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1. 发明授权

US09623399B2 Method of surface modification of alumina 有权
公开(公告)号：US09623399B2
公开(公告)日：2017-04-18
申请号：US14476762
申请日：2014-09-04
申请人： Sunshine Kaidi New Energy Group Co., Ltd.
发明人： Shenke Zheng , Dechen Song , Xiaodong Zhan
IPC分类号： B01D53/86 , H01B1/12 , B01J21/04 , B01J35/02 , B01J35/10 , C01F7/02
CPC分类号： B01J21/04 , B01J35/023 , B01J35/1014 , B01J35/1038 , B01J35/1042 , B01J35/1061 , C01F7/021 , C01P2004/61 , C01P2006/12 , C01P2006/14 , C01P2006/16 , C01P2006/90
摘要： A method of surface modification of an alumina carrier. The method includes: 1) dissolving a soluble kazoe in deionized water to yield a kazoe aqueous solution; 2) submerging an alumina carrier in the kazoe aqueous solution and drying the alumina carrier in a vacuum environment; 3) placing the dried alumina carrier in a reactor, adding silicon tetrachloride and Grignard reagent dropwise to the reactor, sealing the reactor and heating it to a constant temperature, and maintaining the constant temperature for between 3 and 18 hours, where a volume ratio of the added silicon tetrachloride and the alumina carrier is between 0.5:1 and 5:1, the constant temperature is controlled to be between 160 and 350° C.; and 4) cooling the reactor, filtering, washing, and drying the alumina carrier in the vacuum environment.

2. 发明授权

US09005555B2 Method for preparing solid ruthenium nitrosyl nitrate 有权
标题翻译：固体硝基硝酸硝基钌的制备方法
公开(公告)号：US09005555B2
公开(公告)日：2015-04-14
申请号：US14475547
申请日：2014-09-02
申请人： Sunshine Kaidi New Energy Group Co., Ltd.
发明人： Li Xu , Bo Lai , Dechen Song , Qianqian Liu , Yiming Han
IPC分类号： C01G55/00 , C22B3/00
CPC分类号： C22B11/048 , C01G55/00 , C01P2006/80 , C22B1/005 , C22B7/009 , Y02P10/214 , Y02P10/234
摘要： A method for preparing solid ruthenium nitrosyl nitrate, including: 1) drying a ruthenium-containing spent catalyst, and calcining the spent catalyst, and cooling to room temperature, whereby yielding a ruthenium-containing solid; 2) grinding the ruthenium-containing solid to yield a powder, introducing the powder to a fluidized bed reactor, aerating the fluidized bed reactor with nitrogen or an inert gas, charging hydrogen, whereby yielding ruthenium metal; 3) contacting a mixed gas of ozone and air with the ruthenium metal, whereby yielding gaseous ruthenium tetroxide; 4) introducing the gaseous ruthenium tetroxide into a three-stage absorption plant, whereby yielding an acid solution including ruthenium nitrate; 5) adding a solid of sodium nitrite to the acid solution, stirring, and heating a resulting solution, whereby yielding a solution of ruthenium nitrosyl nitrate; and 6) extracting the solution of ruthenium nitrosyl nitrate with anhydrous ether.
摘要翻译：一种制备固体硝酸亚硝基硝酸盐的方法，包括：1）干燥含钌废废催化剂，煅烧废催化剂，冷却至室温，由此得到含钌固体; 2）研磨含钌固体产生粉末，将粉末引入流化床反应器，用氮气或惰性气体充气流化床反应器，加入氢气，从而产生钌金属; 3）将臭氧和空气的混合气体与钌金属接触，从而产生四氧化四钌; 4）将气态四氧化钌引入三级吸收装置，从而产生包含硝酸钌的酸溶液; 5）向酸溶液中加入亚硝酸钠固体，搅拌并加热所得溶液，由此得到硝酸亚硝基硝酸钌溶液; 和6）用无水乙醚萃取硝酸亚硝基硝酸钌溶液。

3. 发明申请

US20140250931A1 SEASONAL THERMAL ENERGY STORAGE SYSTEM 有权
标题翻译：季节热能储存系统
公开(公告)号：US20140250931A1
公开(公告)日：2014-09-11
申请号：US14285666
申请日：2014-05-23
申请人： SUNSHINE KAIDI NEW ENERGY GROUP CO., LTD
发明人： Yilong CHEN , Shuchuan HU
IPC分类号： F25B27/00 , F24J2/34
CPC分类号： F25B27/007 , F24D11/003 , F24F5/0017 , F24F2005/0025 , F24S60/30 , F25B15/06 , F25B30/04 , Y02A30/272 , Y02A30/277 , Y02B10/20 , Y02B10/24 , Y02B30/62 , Y02E60/147 , Y02E70/30
摘要： A seasonal thermal energy storage system for heat supply and removal, including an energy-storage device, a solar collector, a refrigerating unit, and a water supply device in closed-loop connection to a user terminal. The energy-storage device includes at least a heat source storage pond and a cold source storage pond. The heat source storage pond and the cold source storage pond are connected to water source via first water pumps. The water supply device includes a hot water supply pool connected to the heat source storage pond and a cold water supply pool connected to the cold source storage pond. The solar collector is connected to the heat source storage pond and the hot water supply pool via second water pumps. The refrigerating unit is connected to the hot water supply pool and the cold water supply pool via third water pumps.
摘要翻译：一种用于供热和排除的季节性热能储存系统，包括能量存储装置，太阳能收集器，制冷单元和与用户终端闭环连接的供水装置。储能装置至少包括热源储存池和冷源储存池。热源蓄水池和冷源蓄水池通过第一台水泵连接到水源。供水装置包括连接到热源储存池的热水供应池和连接到冷源储存池的冷水供应池。太阳能集热器通过第二台水泵连接到热源蓄水池和热水供水池。制冷机组通过第三台水泵连接到热水供应池和冷水供水池。

4. 发明授权

US09961840B2 Method and device for supplying heat energy and carbon dioxide from exhaust gas for vegetable and/or algae production 有权
公开(公告)号：US09961840B2
公开(公告)日：2018-05-08
申请号：US14040678
申请日：2013-09-28
申请人： Sunshine Kaidi New Energy Group Co., Ltd.
发明人： Yilong Chen , Shuchuan Hu , Yanfeng Zhang
IPC分类号： A01G7/02 , A01G33/00 , C12N1/12 , F28F1/00
CPC分类号： A01G7/02 , A01G33/00 , C12N1/12 , F28F1/00 , Y02A40/88 , Y02P60/247
摘要： A method for supplying heat energy and carbon dioxide for vegetables and/or algae production using exhaust gas. The method includes: 1) introducing the exhaust gas to a primary heat exchanger to conduct a first indirect heat exchange between the exhaust gas and air from a vegetable greenhouse and/or an algae culturing house, thereby providing hot air for the vegetable greenhouse and/or the algae culturing house; 2) introducing part of the exhaust gas after the first indirect heat exchange to a secondary heat exchanger to conduct a second indirect heat exchange between the exhaust gas and outdoor air; 3) introducing the exhaust gas to a CO2 pressure swing adsorption device, separating and pumping carbon dioxide to a carbon dioxide storage tank for storage; and 4) supplying the carbon dioxide to the vegetable greenhouse and/or a carbon-absorption tank of the algae culturing house.

5. 发明授权

US09822319B2 Method and system for gasification of biomass 有权
公开(公告)号：US09822319B2
公开(公告)日：2017-11-21
申请号：US15011644
申请日：2016-01-31
申请人： SUNSHINE KAIDI NEW ENERGY GROUP CO., LTD.
发明人： Yilong Chen , Yanfeng Zhang , Hongming Tang
IPC分类号： B01J7/00 , C10J3/84 , C10J3/20 , C10K1/06 , C10J3/46 , C10K1/00 , C10K1/02
CPC分类号： C10J3/84 , C10J3/20 , C10J3/46 , C10J2200/152 , C10J2300/0906 , C10J2300/0916 , C10J2300/0973 , C10J2300/0976 , C10J2300/1238 , C10J2300/1246 , C10J2300/1653 , C10J2300/1659 , C10J2300/1665 , C10J2300/1693 , C10J2300/1853 , C10J2300/1884 , C10J2300/1892 , C10K1/002 , C10K1/003 , C10K1/02 , C10K1/06 , Y02E20/18 , Y02E50/14 , Y02E50/18 , Y02P20/145
摘要： A system for gasifying biomass is disclosed. The system comprises a water storage tank, a water pump, a heat exchanger, a plasma torch heater, a gasifier, an ash cooler, a spray tower, a dust collector, a deacidification tower, and a desiccator. The water storage tank is connected to the water inlet of the heat exchanger; the vapor outlet of the heat exchanger is connected to the vapor inlet of the plasma torch heater; the vapor outlet of the plasma torch heater is connected to the vapor nozzle of the gasifier; the ash outlet of the gasifier is connected to the ash inlet of the ash cooler; the gas outlet of the gasifier is connected to the gas inlet of the spray tower; and the gas outlet of the spray tower is connected to the gas inlet of the heat exchanger.

6. 发明申请

US20170152454A1 METHOD AND SYSTEM FOR COGENERATING GAS-STEAM BASED ON GASIFICATION AND METHANATION OF BIOMASS 审中-公开
公开(公告)号：US20170152454A1
公开(公告)日：2017-06-01
申请号：US15429129
申请日：2017-02-09
申请人： Sunshine Kaidi New Energy Group Co., Ltd.
发明人： Weiguang YANG , Yan GONG , Xiaodong ZHAN , Dechen SONG
IPC分类号： C10L3/08 , C10J3/86 , C10J3/82
CPC分类号： C10L3/08 , C10J3/82 , C10J3/86 , C10J2300/0916 , C10J2300/1662 , C10J2300/1687 , C10L2200/0469 , C10L2290/04 , C10L2290/06 , C10L2290/10 , C10L2290/42 , F22B1/18 , F22B27/14 , F22G1/02 , Y02E20/16 , Y02E20/18 , Y02E50/32
摘要： A system for cogenerating gas-steam based on gasification and methanation of biomass, the system including a gasification unit, a shift unit, a purification unit, a methanation unit, and a methane concentration unit. A waste heat boiler is provided in an upper part of a gasifier of the gasification unit. The methanation unit includes a first primary methanation reactor, a second primary methanation reactor, a first secondary methanation reactor, and a second secondary methanation reactor connected in series. An outlet of the second primary methanation reactor is provided with two bypasses, one of which is connected to an inlet of the first primary methanation reactor, the other of which is connected to the first secondary methanation reactor. The second secondary methanation reactor is connected to the methane concentration unit.

7. 发明申请

US20150105480A1 METHOD FOR RECYCLING NOBLE METALS FROM FISCHER-TROPSCH PRODUCTS 有权
标题翻译：从FISCHER-TROPSCH产品中回收贵金属的方法
公开(公告)号：US20150105480A1
公开(公告)日：2015-04-16
申请号：US14578539
申请日：2014-12-22
申请人： SUNSHINE KAIDI NEW ENERGY GROUP CO., LTD.
发明人： Yilong CHEN , Jiaqi JIN , Yanfeng ZHANG , Kan SONG , Xiaodong ZHAN , Manyi JIANG
IPC分类号： C22B61/00 , C21B15/00 , C22B3/00
CPC分类号： C22B61/00 , B01J8/006 , B01J8/007 , B01J8/22 , B01J23/75 , C10G31/09 , C10G2300/1022 , C10G2300/205 , C10G2300/208 , C10G2300/706 , C21B15/00 , C21B2200/00 , C22B7/009 , C22B11/026 , C22B23/04 , Y02P10/214 , Y02W30/54
摘要： A method for recycling a noble metal from Fischer-Tropsch synthesis products. The method includes: 1) filtering a reaction product in a Fischer-Tropsch synthesis reactor by an inner filter; discharging a filtered reaction product to a first filtration buffer tank; separating a gas phase product or a part of a liquid phase product from the reaction product; introducing the liquid-solid two-phase product to a refining filter for product refining; 2) introducing a liquid phase product containing a catalyst slurry to a dynamic filter, collecting the filtered liquid phase product including a waste catalyst and noble metal ions; introducing the liquid phase product to a second filtration buffer tank; and introducing the filtered liquid phase product to the refining filter; and 3) forming a clay filter cake on a filter disk; and refining the products introduced into the refining filter in 1) and 2).
摘要翻译：一种从费 - 托合成产品中回收贵金属的方法。该方法包括：1）通过内部过滤器过滤费 - 托合成反应器中的反应产物; 将过滤的反应产物排放到第一过滤缓冲罐; 从反应产物中分离气相产物或一部分液相产物; 将液固两相产品引入用于产品精炼的精制过滤器; 2）将含有催化剂浆液的液相产物引入动态过滤器，收集包含废催化剂和贵金属离子的过滤液相产物; 将液相产物引入第二过滤缓冲罐; 并将经过滤的液相产物引入精炼过滤器; 和3）在过滤盘上形成粘土滤饼; 并在1）和2）中精炼引入精制过滤器的产品。

8. 发明申请

US20140026473A1 METHOD AND DEVICE FOR SUPPLYING HEAT ENERGY AND CARBON DIOXIDE FROM EXHAUST GAS FOR VEGETABLE AND/OR ALGAE PRODUCTION 有权
标题翻译：从用于蔬菜和/或生产的废气中提供热能和二氧化碳的方法和装置
公开(公告)号：US20140026473A1
公开(公告)日：2014-01-30
申请号：US14040678
申请日：2013-09-28
申请人： Sunshine Kaidi New Energy Group Co., Ltd.
发明人： Yilong CHEN , Shuchuan HU , Yanfeng ZHANG
IPC分类号： A01G7/02 , F28F1/00
CPC分类号： A01G7/02 , A01G33/00 , C12N1/12 , F28F1/00 , Y02A40/88 , Y02P60/247
摘要： A method for supplying heat energy and carbon dioxide for vegetables and/or algae production using exhaust gas. The method includes: 1) introducing the exhaust gas to a primary heat exchanger to conduct a first indirect heat exchange between the exhaust gas and air from a vegetable greenhouse and/or an algae culturing house whereby providing hot air for the vegetable greenhouse and/or the algae culturing house; 2) introducing part of the exhaust gas after the first indirect heat exchange to a secondary heat exchanger to conduct a second indirect heat exchange between the exhaust gas and outdoor air; 3) introducing the exhaust gas to a CO2 pressure swing adsorption device, separating and pumping carbon dioxide to a carbon dioxide storage tank for storage; and 4) supplying the carbon dioxide to the vegetable greenhouse and/or a carbon-absorption tank of the algae culturing house.
摘要翻译：用于使用废气提供用于蔬菜和/或藻类生产的热能和二氧化碳的方法。该方法包括：1）将废气引入主要热交换器，以便在来自蔬菜温室和/或藻类培育室的废气和空气之间进行第一次间接热交换，从而为蔬菜温室和/或藻类养殖场; 2）将第一间接热交换后的一部分废气引入二次热交换器，以在废气与室外空气之间进行第二间接热交换; 3）将废气引入二氧化碳变压吸附装置，将二氧化碳分离并泵入二氧化碳储存罐进行储存; 以及4）将二氧化碳供应到藻类培育室的蔬菜温室和/或碳吸收罐。

9. 发明授权

US09560867B2 Method for removal of metal ions from rice hull 有权
标题翻译：从稻壳中去除金属离子的方法
公开(公告)号：US09560867B2
公开(公告)日：2017-02-07
申请号：US14477833
申请日：2014-09-04
申请人： Sunshine Kaidi New Energy Group Co., Ltd.
发明人： Yilong Chen , Yanfeng Zhang , Leiming Tao , Wenxue Luo , Zhilong Wang , Zhixiang Luo , Yongjie Xue
IPC分类号： A23L1/00 , A23L1/10 , C01G49/00 , B09B3/00 , B09B5/00
CPC分类号： A23L5/276 , A23L5/23 , A23L7/115 , A23V2002/00 , B09B3/00 , B09B5/00 , C01G49/00
摘要： A method for removal of metal ions from rice hulls. The method includes: 1) providing a water storage reactor, and disposing a gas dispersion device at the bottom of the water storage reactor; 2) bagging rice hulls, placing it in the water storage reactor, and pressing down on the bagged rice hulls to be lower than a water surface in the water storage reactor; 3) spraying industrial flue gas into the water storage reactor; controlling the amount of the industrial flue gas such that about 1 g of carbon dioxide is dissolved per 100 g of water, thus generating a carbonic acid solution; 4) allowing the carbonic acid solution to react with metal ions in the rice hulls to yield a precipitate; and 5) washing the rice hulls collected in step 4), washing again with desalinated water, and then squeezing the rice hulls.
摘要翻译：从稻壳中去除金属离子的方法。该方法包括：1）提供储水反应器，并在储水反应堆底部设置气体分散装置; 2）装载米壳，将其放置在储水反应堆中，并将袋装的稻壳按压低于储水反应堆的水面; 3）将工业废气喷入储水反应堆; 控制工业烟气的量，使得每100g水溶解约1g二氧化碳，从而产生碳酸溶液; 4）允许碳酸溶液与稻壳中的金属离子反应产生沉淀物; 和5）洗涤步骤4）中收集的米壳，再次用淡化水洗涤，然后挤压稻壳。

10. 发明申请

US20160145514A1 METHOD AND SYSTEM FOR GASIFICATION OF BIOMASS 有权
标题翻译：生物量气化方法与系统
公开(公告)号：US20160145514A1
公开(公告)日：2016-05-26
申请号：US15011644
申请日：2016-01-31
申请人： SUNSHINE KAIDI NEW ENERGY GROUP CO., LTD.
发明人： Yilong CHEN , Yanfeng ZHANG , Hongming TANG
IPC分类号： C10J3/84 , C10K1/00 , C10K1/02
CPC分类号： C10J3/84 , C10J3/20 , C10J3/46 , C10J2200/152 , C10J2300/0906 , C10J2300/0916 , C10J2300/0973 , C10J2300/0976 , C10J2300/1238 , C10J2300/1246 , C10J2300/1653 , C10J2300/1659 , C10J2300/1665 , C10J2300/1693 , C10J2300/1853 , C10J2300/1884 , C10J2300/1892 , C10K1/002 , C10K1/003 , C10K1/02 , C10K1/06 , Y02E20/18 , Y02E50/14 , Y02E50/18 , Y02P20/145
摘要： A system for gasifying biomass is disclosed. The system comprises a water storage tank, a water pump, a heat exchanger, a plasma torch heater, a gasifier, an ash cooler, a spray tower, a dust collector, a deacidification tower, and a desiccator. The water storage tank is connected to the water inlet of the heat exchanger; the vapor outlet of the heat exchanger is connected to the vapor inlet of the plasma torch heater; the vapor outlet of the plasma torch heater is connected to the vapor nozzle of the gasifier; the ash outlet of the gasifier is connected to the ash inlet of the ash cooler; the gas outlet of the gasifier is connected to the gas inlet of the spray tower; and the gas outlet of the spray tower is connected to the gas inlet of the heat exchanger.
摘要翻译：公开了一种用于气化生物质的系统。该系统包括储水箱，水泵，热交换器，等离子体焰炬加热器，气化器，灰分冷却器，喷雾塔，集尘器，脱酸塔和干燥器。储水箱与热交换器的进水口连接; 热交换器的蒸汽出口连接到等离子体焰炬加热器的蒸汽入口; 等离子体焰炬加热器的蒸汽出口连接到气化器的蒸汽喷嘴; 气化炉灰渣出口连接灰渣冷却器的进灰口; 气化器的气体出口连接到喷射塔的气体入口; 并且喷射塔的气体出口连接到热交换器的气体入口。

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