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1. 发明申请

US20130139695A1 METHOD AND SYSTEM FOR CAPTURING CARBON DIOXIDE AND/OR SULFUR DIOXIDE FROM GAS STREAM 有权
标题翻译：从气体流中吸收二氧化碳和/或二氧化硫的方法和系统
公开(公告)号：US20130139695A1
公开(公告)日：2013-06-06
申请号：US13757550
申请日：2013-02-01
申请人： Shih-Ger Chang , Yang Li , Xinglei Zhao
发明人： Shih-Ger Chang , Yang Li , Xinglei Zhao
IPC分类号： B01D53/14
CPC分类号： B01D53/1475 , B01D53/1406 , B01D53/1425 , B01D53/1481 , B01D53/1493 , B01D53/501 , B01D2251/306 , B01D2251/606 , B01D2252/10 , B01D2252/20447 , B01D2252/20484 , B01D2252/20489 , B01D2252/20494 , B01D2252/602 , B01D2252/604 , B01D2252/606 , B01D2252/608 , B01D2256/22 , B01D2257/302 , B01D2257/504 , B01D2258/0283 , Y02A50/2342 , Y02A50/2349 , Y02C10/06
摘要： The present invention provides a system for capturing CO2 and/or SO2, comprising: (a) a CO2 and/or SO2 absorber comprising an amine and/or amino acid salt capable of absorbing the CO2 and/or SO2 to produce a CO2- and/or SO2-containing solution; (b) an amine regenerator to regenerate the amine and/or amino acid salt; and, when the system captures CO2, (c) an alkali metal carbonate regenerator comprising an ammonium catalyst capable catalyzing the aqueous alkali metal bicarbonate into the alkali metal carbonate and CO2 gas. The present invention also provides for a system for capturing SO2, comprising: (a) a SO2 absorber comprising aqueous alkali metal carbonate, wherein the alkali metal carbonate is capable of absorbing the SO2 to produce an alkali metal sulfite/sulfate precipitate and CO2.
摘要翻译：本发明提供了一种用于捕获CO 2和/或SO 2的系统，其包括：（a）包含能够吸收CO 2和/或SO 2以产生CO 2的胺和/或氨基酸盐的CO 2和/或SO 2吸收剂， /或含SO2溶液; （b）胺再生器，用于再生胺和/或氨基酸盐; 并且当系统捕获CO 2时，（c）含有能够将碱金属碳酸氢盐水溶液转化为碱金属碳酸盐和CO 2气体的铵催化剂的碱金属碳酸盐再生器。本发明还提供一种用于捕获SO 2的系统，其包括：（a）包含碱金属碳酸盐水溶液的SO 2吸收剂，其中所述碱金属碳酸盐能够吸收SO 2以产生碱金属亚硫酸盐/硫酸盐沉淀物和CO 2。

2. 发明授权

US08007749B2 Method for scavenging mercury 有权
标题翻译：清除汞的方法
公开(公告)号：US08007749B2
公开(公告)日：2011-08-30
申请号：US12792135
申请日：2010-06-02
申请人： Shih-Ger Chang , Shou-Heng Liu , Zhao-Rong Liu , Naiqiang Yan
发明人： Shih-Ger Chang , Shou-Heng Liu , Zhao-Rong Liu , Naiqiang Yan
IPC分类号： B01D53/64
CPC分类号： B01D53/64 , B01D2257/602
摘要： Disclosed herein is a method for removing mercury from a gas stream comprising contacting the gas stream with a getter composition comprising bromine, bromochloride, sulphur bromide, sulphur dichloride or sulphur monochloride and mixtures thereof. In one preferred embodiment the getter composition is adsorbed onto a sorbent. The sorbent may be selected from the group consisting of flyash, limestone, lime, calcium sulphate, calcium sulfite, activated carbon, charcoal, silicate, alumina and mixtures thereof. Preferred is flyash, activated carbon and silica.
摘要翻译：本文公开了一种从气流中除去汞的方法，包括使气流与包含溴，溴氯化物，溴化硫，二氯化硫或一氯化硫的吸气剂组合物及其混合物接触。在一个优选实施方案中，吸气剂组合物被吸附到吸附剂上。吸附剂可以选自飞灰，石灰石，石灰，硫酸钙，亚硫酸钙，活性炭，木炭，硅酸盐，氧化铝及其混合物。优选的是飞灰，活性炭和二氧化硅。

3. 发明授权

US5106601A Process for the removal of acid forming gases from exhaust gases and production of phosphoric acid 失效
标题翻译：从废气中除去酸性气体和生产磷酸的工艺
公开(公告)号：US5106601A
公开(公告)日：1992-04-21
申请号：US518722
申请日：1990-05-04
申请人： Shih-Ger Chang , David K. Liu
发明人： Shih-Ger Chang , David K. Liu
IPC分类号： B01D53/60
CPC分类号： B01D53/60
摘要： Exhaust gases are treated to remove NO or NO.sub.x and SO.sub.2 by contacting the gases with an aqueous emulsion or suspension of yellow phosphorous preferably in a wet scrubber. The addition of yellow phosphorous in the system induces the production of O.sub.3 which subsequently oxidizes NO to NO.sub.2. The resulting NO.sub.2 dissolves readily and can be reduced to form ammonium ions by dissolved SO.sub.2 under appropriate conditions. In a 20 acfm system, yellow phosphorous is oxidized to yield P.sub.2 O.sub.5 which picks up water to form H.sub.3 PO.sub.4 mists and can be collected as a valuable product. The pressure is not critical, and ambient pressures are used. Hot water temperatures are best, but economics suggest about 50.degree. C. The amount of yellow phosphorus used will vary with the composition of the exhaust gas, less than 3% for small concentrations of NO, and 10% or higher for concentrations above say 1000 ppm. Similarly, the pH will vary with the composition being treated, and it is adjusted with a suitable alkali. For mixtures of NO.sub.x and SO.sub.2, alkalis that are used for flue gas desulfurization are preferred. With this process, better than 90% of SO.sub.2 and NO in simulated flue gas can be removed. Stoichiometric ratios (P/NO) ranging between 0.6 and 1.5 were obtained.
摘要翻译：通过使气体与水性乳液或黄磷的悬浮液接触，优选在湿式洗涤器中处理废气以除去NO或NO x和SO 2。在系统中加入黄色磷诱导O3的产生，其随后将NO氧化成NO 2。所得的NO 2容易溶解并且可以在合适的条件下通过溶解的SO 2还原形成铵离子。在20 acfm系统中，黄磷被氧化产生P2O5，其吸收水以形成H 3 PO 4雾，并且可以作为有价值的产物收集。压力并不重要，并且使用环境压力。热水温度最好，但经济学表明约为50℃。所用的黄磷量将随着废气的组成而变化，对于小浓度的NO，小于3％，高于1000的浓度为10％以上 ppm。类似地，pH将随待处理的组合物而变化，并用合适的碱调节。对于NOx和SO 2的混合物，优选用于烟道气脱硫的碱。通过这个过程，可以去除模拟烟道气中优于SO2和NO的90％。化学计量比（P / NO）为0.6〜1.5。

4. 发明申请

US20100272621A1 METHOD FOR SCAVENGING MERCURY 有权
标题翻译：切割汞的方法
公开(公告)号：US20100272621A1
公开(公告)日：2010-10-28
申请号：US12792135
申请日：2010-06-02
申请人： Shih-ger CHANG , Shou-heng LIU , Zhao-rong LIU , Naiqiang YAN
发明人： Shih-ger CHANG , Shou-heng LIU , Zhao-rong LIU , Naiqiang YAN
IPC分类号： B01D53/64
CPC分类号： B01D53/64 , B01D2257/602
摘要： Disclosed herein is a method for removing mercury from a gas stream comprising contacting the gas stream with a getter composition comprising bromine, bromochloride, sulphur bromide, sulphur dichloride or sulphur monochloride and mixtures thereof. In one preferred embodiment the getter composition is adsorbed onto a sorbent. The sorbent may be selected from the group consisting of flyash, limestone, lime, calcium sulphate, calcium sulfite, activated carbon, charcoal, silicate, alumina and mixtures thereof. Preferred is flyash, activated carbon and silica.
摘要翻译：本文公开了一种从气流中除去汞的方法，包括使气流与包含溴，溴氯化物，溴化硫，二氯化硫或一氯化硫的吸气剂组合物及其混合物接触。在一个优选实施方案中，吸气剂组合物被吸附到吸附剂上。吸附剂可以选自飞灰，石灰石，石灰，硫酸钙，亚硫酸钙，活性炭，木炭，硅酸盐，氧化铝及其混合物。优选的是飞灰，活性炭和二氧化硅。

5. 发明申请

US20060057044A1 Method for scavenging mercury 有权
公开(公告)号：US20060057044A1
公开(公告)日：2006-03-16
申请号：US11101713
申请日：2005-04-07
申请人： Shih-ger Chang , Shou-heng Liu , Zhao-rong Liu , Naiqiang Yan
发明人： Shih-ger Chang , Shou-heng Liu , Zhao-rong Liu , Naiqiang Yan
IPC分类号： B01D53/64
CPC分类号： B01D53/64 , B01D2257/602
摘要： Disclosed herein is a method for removing mercury from a gas stream comprising contacting the gas stream with a getter composition comprising bromine, bromochloride, sulphur bromide, sulphur dichloride or sulphur monochloride and mixtures thereof. In one preferred embodiment the getter composition is adsorbed onto a sorbent. The sorbent may be selected from the group consisting of flyash, limestone, lime, calcium sulphate, calcium sulfite, activated carbon, charcoal, silicate, alumina and mixtures thereof. Preferred is flyash, activated carbon and silica.

6. 发明申请

US20090155149A1 METHOD FOR SCAVENGING MERCURY 有权
标题翻译：切割汞的方法
公开(公告)号：US20090155149A1
公开(公告)日：2009-06-18
申请号：US12355151
申请日：2009-01-16
申请人： Shih-ger CHANG , Shou-heng Liu , Zhao-rong Liu , Naiqiang Yan
发明人： Shih-ger CHANG , Shou-heng Liu , Zhao-rong Liu , Naiqiang Yan
IPC分类号： B01D53/64
CPC分类号： B01D53/64 , B01D2257/602
摘要： Disclosed herein is a method for removing mercury from a gas stream comprising contacting the gas stream with a getter composition comprising bromine, bromochloride, sulphur bromide, sulphur dichloride or sulphur monochloride and mixtures thereof. In one preferred embodiment the getter composition is adsorbed onto a sorbent. The sorbent may be selected from the group consisting flyash, limestone, lime, calcium sulphate, calcium sulfite, activated carbon, charcoal, silicate, alumina and mixtures thereof. Preferred is flyash, activated carbon and silica.
摘要翻译：本文公开了一种从气流中除去汞的方法，包括使气流与包含溴，溴氯化物，溴化硫，二氯化硫或一氯化硫的吸气剂组合物及其混合物接触。在一个优选实施方案中，吸气剂组合物被吸附到吸附剂上。吸附剂可以选自飞灰，石灰石，石灰，硫酸钙，亚硫酸钙，活性炭，木炭，硅酸盐，氧化铝及其混合物。优选的是飞灰，活性炭和二氧化硅。

7. 发明授权

US07479263B2 Method for scavenging mercury 有权
标题翻译：清除汞的方法
公开(公告)号：US07479263B2
公开(公告)日：2009-01-20
申请号：US11101713
申请日：2005-04-07
申请人： Shih-ger Chang , Shou-heng Liu , Zhao-rong Liu , Naiqiang Yan
发明人： Shih-ger Chang , Shou-heng Liu , Zhao-rong Liu , Naiqiang Yan
IPC分类号： B01D53/64
CPC分类号： B01D53/64 , B01D2257/602
摘要： Disclosed herein is a method for removing mercury from a gas stream comprising contacting the gas stream with a getter composition comprising bromine, bromochloride, sulphur bromide, sulphur dichloride or sulphur monochloride and mixtures thereof. In one preferred embodiment the getter composition is adsorbed onto a sorbent. The sorbent may be selected from the group consisting of flyash, limestone, lime, calcium sulphate, calcium sulfite, activated carbon, charcoal, silicate, alumina and mixtures thereof. Preferred is flyash, activated carbon and silica.
摘要翻译：本文公开了一种从气流中除去汞的方法，包括使气流与包含溴，溴氯化物，溴化硫，二氯化硫或一氯化硫的吸气剂组合物及其混合物接触。在一个优选实施方案中，吸气剂组合物被吸附到吸附剂上。吸附剂可以选自飞灰，石灰石，石灰，硫酸钙，亚硫酸钙，活性炭，木炭，硅酸盐，氧化铝及其混合物。优选的是飞灰，活性炭和二氧化硅。

8. 发明授权

US06297189B1 Sulfide catalysts for reducing SO2 to elemental sulfur 失效
公开(公告)号：US06297189B1
公开(公告)日：2001-10-02
申请号：US09006702
申请日：1998-01-14
申请人： Yun Jin , Qiquan Yu , Shih-Ger Chang
发明人： Yun Jin , Qiquan Yu , Shih-Ger Chang
IPC分类号： B01J27055
CPC分类号： B01J27/049 , B01D53/8609 , B01J27/043 , B01J27/0515 , B01J37/20 , C01B17/0473 , C01B17/0491
摘要： A highly efficient sulfide catalyst for reducing sulfur dioxide to elemental sulfur, which maximizes the selectivity of elemental sulfur over byproducts and has a high conversion efficiency. Various feed stream contaminants, such as water vapor are well tolerated. Additionally, hydrogen, carbon monoxide, or hydrogen sulfides can be employed as the reducing gases while maintaining high conversion efficiency. This allows a much wider range of uses and higher level of feed stream contaminants than prior art catalysts.

9. 发明授权

US5658545A Metal regeneration of iron chelates in nitric oxide scrubbing 失效
标题翻译：一氧化氮洗涤中铁螯合物的金属再生
公开(公告)号：US5658545A
公开(公告)日：1997-08-19
申请号：US412706
申请日：1995-03-29
申请人： Shih-Ger Chang , David Littlejohn , Yao Shi
发明人： Shih-Ger Chang , David Littlejohn , Yao Shi
IPC分类号： B01D53/56 , B01D53/96 , C01C1/04 , C21B3/04 , B01J8/00
CPC分类号： B01D53/96 , B01D53/56 , C01C1/04 , C21B3/04 , Y02P10/143 , Y02P10/216 , Y02W30/542
摘要： The present invention relates to a process of using metal particles to reduce NO to NH.sub.3. More specifically, the invention concerns an improved process to regenerate iron (II) (CHELATE) by reduction of iron (II) (CHELATE) (NO) complex, which process comprises: a) contacting an aqueous solution containing iron (II) (CHELATE) (NO) with metal particles at between about 20.degree. and 90.degree. C. to reduce NO present, produce ammonia or an ammonium ion, and produce free iron (II) (CHELATE) at a pH of between about 3 and 8. The process is useful to remove NO from flue gas and reduce pollution.
摘要翻译：本发明涉及使用金属颗粒将NO还原成NH 3的方法。更具体地，本发明涉及通过还原铁（II）（CHELATE）（NO）络合物来再生铁（II）（CHELATE）的改进方法，该方法包括：a）使含有铁（II）（CHELATE））（NO）与金属颗粒在约20-90℃之间以减少NO存在，产生氨或铵离子，并且在约3至8的pH下产生游离的铁（II）（CHELATE）。过程有助于从烟道气中去除NO，减少污染。

10. 发明授权

US5494879A Catalyst for the reduction of sulfur dioxide to elemental sulfur 失效
标题翻译：用于将二氧化硫还原成元素硫的催化剂
公开(公告)号：US5494879A
公开(公告)日：1996-02-27
申请号：US23765
申请日：1993-02-26
申请人： Yun Jin , Qiquan Yu , Shih-Ger Chang
发明人： Yun Jin , Qiquan Yu , Shih-Ger Chang
IPC分类号： B01J23/74 , B01J23/76 , B01J23/88 , B01J23/887 , B01J37/02 , C01B17/04 , B01J23/745 , B01J23/80 , B01J23/881
CPC分类号： B01J23/8878 , B01J23/74 , B01J23/76 , B01J37/0201 , C01B17/0434 , C01B17/0478 , C01B17/0491
摘要： The inventive catalysts allow for the reduction of sulfur dioxide to elemental sulfur in smokestack scrubber environments. The catalysts have a very high sulfur yield of over 90% and space velocity of 10,000 h.sup.-1. They also have the capacity to convert waste gases generated during the initial conversion into elemental sulfur. The catalysts have inexpensive components, and are inexpensive to produce. The net impact of the invention is to make this technology practically available to industrial applications.
摘要翻译：本发明的催化剂允许在烟熏洗涤器环境中将二氧化硫还原成元素硫。催化剂具有超过90％的非常高的硫产率和10,000h -1的空速。它们还具有将初始转化期间产生的废气转化成元素硫的能力。催化剂具有廉价的组分，并且生产成本便宜。本发明的净影响是使该技术实际上可用于工业应用。

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