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    • 1. 发明授权
    • Process for the conversion of coal
    • 煤转化工艺
    • US4331530A
    • 1982-05-25
    • US881233
    • 1978-02-27
    • Shaik A. Qader
    • Shaik A. Qader
    • C10G1/08C10G1/06
    • C10G1/08
    • A process for the hydrogenation of coal and subsequent treatment of hydrogenated coal to produce useful fuels and chemicals which comprises comminuting coal ore to a particle size range of from about 150 mesh to about 250 mesh; hydrogenating the particulate coal in the presence of a hydrogenation catalyst and a source of hydrogen at a temperature of from about 100.degree. to about 300.degree. C. and a pressure of from about 500 to about 1,000 psi for a time sufficient to react hydrogen with the coal to form predominantly hydroaromatic coal; and recovering the hydrogenated coal. The hydrogenated coal is subsequently hydrocracked or pyrolyzed. The hydrogenated coal is hydrocracked at from about 500.degree. to about 700.degree. C. a pressure of from about 500 to about 2,000 psi for a time sufficient to crack the coal to produce benzene, toluene, xylene and gasoline. The hydrogenated coal is pyrolyzed at from about 400.degree. to about 700.degree. C., at a pressure of about atmospheric pressure and for a time sufficient to convert the coal to C.sub.1 -C.sub.4 gaseous hydrocarbons, naphtha and tar.
    • 一种用于氢化氢和随后处理氢化煤以产生有用的燃料和化学品的方法,其包括将煤矿粉碎至约150目至约250目的粒度范围; 在约100至约300℃的温度和约500至约1,000psi的压力下,在氢化催化剂和氢源存在下使颗粒煤氢化足够时间以使氢与 煤主要形成水芳烃煤; 并回收氢化煤。 氢化煤随后加氢裂化或热解。 氢化煤在约500至约700℃下加压裂化,压力为约500至约2,000psi,时间足以裂解煤以产生苯,甲苯,二甲苯和汽油。 氢化煤在约400℃至约700℃下在约大气压的压力下热解,并持续足够时间将煤转化为C1-C4气态烃,石脑油和焦油。
    • 2. 发明授权
    • Solar heated oil shale pyrolysis process
    • 太阳能加热油页岩热解过程
    • US4582590A
    • 1986-04-15
    • US633363
    • 1984-07-23
    • Shaik A. Qader
    • Shaik A. Qader
    • B01J19/12C10B49/06C10B53/06C10G1/02
    • C10B49/06B01J19/127C10B53/06C10G1/02Y02P20/129Y10S48/09
    • A bed (76, 202) of oil shale particles (10) are pyrolyzed in a retort (70, 200) by means of a heated carrier gas stream passing through a central conduit (54, 202) within the bed (76, 202) and then upwardly through a fixed bed (76) or fluidized bed (202) of the shale. The shale is subjected to pyrolysis and evolves kerogen liquid, thermally and pyrolyzed liquids and gases which enter the carrier gas to form a pyrolysis gas. The liquid pyrolysis oil is separated from the pyrolysis gas ion separator (94, 224) and a portion of the separated gas is recycled to a solar heat exchanger (50, 204) and heated to a temperature of at least 350.degree. C. before being fed to the central conduit (54, 202).
    • 油页岩颗粒(10)的床(76,202)通过穿过床(76,202)内的中心导管(54,202)的加热的载气流在蒸馏器(70,200)中热解, 然后向上通过页岩的固定床(76)或流化床(202)。 页岩经受热解并产生干酪根液体,热和热解的液体和进入载气的气体,形成裂解气。 将液体热解油与热解气体离子分离器(94,224)分离,并将一部分分离的气体再循环至太阳能热交换器(50,204),并加热到至少350℃的温度 馈送到中心导管(54,202)。