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    • 2. 发明授权
    • Silver halide color photographic material
    • 卤化银彩色照相材料
    • US5460929A
    • 1995-10-24
    • US45776
    • 1993-04-14
    • Satoshi NagaokaKazuyoshi YamakawaMitsuru YamamotoMakoto SuzukiYasuhiro ShimadaKatsuro NagaokaHideo IkedaTakefumi HaraSadanobu Shuto
    • Satoshi NagaokaKazuyoshi YamakawaMitsuru YamamotoMakoto SuzukiYasuhiro ShimadaKatsuro NagaokaHideo IkedaTakefumi HaraSadanobu Shuto
    • G03C1/14G03C7/30G03C7/305G03C7/38G03C1/46
    • G03C7/30511G03C1/14G03C7/3041G03C7/3825
    • There is disclosed a silver halide color photographic material having a red-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer, a blue-sensitive silver halide emulsion layer, which comprises a cyan dye-forming coupler represented by formula (Ia) and (a) a sensitizing dye containing a sulfonamide group, (b) negative-type internal latent image-type silver halide grains chemically sensitized to a defined depth from the surface, (c) grains each having a defined spectral sensitivity distribution and a DIR-hydroquinone, (d) a monodisperse silver halide emulsion, (e) non-photosensitive silver halide emulsion wherein the inside or the surface of grains is fogged, (f) a colloidal silver, or (g) a DIR-hydroquinone: ##STR1## wherein Za represents --NH-- or --CH(R.sub.3)--, Zb and Zc each represent --C(R.sub.4).dbd. or --N.dbd., R.sub.1, R.sub.2, and R.sub.3 each represent an electron-attracting group wherein the Hammett substituent constant .sigma..sub.p value is 0.20 or more, provided that the sum of the .sigma..sub.p value of R.sub.1 and the .sigma..sub.p value of R.sub.2 is 0.65 or more, R.sub.4 represents a hydrogen atom or a substituent, if there are two groups R.sub.4 in the formula, they may be the same or different, and X represents a hydrogen atom or a group capable of being released upon a coupling reaction with the oxidized product of an aromatic primary amine color-developing agent, provided that R.sub.1, R.sub.2, R.sub.3, R.sub.4, or X may be a divalent group to form a homopolymer or a copolymer by bonding with a dimer or higher polymer or polymer chain.
    • 公开了具有感红卤化银乳剂层,感绿卤化银乳剂层,感蓝卤化银乳剂层的卤化银彩色照相材料,其包含由式(Ia)表示的形成青色染料的成色剂 )和(a)含有磺酰胺基团的增感染料,(b)从表面定义的深度化学敏化的负型内部潜像型卤化银颗粒,(c)各自具有确定的光谱灵敏度分布的颗粒和 DIR-氢醌,(d)单分散卤化银乳剂,(e)非光敏卤化银乳剂,其中颗粒的内部或表面起雾,(f)胶体银,或(g)DIR-氢醌:NH - 或-CH(R3) - ,Zb和Zc各自表示-C(R4)=或-N =,R1,R2和R3各自表示吸电子基团,其中哈米特取代基常数σp值为0.20以上 ,条件是R1的sigma p值和sigm的总和 R2的ap值为0.65以上,R4表示氢原子或取代基,如果式中有两个基团R 4,它们可以相同或不同,X表示氢原子或能够被释放的基团 与芳族伯胺显色剂的氧化产物的偶联反应,条件是R1,R2,R3,R4或X可以是二价基团,以通过与二聚体或更高级聚合物的键合形成均聚物或共聚物,或 聚合物链。
    • 3. 发明授权
    • Silver halide color photographic material comprising at least one
DIR-hydroquinone compound, and having a total silver content of less
than 1.0 g/m.sup.2
    • 包含至少一种DIR-氢醌化合物,并且总银含量小于1.0g / m 2的卤化银彩色照相材料
    • US5310638A
    • 1994-05-10
    • US783113
    • 1991-10-25
    • Sadanobu ShutoTakashi Ozawa
    • Sadanobu ShutoTakashi Ozawa
    • G03C7/30G03C7/305G03C1/46
    • G03C7/3022G03C7/30511Y10S430/158
    • A silver halide color photographic material comprises a support, a blue sensitive layer, a green sensitive layer and a red sensitive layer. The total silver content of the photographic material is not more than 1.0 g/m.sup.2. The photographic material further contains a compound represented by the formula (1a) or (1b): ##STR1## in which R.sup.12 is an aliphatic group, an aromatic group or a heterocyclic group; M is --CO--, --SO.sub.2 --, --N(R.sup.15)CO--, --OCO-- or --N(R.sup.15)SO.sub.2 --; each of R.sup.14, R.sup.15 and R.sup.24 independently is hydrogen, an alkyl group or an aryl group; L is a divalent linking group necessary for forming a 5, 6 or 7-membered ring; each of R.sup.11, R.sup.13 and R.sup.21 independently is hydrogen or a substituent group of the hydroquinone nucleus; Time is a group which is released from the oxidation product of the hydroquinone nucleus to further release X; X is a development inhibitor; and t is 0 or 1. M preferably is --SO.sub.2 --, --N(R.sup.15)CO--, --OCO-- or --N(R.sup.15)SO.sub.2 --.
    • 卤化银彩色照相材料包括载体,感蓝敏感层,感绿层和红色敏感层。 照相材料的总银含量不超过1.0g / m 2。 照相材料还含有式(1a)或(1b)表示的化合物:其中R 12是脂族基团,芳族基团或杂环基团; M是-CO - , - SO 2 - , - N(R 15)CO - , - OCO-或-N(R 15)SO 2 - ; R 14,R 15和R 24各自独立地为氢,烷基或芳基; L是形成5,6或7-元环所必需的二价连接基团; R11,R13和R21各自独立地为氢或氢醌核的取代基; 时间是从氢醌核的氧化产物释放出来进一步释放X的基团; X是开发抑制剂; 并且t为0或1.M优选为-SO 2 - , - N(R 15)CO - , - OCO-或-N(R 15)SO 2 - 。
    • 4. 发明授权
    • Method of processing silver halide color photographic materials
    • 卤化银彩色照相材料的处理方法
    • US5266448A
    • 1993-11-30
    • US858658
    • 1992-03-27
    • Sadanobu ShutoTakatoshi Ishikawa
    • Sadanobu ShutoTakatoshi Ishikawa
    • G03C5/30G03C5/50G03C7/30G03C7/46
    • G03C5/50G03C7/3022Y10S430/141
    • A method for color reversal processing of an imagewise exposed silver halide color photographic material comprising first developing in a black-and-white developing bath, next color developing in a color developing bath, and then desilvering in a bath having a bleaching ability. The black-and-white developing bath has a bromide concentration in the range of 0.025 to 0.1 mol/l and is used for the black-and-white development. Furthermore, in a preferred embodiment, the photographic material comprises at least one silver halide emulsion layer containing a silver halide emulsion comprising silver halide grains having an average grain size of 0.3 .mu.m or less. In accordance with the invention, the maximum densities of the developed color images are increased without lowering of the sensitivity and contrast.
    • 一种成像曝光的卤化银彩色照相材料的颜色反转处理方法,包括首先在黑白显影浴中显影,接着在彩色显影浴中显色,然后在具有漂白能力的浴中脱溶剂。 黑白显影浴的溴化物浓度范围为0.025〜0.1mol / l,用于黑白显影。 此外,在优选实施方案中,照相材料包含至少一种含有卤化银乳剂的卤化银乳剂层,该卤化银乳剂包含平均粒度为0.3μm或更小的卤化银颗粒。 根据本发明,显影的彩色图像的最大密度在不降低灵敏度和对比度的情况下增加。
    • 6. 发明授权
    • Process for processing a color reversal photographic light-sensitive
material
    • 处理彩色反转照相感光材料的方法
    • US4717648A
    • 1988-01-05
    • US827138
    • 1986-02-07
    • Shinji UedaJunya NakajimaTadao ShishidoSadanobu Shuto
    • Shinji UedaJunya NakajimaTadao ShishidoSadanobu Shuto
    • G03C5/305G03C7/16G03C5/24G03C5/50
    • G03C5/305
    • A process for processing a silver halide color reversal photographic light-sensitive material is disclosed, which comprises developing an imagewise exposed silver halide color reversal photographic light-sensitive material with a black-and-white developer containing at least one compound selected from the compounds of Group A, at least one compound selected from the compounds of Group B, and preferably further at least one compound selected from the compounds of Group C, whereinGroup A consists of organic heterocyclic compounds represented by formulae (A-I), (A-II), (A-III), and (A-IV) ##STR1## Group B consists of benzoimidazole, indazole, benzotriazole, benzooxazole and benzothiazole compounds, not containing a thiol group, a thioether bond, a thioketone group, or a disulfide bond.Group C consists of compounds represented by formulae (C-I) and (C-II). ##STR2## wherein the symbols are as defined in the appended claims.
    • 公开了一种处理卤化银彩色反转照相感光材料的方法,其包括用含有至少一种选自以下化合物的黑白显影剂显影成像曝光的卤化银彩色反转照相感光材料: A组,选自B组化合物的至少一种化合物,优选至少一种选自C组化合物的化合物,其中A组由式(AI),(A-II)表示的有机杂环化合物组成, (A-III)和(A-IV)组合物(A-IV)(A-IV)(A-IV) ,苯并三唑,苯并恶唑和苯并噻唑化合物,不含硫醇基,硫醚键,硫酮基或二硫键。 C组由式(C-I)和(C-II)表示的化合物组成。 (C-I)(C-II)其中符号如所附权利要求中所定义。