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1. 发明授权

US08927160B2 Pentacyclic anion salt and use thereof as an electrolyte 有权
标题翻译：五环阴离子盐及其作为电解质的用途
公开(公告)号：US08927160B2
公开(公告)日：2015-01-06
申请号：US13060776
申请日：2009-08-28
申请人： Michel Armand , Sylvie Grugeon , Stephane Laruelle , Maria Bukowska , Przemyslaw Szczecinski , Wladyslaw Wieczorek , Leszek Niedzicky , Bruno Scrosati , Stefania Panero , Priscilla Realle
发明人： Michel Armand , Sylvie Grugeon , Stephane Laruelle , Maria Bukowska , Przemyslaw Szczecinski , Wladyslaw Wieczorek , Leszek Niedzicky , Bruno Scrosati , Stefania Panero , Priscilla Realle
IPC分类号： H01M6/16 , H01M10/0568 , B22F9/24 , C07D233/00 , C22B5/00 , H01M4/58 , H01M10/0525
CPC分类号： C07D233/90 , B22F9/24 , B22F2009/245 , B22F2999/00 , C07D207/06 , C07D213/18 , C07D233/00 , C07D233/58 , C22B5/00 , H01M4/5825 , H01M10/052 , H01M10/0525 , H01M10/0568 , H01M10/0569 , H01M2300/0028 , B22F2202/13 , B22F2202/11
摘要： The invention relates to a pentacyclic anion salt and to the use thereof in electrolyte compositions. The compound comprises an inorganic, organic or organometallic cation M of valency m (1≦m≦3) and m anions corresponding to the formula (I) in which Rf is a —CFZ′Z″ group in which Z′ is F or a perfluoroalkyl group having from 1 to 3 carbon atoms, and Z″ is an H, F or Cl group, an optionally fluorinated or perfluorinated alkoxy group having from 1 to 5 carbon atoms, an optionally fluorinated or perfluorinated oxaalkoxy group having from 1 to 5 carbon atoms or an optionally fluorinated or perfluorinated alkyl group having from 1 to 5 carbon atoms; Z″ being other than F when Z′ is F. An electrolyte composition comprises said salt in solution in a liquid solvent or a polymer solvent.
摘要翻译：本发明涉及五环阴离子盐及其在电解质组合物中的用途。该化合物包括价态m（1＆nlE; m＆lt; 1; 3）的无机，有机或有机金属阳离子M和对应于式（I）的阴离子，其中R f是其中Z'为F的-CFZ'Z“基团或具有1至3个碳原子的全氟烷基，Z“是H，F或Cl基团，具有1至5个碳原子的任选氟化或全氟化烷氧基，任选氟化或全氟化的具有1至5个碳原子的氧杂烷氧基原子或具有1至5个碳原子的任选氟化或全氟化的烷基; Z“在Z'为F时为F。电解质组合物包含溶液中的所述盐在液体溶剂或聚合物溶剂中。

2. 发明申请

US20110311884A1 PENTACYCLIC ANION SALT AND USE THEREOF AS AN ELECTROLYTE 有权
标题翻译： PENTACYCLIC ANION SALT和其作为电解质的使用
公开(公告)号：US20110311884A1
公开(公告)日：2011-12-22
申请号：US13060776
申请日：2009-08-28
申请人： Michel Armand , Sylvie Grugeon , Stephane Laruelle , Maria Bukowska , Przemyslaw Szczecinski , Wladyslaw Wieczorek , Leszek Niedzicki , Bruno Scrosati , Stefania Panero , Priscilla Realle
发明人： Michel Armand , Sylvie Grugeon , Stephane Laruelle , Maria Bukowska , Przemyslaw Szczecinski , Wladyslaw Wieczorek , Leszek Niedzicki , Bruno Scrosati , Stefania Panero , Priscilla Realle
IPC分类号： H01M10/056 , C07D213/06 , C07D249/04 , B01J19/12 , C07D233/90 , C07D295/00 , B82Y40/00 , B82Y99/00
CPC分类号： C07D233/90 , B22F9/24 , B22F2009/245 , B22F2999/00 , C07D207/06 , C07D213/18 , C07D233/00 , C07D233/58 , C22B5/00 , H01M4/5825 , H01M10/052 , H01M10/0525 , H01M10/0568 , H01M10/0569 , H01M2300/0028 , B22F2202/13 , B22F2202/11
摘要： The invention relates to a pentacyclic anion salt and to the use thereof in electrolyte compositions. The compound comprises an inorganic, organic or organometallic cation M of valency m (1≦m≦3) and m anions corresponding to the formula (I) in which Rf is a —CFZ′Z″ group in which Z′ is F or a perfluoroalkyl group having from 1 to 3 carbon atoms, and Z″ is an H, F or Cl group, an optionally fluorinated or perfluorinated alkoxy group having from 1 to 5 carbon atoms, an optionally fluorinated or perfluorinated oxaalkoxy group having from 1 to 5 carbon atoms or an optionally fluorinated or perfluorinated alkyl group having from 1 to 5 carbon atoms; Z″ being other than F when Z′ is F. An electrolyte composition comprises said salt in solution in a liquid solvent or a polymer solvent.
摘要翻译：本发明涉及五环阴离子盐及其在电解质组合物中的用途。该化合物包括价态m（1＆nlE; m＆lt; 1; 3）的无机，有机或有机金属阳离子M和对应于式（I）的阴离子，其中R f是其中Z'为F的-CFZ'Z“基团或具有1至3个碳原子的全氟烷基，Z“是H，F或Cl基团，具有1至5个碳原子的任选氟化或全氟化烷氧基，任选氟化或全氟化的具有1至5个碳原子的氧杂烷氧基原子或具有1至5个碳原子的任选氟化或全氟化的烷基; Z“在Z'为F时为F。电解质组合物包含溶液中的所述盐在液体溶剂或聚合物溶剂中。

3. 发明申请

US20110171112A1 BORON OR ALUMINUM COMPLEXES 有权
标题翻译：硼或铝复合物
公开(公告)号：US20110171112A1
公开(公告)日：2011-07-14
申请号：US12736195
申请日：2009-03-19
申请人： Michel Armand , Jean-Marie Tarascon , Nadir Recham , Sylvie Grugeon , Stephane Laruelle , Shanmukaraj Devaraj
发明人： Michel Armand , Jean-Marie Tarascon , Nadir Recham , Sylvie Grugeon , Stephane Laruelle , Shanmukaraj Devaraj
IPC分类号： C07F5/04 , C07F5/02 , C07F5/06 , C01G49/02
CPC分类号： C07F5/022 , C07F5/025 , C07F5/069 , H01M10/052 , H01M10/0567
摘要： The present invention relates to boron and aluminum complexes, to the preparation thereof, and to the use thereof for solubilizing ionic compounds. The complexes have one of the following formulae: in which D represents B or Al; R1 represents R, RF, NO2, CN, C(═O)OR, RSO2, or RFSO2; —X1—, —X2—, —X3— and X4 each represent a divalent group >C═O, >C═NC≡N, >C═C(C≡N)2, >CR2R3 or >SO2; —Y1—, —Y2— and —Y3— each represent a divalent group —O—, >N(C≡N), >N(CORF), >N(SO2R4), >NR4, >N(COR4) or >N(SO2RF); R, R2 and R3 each represent H, an alkyl group, an aryl group, an alkylaryl group, an arylalkyl group, an oxaalkyl group or an alkenyl group; R4 represents an alkyl group, an aryl group, an alkylaryl group, a heteroaryl group, an arylalkyl group, an oxaalkyl group, an alkenyl group or an RFCH2— group; RF is a perfluoroalkyl group, a partially fluorinated alkyl group, or a partially or totally fluorinated phenyl group; each of the R′2 and R′3 groups represents R or F.
摘要翻译：本发明涉及硼和铝络合物，其制备方法及其用于增溶离子化合物的用途。所述络合物具有下式之一：其中D表示B或Al; R1表示R，RF，NO2，CN，C（= O）OR，RSO2或RFSO2; -X1-，-X2-，-X3-和X4各自表示二价基团> C = O，> C =NC≡N，> C = C（C≡N）2，> CR2R3或> SO2; -Y1-，-Y2-和-Y3-各自表示二价基团-O - ，> N（C≡N），> N（CORF），> N（SO 2 R 4），NR 4，N（COR 4） N（SO2RF）; R，R 2和R 3各自表示H，烷基，芳基，烷基芳基，芳烷基，氧杂烷基或烯基; R4表示烷基，芳基，烷基芳基，杂芳基，芳基烷基，氧杂烷基，烯基或RFCH2-基团; RF是全氟烷基，部分氟化的烷基或部分或全部氟化的苯基; R'2和R'3各自表示R或F.

4. 发明申请

US20130298386A1 METHOD FOR PRODUCING A LITHIUM OR SODIUM BATTERY 审中-公开
标题翻译：生产锂电池或钠电池的方法
公开(公告)号：US20130298386A1
公开(公告)日：2013-11-14
申请号：US13704418
申请日：2011-06-16
申请人： Jean-Marie Tarascon , Michel Armand , Shanmukaraj Devaraj , Sylvie Grugeon , Stephane Laruelle
发明人： Jean-Marie Tarascon , Michel Armand , Shanmukaraj Devaraj , Sylvie Grugeon , Stephane Laruelle
IPC分类号： H01M4/139
CPC分类号： H01M4/139 , H01M4/13 , H01M4/131 , H01M4/136 , H01M4/62 , H01M10/0525 , H01M10/054 , H01M10/0562 , H01M10/0565 , H01M10/3909 , Y10T29/49108
摘要： The invention relates to a method for producing a battery using A+ (Li+ or Na+) as an electrochemical carrier, as well as to the resulting batteries. The method involves assembling together a negative electrode, a positive electrode, and an electrolyte, and then exposing the assembly to a firm charge at the operating temperature of the battery. The electrolyte is a ceramic or a solution of an A+ salt in a polar liquid, a polymer, or the mixture thereof. The active material of the negative electrode is a material which has a redox couple, the potential of which is 0 V to 1.6 V relative to the A+/A+ couple. The active material of the positive electrode is a material which has a redox couple, the potential of which is higher then that of the couple of the negative electrode. The positive electrode used during assembly consists of a current collector having a comprises material which contains the positive active material and at least one sacrificial salt of a cations E+ is selected from among Li+, Na+, K+ and the onium cations, and a redox action selected from azide anions, ketocarboxylate anions, and hydrazide anions, optionally in the form of a polymers.
摘要翻译：本发明涉及使用A +（Li +或Na +）作为电化学载体制造电池的方法，以及所得的电池。该方法包括将负极，正电极和电解质组装在一起，然后在电池的工作温度下将组件暴露于牢固的电荷。电解质是陶瓷或A +盐在极性液体，聚合物或其混合物中的溶液。负极的活性材料是具有氧化还原电位的材料，其电位相对于A + / A +电压为0V至1.6V。正极的活性物质是具有氧化还原电位的材料，其电位高于负电极的电位。在组装期间使用的正电极由具有包含正极活性材料的材料和至少一种阳离子E +的牺牲盐选自Li +，Na +，K +和鎓阳离子的集电器组成，并且选择氧化还原作用从叠氮阴离子，酮羧酸根阴离子和酰肼阴离子，任选地以聚合物的形式。

5. 发明申请

US20070231688A1 Component Comprising an Electron Collector and an Active Material, and the Use Thereof as a Battery Electrode 审中-公开
标题翻译：包含电子收集器和活性材料的组件及其用途作为电池电极
公开(公告)号：US20070231688A1
公开(公告)日：2007-10-04
申请号：US11569052
申请日：2005-05-19
申请人： Sylvie Grugeon , Stephane Laruelle , Jean-Marie Tarascon
发明人： Sylvie Grugeon , Stephane Laruelle , Jean-Marie Tarascon
IPC分类号： H01M4/02
CPC分类号： H01M6/02 , H01M4/04 , H01M4/64 , H01M4/669 , Y10T29/49108
摘要： The invention relates to a component for an accumulator or for a supercondenser, said component comprising at least one election collector and an active material containing at least one transition metal and having been formed at least partially from the collector. The active material is at least partially at the surface of the electron collector, and at least part of the active material comprises nanoparticles of at least one compound of the transition metal or agglomerates of said nanoparticles, the nanoparticles having an average size of between 1 and 1,000 nm, and the agglomerates of nanoparticles having an average size of between 1 and 10,000 nm. The invention also relates to a method for producing one such component, and to a supercondenser and a preferably lithium electrochemical accumulator comprising one such component
摘要翻译：本发明涉及一种用于蓄能器或超级冷凝器的部件，所述部件包括至少一个选择收集器和包含至少一种过渡金属并至少部分地由收集器形成的活性材料。活性材料至少部分地位于电子收集器的表面，至少部分活性材料包含至少一种过渡金属的化合物或所述纳米颗粒的附聚物的纳米颗粒，所述纳米颗粒的平均尺寸介于1和 1,000nm的纳米颗粒和平均尺寸在1至10,000nm之间的聚集体。本发明还涉及一种制备这种组分的方法，以及一种超级冷凝剂和优选锂电化学蓄电池，其包括一种这样的组分

6. 发明授权

US08563761B2 Boron or aluminum complexes 有权
标题翻译：硼或铝络合物
公开(公告)号：US08563761B2
公开(公告)日：2013-10-22
申请号：US12736195
申请日：2009-03-19
申请人： Michel Armand , Jean-Marie Tarascon , Nadir Recham , Sylvie Grugeon , Stephane Laruelle , Shanmukaraj Devaraj
发明人： Michel Armand , Jean-Marie Tarascon , Nadir Recham , Sylvie Grugeon , Stephane Laruelle , Shanmukaraj Devaraj
IPC分类号： C07F5/06 , C07F5/02 , C01G49/02
CPC分类号： C07F5/022 , C07F5/025 , C07F5/069 , H01M10/052 , H01M10/0567
摘要： The present invention relates to boron and aluminum complexes, to the preparation thereof, and to the use thereof for solubilizing ionic compounds. The complexes have one of the following formulae: in which D represents B or Al; R1 represents R, RF, NO2, CN, C(═O)OR, RSO2, or RFSO2; —X1—, —X2—, —X3— and X4 each represent a divalent group >C═O, >C═NC≡N, >C═C(C≡N)2, >CR2R3 or >SO2; —Y1—, —Y2— and —Y3— each represent a divalent group —O—, >N(C≡N), >N(CORF), >N(SO2R4), >NR4, >N(COR4) or >N(SO2RF); R, R2 and R3 each represent H, an alkyl group, an aryl group, an alkylaryl group, an arylalkyl group, an oxaalkyl group or an alkenyl group; R4 represents an alkyl group, an aryl group, an alkylaryl group, a heteroaryl group, an arylalkyl group, an oxaalkyl group, an alkenyl group or an RFCH2— group; RF is a perfluoroalkyl group, a partially fluorinated alkyl group, or a partially or totally fluorinated phenyl group; each of the R′2 and R′3 groups represents R or F.
摘要翻译：本发明涉及硼和铝络合物，其制备方法及其用于增溶离子化合物的用途。所述络合物具有下式之一：其中D表示B或Al; R1表示R，RF，NO2，CN，C（= O）OR，RSO2或RFSO2; -X1-，-X2-，-X3-和X4各自表示二价基团> C = O，> C = NC = N，> C = C（C = N）2，> CR2R3或> SO2; -Y2-，-Y2-和-Y3-各自表示二价基团-O - ，> N（C = N），> N（CORF），> N（SO 2 R 4），NR 4，N（COR 4） N（SO2RF）; R，R 2和R 3各自表示H，烷基，芳基，烷基芳基，芳烷基，氧杂烷基或烯基; R4表示烷基，芳基，烷基芳基，杂芳基，芳基烷基，氧杂烷基，烯基或RFCH2-基团; RF是全氟烷基，部分氟化烷基或部分或全部氟化苯基; R'2和R'3各自表示R或F.

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