烯酸苯酯，甲基丙烯酸苄酯，丙烯酸烷基酯，甲基丙烯酸烷基酯，丙烯酸环己酯和甲基丙烯酸环己酯，所述交联剂选自（II）其中X表示氢原子或甲基，a是2〜2的整数， 23，b和c分别为2〜14的整数。

6. 发明授权

US5883147A Photopolymerizable adhesive composition 失效
标题翻译：可光聚合粘合剂组合物
公开(公告)号：US5883147A
公开(公告)日：1999-03-16
申请号：US476368
申请日：1995-06-07
申请人： Eiichi Masuhara , Shigeo Komiya , Takeyuki Sawamoto , Satoko Maeda
发明人： Eiichi Masuhara , Shigeo Komiya , Takeyuki Sawamoto , Satoko Maeda
IPC分类号： C08F2/50 , C09J4/00 , C09J4/06 , C09J4/02
CPC分类号： C09J4/00 , C09J4/06
摘要： A photopolymerizable adhesive consisting of Compound (1) which contains at least one (meth)acryloxy group as a polymerizing group in its molecule, and other structures constructed from the group(s) selected from the group consisting of alkyl group, alkyloxy group, polyalkoxy group, siloxanyl group and the substituted group thereof substituted by fluorine, hydroxy or alkoxy group; Compound (2) selected from (meth)acrylic acids, hydroxyalkyl (meth)acrylates, (meth)acryloxyalkyl succinic acids, trialkoxyvinyl silanes and .gamma.-(meth)acryloxyalkyl trialkoxy silanes; and Compound (3) selected from hydroxyacetophenones, acetophenones, glyoxy esters and camphorquinones, wherein said adhesive comprises 3 to 60 wt % of the compound (2), and 0.1 to 2 wt % of the Compound (3).
摘要翻译：由在分子中含有至少一个（甲基）丙烯酰氧基作为聚合基团的化合物（1）和由选自烷基，烷氧基，聚烷氧基中的基团构成的其它结构的光聚合性粘合剂基团，硅氧烷基和被氟，羟基或烷氧基取代的取代基; 选自（甲基）丙烯酸，（甲基）丙烯酸羟烷基酯，（甲基）丙烯酰氧基烷基琥珀酸，三烷氧基乙烯基硅烷和γ-（甲基）丙烯酰氧基烷基三烷氧基硅烷的化合物（2）和选自羟基苯乙酮，苯乙酮，乙二醇酯和樟脑醌的化合物（3），其中所述粘合剂包含3至60重量％的化合物（2）和0.1至2重量％的化合物（3）。

7. 发明授权

US5607985A Photopolymerization initiator for visible light-polymerizing adhesive 失效
标题翻译：用于可见光聚合粘合剂的光聚合引发剂
公开(公告)号：US5607985A
公开(公告)日：1997-03-04
申请号：US290867
申请日：1994-10-04
申请人： Eiichi Masuhara , Shigeo Komiya , Takeyuki Sawamoto , Yumiko Satou
发明人： Eiichi Masuhara , Shigeo Komiya , Takeyuki Sawamoto , Yumiko Satou
IPC分类号： C08F2/00 , C08F2/50 , C09J4/00 , C09J11/00
CPC分类号： C08F2/50 , C09J4/00 , F02B2275/18
摘要： Photopolymerization initiator for the visible light-polymerizing adhesives; and the visible light-polymerizing adhesives comprising the photopolymerization initiator, an aliphatic tertiary amine and a radical polymerizing monomer. The visible light-polymerizing adhesive of the invention has good transparency without coloring after photopolymerization as well as good adhering activity. It also has colorless, good transparency after photopolymerization and good adhering activity in an UV irradiation test, as well as excellent light resistance showing very little color change and deterioration in an UV irradiation test. The visible light-polymerizing adhesive of the invention is also excellent in photopolymerizing activity. Furthermore, the visible light-polymerizing adhesive of the invention has photopolymerizing activity not only to visible light but also to near-UV. It hardly has problems of such decrease in transparency caused by both kinds of lights as coloring and color change.
摘要翻译： PCT No.PCT / JP92 / 01669 Sec。 371日期：1994年10月4日 102（e）日期1994年10月4日PCT 1992年12月21日PCT PCT。出版物WO94 / 14913 日期1994年7月7日可见光聚合粘合剂的光聚合引发剂; 以及包含光聚合引发剂，脂族叔胺和自由基聚合单体的可见光聚合粘合剂。本发明的可见光聚合粘合剂在光聚合之后具有良好的透明性而不着色，并且具有良好的粘附活性。在UV光照射试验中，光聚合后的透明性也好，粘着性好，耐光性优异，紫外线照射试验变差。本发明的可见光聚合粘合剂的光聚合活性也优异。此外，本发明的可见光聚合粘合剂不仅对可见光而且对近紫外光具有光聚合活性。几乎不存在作为着色和颜色变化的两种灯的透明度降低的问题。

8. 发明授权

US5308886A Photosetting resin for making strong, tough resin articles 失效
标题翻译：用于制造强韧树脂制品的树脂树脂
公开(公告)号：US5308886A
公开(公告)日：1994-05-03
申请号：US820625
申请日：1992-01-28
申请人： Eiichi Masuhara , Shigeo Komiya , Takeyuki Sawamoto
发明人： Eiichi Masuhara , Shigeo Komiya , Takeyuki Sawamoto
IPC分类号： A61K6/083 , C08F2/44 , C08F2/46 , C08F2/48 , C08F20/10 , C08F220/10 , C08F220/18 , C08F220/30 , C08F290/00 , C08F299/02 , G02B1/04 , C08F220/26 , C08K3/22
CPC分类号： C08F220/30 , A61K6/083 , G02B1/04
摘要： A photosetting resin comprising a liquid monomer composition and a photopolymerization initiator, the monomer composition containing a compound represented by the following formula (1) and a compound represented by the following formula (2) in a weight ratio within the range from 97:3 to 50:50: ##STR1## (wherein R.sub.1 is H or CH.sub.3, and 0.ltoreq.m.sub.1 +m.sub.2 .ltoreq.4) ##STR2## (wherein R.sub.2 is H or CH.sub.3, and 5.ltoreq.n.sub.1 +n.sub.2 .ltoreq.12).This photosetting resin can provide a cured resin which is excellent in both strength and toughness.
摘要翻译： PCT No.PCT / JP91 / 00451 Sec。 371日期1992年1月28日 102（e）日期1992年1月28日PCT 1991年4月19日PCT PCT。出版物WO91 / 16364 日期：1991年10月31日。一种含有液体单体组合物和光聚合引发剂的光固化树脂，所述单体组合物含有下式（1）表示的化合物和下式（2）表示的化合物，范围从97：3到50:50：（其中R1是H或CH3，0 ）（其中R2是H或 CH3和5

9. 发明授权

US5147396A Intraocular lens 失效
标题翻译：内窥镜
公开(公告)号：US5147396A
公开(公告)日：1992-09-15
申请号：US327701
申请日：1989-03-23
申请人： Mayumi Kageyama , Takeyuki Sawamoto , Niro Tarumi , Hiroshi Sakai
发明人： Mayumi Kageyama , Takeyuki Sawamoto , Niro Tarumi , Hiroshi Sakai
IPC分类号： A61L27/00 , A61L27/18 , A61L27/50
CPC分类号： A61L27/50 , A61F2/16 , A61L27/18 , A61F2002/1681 , A61L2430/16
摘要： An intraocular lens whose optic or optic and haptic are composed of a substantially soft polymer obtained by curing a composition comprising:(a) a dimethylsiloxane-phenylsiloxane copolymer having a vinyl group at each of the both terminals of the molecular chain,(b) a diorganopolysiloxane having at least three hydrosilyl groups in the molecule, and(c) an U.V. absorber.The intraocular lens obtained above has good intraocular stability, excellent biocompatibility, high optical properties and an U.V. absorbability closer to that of the human lens.By further incorporting a filler as the component (d), the intraocular lens has improved mechanical properties and higher intraocular stability.

10. 发明授权

US5135685A Method and apparatus for continuous hardening of visible light-curing resins 失效
标题翻译：可见光固化树脂连续硬化的方法和装置
公开(公告)号：US5135685A
公开(公告)日：1992-08-04
申请号：US459159
申请日：1989-12-29
申请人： Eiichi Masuhara , Shigeo Komiya , Takeyuki Sawamoto , Shusuke Kimura , Koji Ozeki , Kensuke Nakajima , Kiyomi Sanbonmatsu , Noboru Nishiyama
发明人： Eiichi Masuhara , Shigeo Komiya , Takeyuki Sawamoto , Shusuke Kimura , Koji Ozeki , Kensuke Nakajima , Kiyomi Sanbonmatsu , Noboru Nishiyama
IPC分类号： A61C13/15 , A61K6/083 , B01J19/12 , B29C35/02 , B29C35/08 , B29C35/16 , B29L31/48 , C08F2/48
CPC分类号： A61K6/083 , A61C19/003 , B01J19/122 , B29C35/0288 , B29C35/08 , C08F2/48 , B29C2035/0833 , B29C2035/1658 , B29L2011/0016
摘要： A method and apparatus to continuously harden articles made of visible light-curable resins, including continuously moving the articles to be hardened relative to a multiplicity of sources of visible light which are independently controllable to be able to vary the radiation to which the articles is exposed during its passage while independently controlling the temperature at which this takes place; and apparatus to accomplish this such that a large number of the objects to be irradiated passing through the hardening apparatus have the same exposure history to the visible light and to heating or cooling respectively. As the result, there is substantially no variation in the physical properties of these photo-polymerized products.

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