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    • 6. 发明授权
    • Process for the recovery of alkylation catalyst
    • 回收烷基化催化剂的方法
    • US5618769A
    • 1997-04-08
    • US400859
    • 1995-03-08
    • Sven I. Hommeltoft
    • Sven I. Hommeltoft
    • B01J31/40C07C2/54B01J38/60B01J38/66
    • B01J31/0225B01J31/0224B01J31/40C07C2/54B01J2231/4205B01J31/0239C07C2531/025Y02P20/584
    • Process for the recovery of spent fluorinated sulfonic catalyst from acid soluble oil (ASO) being formed during alkylation of hydrocarbons in the presence of the acid catalyst. The process includeswashing the ASO with water and recovering an aqueous solution of the acid catalyst,neutralizing the acid in the aqueous solution by adding to the solution a basic compound being selected from the group of amino compounds, ammonia and ammonium salts, thereby, forming ammonium salts of the acid catalyst with a melting point at which the obtained acid catalyst salt in a subsequent concentration and drying step is in the form of a melt,drying the melt, and finallyrecovering the acid catalyst by protonization of the dried melt with sulfuric acid and distilling off the recovered acid catalyst from the sulfuric acid.
    • 在酸催化剂存在下,在烃的烷基化过程中形成的酸溶性油(ASO)中回收乏氟氟磺酸催化剂的方法。 该方法包括用水洗涤ASO并回收酸催化剂的水溶液,通过向该溶液中加入选自氨基化合物,氨和铵盐的碱性化合物,中和水溶液中的酸,从而形成 具有熔点的酸催化剂的铵盐,其中所获得的酸催化剂盐在随后的浓缩和干燥步骤中是熔体形式,干燥熔体,最后通过硫酸质子化干燥的熔体回收酸催化剂 酸并从硫酸中蒸馏出回收的酸催化剂。