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    • 1. 发明授权
    • Process for recovering electrolytic copper of high purity by means of
reduction electrolysis
    • 通过还原电解回收高纯度电解铜的方法
    • US4030990A
    • 1977-06-21
    • US698558
    • 1976-06-22
    • Norbert L. PiretHans Joachim RabbenHerbert KudelkaSiegbert Schmidt
    • Norbert L. PiretHans Joachim RabbenHerbert KudelkaSiegbert Schmidt
    • C22B15/00C25C1/12
    • C25C1/12C22B15/0071C22B15/0089C22B15/0091C22B15/0093Y02P10/236
    • Copper sulfate solution obtained by the sulfuric acid leaching of cupriferous material and containing impurities such as Fe, As, Sb, Bi, Se, Te, Sn, Pb, Cl, Ag, Hg, and PO.sub.4, are subjected to a two step purification process. In the first step, the pH is adjusted to 2.7-3.3 with, e.g. Ca(OH).sub.2, and the potential in relation to the standard hydrogen electrode is adjusted to at least 575 mv with an oxidizing agent, e.g. air. The temperature is 50.degree.-90.degree. C. Impurities precipitate and are separated. Se, Cl, and possibly Ag and Hg remain in solution and are removed in the second step, wherein the potential is reduced to below 350 mv by addition of a cupriferous reducing agent, e.g. Cu or Cu.sub.2 O. The pH is below 3 and the temperature is below 50.degree. C. Impurities precipitate as copper (I) compounds, and are separated to provide the solution in condition for the electrolysis. The copper produced is of high purity, having a conductivity of at least 58.8 mho .times. m/mm.sup.2 and a maximum semi-hard temperature of 200.degree. C.
    • 通过硫酸浸出铜含量并含有Fe,As,Sb,Bi,Se,Te,Sn,Pb,Cl,Ag,Hg和PO4等杂质的硫酸铜溶液进行两步纯化过程 。 在第一步中,将pH调节至2.7-3.3。 Ca(OH)2,相对于标准氢电极的电位用氧化剂调节至至少575mv。 空气。 温度为50°-90℃。杂质沉淀并分离。 Se,Cl和可能的Ag和Hg保留在溶液中,并在第二步中除去,其中通过加入铜还原剂,例如还原剂将电位降低至低于350mv。 Cu或Cu2O。 pH值低于3,温度低于50℃。杂质以铜(I)化合物的形式析出,并分离,以提供电解条件下的溶液。 所生产的铜具有高纯度,导电率至少为58.8mhom / m 2,最大半硬温度为200℃。