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1. 发明申请

US20140231641A1 GENERATION OF MODEL OF COMPOSITION OF PETROLEUM BY HIGH RESOLUTION MASS SPECTROMETRY AND ASSOCIATED ANALYTICS 有权
标题翻译：通过高分辨质谱分析和相关分析法生成石油组合物模型
公开(公告)号：US20140231641A1
公开(公告)日：2014-08-21
申请号：US14178627
申请日：2014-02-12
申请人： Kuangnan QIAN , Kathleen E EDWARDS , Anthony S. MENNITO , Roland B. SAEGER
发明人： Kuangnan QIAN , Kathleen E EDWARDS , Anthony S. MENNITO , Roland B. SAEGER
IPC分类号： H01J49/00
CPC分类号： H01J49/0027 , G01N33/2835
摘要： A method to determine the model-of-composition of a vacuum resid in which the resid is separated into fractions including the DAO fraction which is then separated into chemical classes including saturates, aromatics, sulfides and polars by a combination of soft ionization methods. The results of the ionization analyses are reconciled with other analyses such as bulk analysis, then consolidated to generate the modeol-of composition.
摘要翻译：确定真空渣油的组成模型的方法，其中残渣分离成包含DAO馏分的级分，然后通过软电离方法的组合将其分离成化学类别，包括饱和物，芳族化合物，硫化物和极性。电离分析的结果与其他分析如批量分析相协调，然后合并生成组分的模式。

2. 发明申请

US20130325418A1 SYSTEM AND METHOD TO GENERATE MOLEDULAR FORMULA DISTRIBUTIONS BEYOND A PREDETERMINED THRESHOLD FOR A PETROLEUM STREAM 审中-公开
标题翻译：用于生成石油流体的预测阈值的公式分布的系统和方法
公开(公告)号：US20130325418A1
公开(公告)日：2013-12-05
申请号：US13834864
申请日：2013-03-15
申请人： Roland B. SAEGER , Kaiyuan HE
发明人： Roland B. SAEGER , Kaiyuan HE
IPC分类号： G06F19/00
CPC分类号： G06F19/701 , G01N33/2823 , G06F19/704
摘要： Methods for generating molecular formula distributions beyond a predetermined threshold for a petroleum stream are disclosed. An initial molecular formula distribution within a predetermined threshold is obtained for a petroleum stream. A correlation between two or more molecular properties of the initial molecular formula distribution is identified, and the initial molecular formula distribution is extrapolated beyond the predetermined threshold along the correlation. The extrapolated molecular formula is renormalized based on renormalized based on renormalization data obtained from the sample. The renormalized molecular formula distribution can then be blended with the initial molecular formula distribution, reconciled to secondary analytical measurements, and/or used to create a model of composition and/or a molecular composition-based model of a resid upgrading process. Systems for implementing the methods are also disclosed.
摘要翻译：公开了用于产生超过石油流的预定阈值的分子式分布的方法。对石油流获得预定阈值内的初始分子式分布。确定初始分子式分布的两种或更多种分子性质之间的相关性，并且初始分子式分布沿相关性外推超过预定阈值。基于从样品获得的重整化数据，外推分子式被重新归一化。然后将重整化的分子式分布与初始分子式分布混合，与二次分析测量相协调，和/或用于创建残留物升级过程的组成模型和/或基于分子组合的模型。还公开了用于实现方法的系统。

3. 发明申请

US20130325362A1 METHOD FOR RECONCILING A MODEL OF COMPOSITION 审中-公开
标题翻译：重构组合物模型的方法
公开(公告)号：US20130325362A1
公开(公告)日：2013-12-05
申请号：US13832747
申请日：2013-03-15
申请人： Roland B. Saeger , Kaiyuan He
发明人： Roland B. Saeger , Kaiyuan He
IPC分类号： G01N33/28
CPC分类号： G01N33/2835 , G01N33/2823 , G06F19/704
摘要： Method for determining the composition of a material, including obtaining a reference model of composition (MoC) of the material based on a molecular formula distribution of the material, and reconciling, using at least one computer processor, the reference MoC to match at least one target property of the material, is provided. The reference MoC can be expressed as a combination of molecular lumps with associated reference percent. The reconciliation can be carried out using by constrained optimization of information entropy, and the optimization can be performed on a more coarse-grained basis relative to the reference MoC.
摘要翻译：用于确定材料组成的方法，包括基于所述材料的分子式分布获得所述材料的组成参考模型（MoC），以及使用至少一个计算机处理器调整所述参考MoC以匹配至少一个提供材料的目标性能。参考MoC可以表示为具有相关参考百分比的分子块的组合。可以通过信息熵的约束优化来进行协调，并且相对于参考MoC可以以更粗粒度的基础执行优化。

4. 发明授权

US6082118A Storage and transport of gas hydrates as a slurry suspenion under metastable conditions 失效
标题翻译：在亚稳态条件下储存和运输天然气水合物作为浆液悬浮液
公开(公告)号：US6082118A
公开(公告)日：2000-07-04
申请号：US111212
申请日：1998-07-07
申请人： Fred P. Endrizzi , Robert F. Heinemann , David Da-Teh Huang , Jinping Long , Roland B. Saeger , Anthony A. Urbanelli
发明人： Fred P. Endrizzi , Robert F. Heinemann , David Da-Teh Huang , Jinping Long , Roland B. Saeger , Anthony A. Urbanelli
IPC分类号： F17C11/00 , C07C9/00
CPC分类号： F17C11/007
摘要： A suitable slurry composition allows gas hydrates to be stored or transported under metastable conditions. The slurry includes gas hydrate particles and a carrier liquid for the gas hydrate particles. Suitable carrier liquids have a specific gravity in the range from about 0.6 to about 2, a pour point below about -20.degree. C. a viscosity of about 10 centipoise or less, and a thermal conductivity lower than that of the gas hydrate particles. The slurry can be stored or transported in a system that includes a container for holding the slurry; a device for agitating the slurry while in the container (e.g., a mixing blade, a rotating screw, a reciprocating box beam, or an ultrasound generator); a device for removing excess carrier liquid from the container while it is loaded or being loaded with gas hydrates and/or carrier liquid (e.g., a skimming device or a drain); and a device for reslurrifying the gas hydrates with carrier liquid before or during unloading of the gas hydrates from the container (e.g., a carrier liquid injection nozzle).
摘要翻译：合适的浆料组合物允许气体水合物在亚稳态下储存或运输。浆料包括气体水合物颗粒和用于气体水合物颗粒的载体液体。合适的载体液体的比重在约0.6至约2的范围内，倾点低于约-20℃，粘度为约10厘泊或更小，导热率低于气体水合物颗粒的热导率。浆料可以在包括用于保持浆料的容器的系统中储存或运输; 在容器（例如混合叶片，旋转螺杆，往复式箱梁或超声波发生器）中搅拌浆料的装置; 用于在装载或装载气体水合物和/或载体液体（例如撇取装置或排水管）时从容器中除去多余载液的装置; 以及用于在从容器（例如，载液注射喷嘴）卸载气体水合物之前或期间，用载液使气体水合物再次充气的装置。

5. 发明申请

US20120153139A1 GENERATION OF MODEL-OF-COMPOSITION OF PETROLEUM BY HIGH RESOLUTION MASS SPECTROMETRY AND ASSOCIATED ANALYTICS 审中-公开
标题翻译：通过高分辨质谱分析和相关分析法生成石油模型
公开(公告)号：US20120153139A1
公开(公告)日：2012-06-21
申请号：US13167816
申请日：2011-06-24
申请人： Kuangnan Qian , Kathleen E. Edwards , Anthony S. Mennito , Roland B. Saeger
发明人： Kuangnan Qian , Kathleen E. Edwards , Anthony S. Mennito , Roland B. Saeger
IPC分类号： H01J49/26
CPC分类号： H01J49/0027 , G01N33/2835
摘要： A method to determine the model-of-composition of a vacuum resid wherein the resid is separated into eight fractions, saturates, aromatics, sulfides and polars by a combination of soft ionization methods.
摘要翻译：确定真空渣油的组成模型的方法，其中通过软电离方法的组合将残渣分离成八个馏分，饱和物，芳烃，硫化物和极性物。

6. 发明授权

US09625439B2 Method for reconciling a model of composition 有权
公开(公告)号：US09625439B2
公开(公告)日：2017-04-18
申请号：US13832747
申请日：2013-03-15
申请人： Roland B Saeger , Kaiyuan He
发明人： Roland B Saeger , Kaiyuan He
IPC分类号： G01N33/28 , G06F19/00
CPC分类号： G01N33/2835 , G01N33/2823 , G06F19/704
摘要： Method for determining the composition of a material, including obtaining a reference model of composition (MoC) of the material based on a molecular formula distribution of the material, and reconciling, using at least one computer processor, the reference MoC to match at least one target property of the material, is provided. The reference MoC can be expressed as a combination of molecular lumps with associated reference percent. The reconciliation can be carried out using by constrained optimization of information entropy, and the optimization can be performed on a more coarse-grained basis relative to the reference MoC.

7. 发明授权

US07598487B2 Micro-hydrocarbon analysis 有权
标题翻译：微量烃分析
公开(公告)号：US07598487B2
公开(公告)日：2009-10-06
申请号：US11598873
申请日：2006-11-14
申请人： Kuangnan Qian , William N. Olmstead , Jason B. English , Larry A. Green , Roland B. Saeger , Stephen B. Jaffe
发明人： Kuangnan Qian , William N. Olmstead , Jason B. English , Larry A. Green , Roland B. Saeger , Stephen B. Jaffe
IPC分类号： G01N30/02 , G01N31/00
CPC分类号： G01N33/28 , G01N30/7206 , G01N2030/8854
摘要： The present invention is a method to determine the composition of a hydrocarbon feedstream from a small sample of hydrocarbons including the steps analyzing the sample with a combination of chromatograph and mass spectrometer, and reconciling output from step a) with other analytical measurements to determine to determine the composition of the hydrocarbon feedstream.
摘要翻译：本发明是一种从小型烃类样品中确定烃类进料流的组成的方法，包括用色谱仪和质谱仪的组合分析样品的步骤，以及调节步骤a）的输出与其他分析测量结果，以确定烃进料流的组成。

8. 发明授权

US06214175B1 Method for recovering gas from hydrates 失效
标题翻译：从水合物中回收气体的方法
公开(公告)号：US06214175B1
公开(公告)日：2001-04-10
申请号：US08774980
申请日：1996-12-26
申请人： Robert F. Heinemann , David Da-Teh Huang , Jinping Long , Roland B. Saeger
发明人： Robert F. Heinemann , David Da-Teh Huang , Jinping Long , Roland B. Saeger
IPC分类号： C07C100
CPC分类号： E21B43/24 , C10L3/06 , E21B36/00 , E21B43/2401 , E21B2043/0115
摘要： The present invention provides a process for recovering gas from a clathrate hydrate comprising the steps of: (a) providing a clathrate hydrate within an occupying zone; (b) positioning a source of electromagnetic radiation within said clathrate hydrate occupying zone; and (c) recovering gas from the clathrate hydrate by applying electromagnetic radiation from the electromagnetic radiation source of step (b) to the clathrate hydrate at a frequency within the range of from direct current to visible light at energy density sufficient to dissociate the clathrate hydrate to evolve its constituent gas.
摘要翻译：本发明提供了一种从笼形水合物中回收气体的方法，包括以下步骤：（a）在占据区内提供笼形水合物;（b）将电磁辐射源定位在所述笼形水合物占据区内; 并且（c）通过将电磁辐射从步骤（b）的电磁辐射源施加到笼形水合物中，从以直接电流到可见光的范围内的频率，以足以解离笼形水合物的能量密度从笼形水合物中回收气体发展其组成气体。

9. 发明授权

US5382743A Skeletal isomerization of n-pentenes using ZSM-35 in the presence of hydrogen 失效
标题翻译：在氢存在下使用ZSM-35对正戊烯的骨架异构化
公开(公告)号：US5382743A
公开(公告)日：1995-01-17
申请号：US51930
申请日：1993-04-26
申请人： James H. Beech, Jr. , Roland B. Saeger , Robert A. Ware
发明人： James H. Beech, Jr. , Roland B. Saeger , Robert A. Ware
IPC分类号： B01J29/40 , C07B61/00 , C07C5/27 , C07C11/10 , C07C5/22
CPC分类号： C07C5/2775
摘要： A method for conversion of linear C5 olefins in the presence of contaminant diolefins to corresponding iso-olefins of the same carbon number which comprises contacting a linear C5 olefin-containing organic feedstock with a catalyst comprising material having the structure of ZSM-35 under skeletal isomerization conditions, wherein said conversion is carried out at temperatures between about 100.degree. and 750.degree. C., weight hourly space velocities (WHSV) based on linear C5 olefins in said feedstock between 0.1 and 500 WHSV, C5 linear olefin partial pressures between 2 and 2000 kPa, and in the presence of hydrogen added in an amount sufficient to enhance linear C5 olefin conversion activity and extend the catalyst life of the catalyst relative to operation without any hydrogen added.
摘要翻译：在存在污染二烯烃的情况下将线性C 5烯烃转化为相同碳数的相应异烯烃的方法，其包括使含有直链C 5烯烃的有机原料与包含具有ZSM-35结构的材料的催化剂在骨架异构化条件，其中所述转化在约100℃和750℃之间的温度下进行，基于在所述原料中的线性C 5烯烃在0.1至500WHSV之间的重小时空速（WHSV），2至2000之间的C5线性烯烃分压 kPa，并且在氢气存在下加入的量足以提高线性C5烯烃转化活性，并延长催化剂相对于操作的催化剂寿命而没有加入任何氢气。

10. 发明授权

US08682597B2 Estimating detailed compositional information from limited analytical data 有权
标题翻译：从有限的分析数据估计详细的组成信息
公开(公告)号：US08682597B2
公开(公告)日：2014-03-25
申请号：US12287541
申请日：2008-10-10
申请人： James M. Brown , Anantha Sundaram , Roland B. Saeger , Helen S. Wellons , Clinton R. Kennedy , Stephen B. Jaffe
发明人： James M. Brown , Anantha Sundaram , Roland B. Saeger , Helen S. Wellons , Clinton R. Kennedy , Stephen B. Jaffe
IPC分类号： G01N31/00
CPC分类号： G01N33/2823
摘要： A method for determining the composition of a material including the steps of fitting multivariate analytical data of the material to a combination of multivariate analytical data in a database to determine coefficients of the combination so as to determine a reference model of composition based on the coefficients and the compositions in the database, wherein the database includes multivariate analytical data of database materials whose compositions are known, and reconciling the reference model of composition to match properties of the material.
摘要翻译：一种用于确定材料的组成的方法，包括以下步骤：将材料的多变量分析数据拟合到数据库中的多变量分析数据的组合，以确定组合的系数，以便基于系数确定组合的参考模型;以及数据库中的组合物，其中数据库包括其组成为已知的数据库材料的多变量分析数据，并且调整组合的参考模型以匹配材料的性质。

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