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1. 发明授权

US5922923A Zeolitic reforming with selective feed-species adjustment 失效
标题翻译：选择性饲料种类调节的沸石重整
公开(公告)号：US5922923A
公开(公告)日：1999-07-13
申请号：US723208
申请日：1996-09-27
申请人： John Y. G. Park , Santi Kulprathipanja , Robert S. Haizmann
发明人： John Y. G. Park , Santi Kulprathipanja , Robert S. Haizmann
IPC分类号： C10G35/095 , C10G61/06 , C07C15/00 , C07C2/52 , C10G35/04
CPC分类号： C10G61/06 , C10G35/095
摘要： The feedstock to an aromatization process is processed by a selective adsorption step to remove hydrocarbon species, particularly indan, which have a severe adverse effect on aromatization catalyst stability. The feedstock preferably is a paraffinic raffinate from aromatics extraction. The intermediate from the adsorption step is particularly suitable for the selective conversion of paraffins to aromatics using a high-activity dehydrocyclization catalyst with high aromatics yields and long catalyst life.
摘要翻译：通过选择性吸附步骤处理芳构化方法的原料以除去对芳构化催化剂稳定性具有严重不利影响的烃类，特别是茚满。原料优选是来自芳烃萃取的链烷烃提余液。来自吸附步骤的中间体特别适用于使用高芳族化合物产率和较长催化剂寿命的高活性脱氢环化催化剂将石蜡选择性转化为芳族化合物。

2. 发明授权

US5472593A BTX from naphtha without extraction 失效
标题翻译： BTX从石脑油无提取
公开(公告)号：US5472593A
公开(公告)日：1995-12-05
申请号：US194964
申请日：1994-02-14
申请人： Christopher D. Gosling , Robert S. Haizmann
发明人： Christopher D. Gosling , Robert S. Haizmann
IPC分类号： C10G35/095 , C10G45/64 , C10G59/02 , C10G35/09
CPC分类号： C10G59/02 , C10G35/095 , C10G45/64
摘要： A hydrocarbon feedstock is catalytically reformed in a sequence comprising a reforming zone containing a catalyst comprising a platinum-group metal and a nonacidic L-zeolite and an aromatics-isomerization zone containing a catalyst comprising a platinum-group metal, a metal attenuator and a refractory inorganic oxide. The process combination features high selectivity in producing a high-purity BTX product from naphtha.
摘要翻译：烃原料以包含含有铂族金属和非酸性L-沸石的催化剂的重整区域和含有包含铂族金属，金属衰减剂和耐火材料的催化剂的芳族化合物 - 异构化区域的顺序催化重整无机氧化物。该方法组合在生产来自石脑油的高纯度BTX产品时具有高选择性。

3. 发明授权

US5270272A Sulfur removal from molecular-sieve catalyst 失效
标题翻译：从分子筛催化剂除硫
公开(公告)号：US5270272A
公开(公告)日：1993-12-14
申请号：US889689
申请日：1992-05-26
申请人： Leonid Galperin , Robert S. Haizmann
发明人： Leonid Galperin , Robert S. Haizmann
IPC分类号： B01J29/90 , B01J38/08 , C10G35/095 , B01J29/38 , B01J38/44
CPC分类号： B01J29/90 , B01J38/08 , C10G35/095 , Y10S502/517
摘要： A sulfur-sensitive catalyst which has been deactivated by accumulating sulfur on the catalyst is desulfurized by contact with ammonia at high temperature. The technique is particularly effective for reforming catalysts containing a large-pore zeolite which are selective for dehydrocyclization of paraffins. The desulfurization may be combined with regeneration for coke removal from the catalyst.
摘要翻译：已经通过在催化剂上积累硫而失活的硫敏感催化剂通过在高温下与氨接触进行脱硫。该技术对于重整含有对链烷烃的脱氢环化有选择性的大孔沸石的催化剂是特别有效的。脱硫可以与从催化剂中除去焦炭的再生相结合。

4. 发明授权

US5107052A Extraction of dimethyl paraffins from isomerates 失效
标题翻译：从异构体中提取二甲基链烷烃
公开(公告)号：US5107052A
公开(公告)日：1992-04-21
申请号：US636646
申请日：1990-12-31
申请人： Beth McCulloch , James R. Lansbarkis , Srikantiah Raghuram , Robert S. Haizmann
发明人： Beth McCulloch , James R. Lansbarkis , Srikantiah Raghuram , Robert S. Haizmann
IPC分类号： C07C5/27 , C07C7/13 , C07C9/00 , C10G25/03 , C10G61/06
CPC分类号： C10G61/06 , C07C5/2767 , C07C7/13 , C07C9/00 , C10G25/03
摘要： The invention relates to the production of high octane fuels including a process for separating the high octane components for the gasoline pool from lower octane components, which are recycled to an isomerization reaction by adsorptively separating dimethyl paraffins from an isomerate with an aluminophosphate zeolite and SSZ-24, an all-silica zeolite adsorbent isostructural with AIPO.sub.4 -5, and a C.sub.6-10 normal paraffin desorbent. The lower octane components of the isomerate, normal paraffins and mono-branched paraffins, are recycled to the isomerization reaction zone for further conversion to multi-branched paraffins. The useful aluminophosphates are SAPO-5, AIPO.sub.4 -5 MgAPO-5 and MAPSO-5.
摘要翻译：本发明涉及高辛烷值燃料的生产，包括通过用磷酸铝沸石和SSZ-沸石从异构体中吸附分离二甲基链烷烃而再循环到异构化反应中将汽油池的高辛烷值成分从低级辛烷成分中分离出来的方法， 24，与AIPO4-5同构结构的全硅沸石吸附剂和C6-10正常石蜡解吸剂。异构体，正链烷烃和单支链烷烃的低辛烷值组分被再循环到异构化反应区，用于进一步转化为多支链链烷烃。有用的磷酸铝是SAPO-5，AIPO4-5 MgAPO-5和MAPSO-5。

5. 发明授权

US5045175A Separation system for C.sub.4 hydrotreater effluent having reduced hydrocarbon loss 失效
标题翻译：具有降低碳氢化合物损失的C4加氢处理器流出物的分离系统
公开(公告)号：US5045175A
公开(公告)日：1991-09-03
申请号：US600790
申请日：1990-10-22
申请人： Robert S. Haizmann , Andrew S. Zarchy , Martin F. Symoniak
发明人： Robert S. Haizmann , Andrew S. Zarchy , Martin F. Symoniak
IPC分类号： C10G67/06
CPC分类号： C10G67/06
摘要： A hydrotreating process uses a separation section that reduces the loss of C.sub.4 and higher hydrocarbons through the use of a low hydrogen to hydrocarbon ratio in the reactor and the adsorptive removal of a majority of hydrogen sulfide from a liquid phase hydrotreater effluent. Sulfurous hydrocarbon feed is admixed with hydrogen to maintain a hydrogen to hydrocarbon ratio of less than 50 SCFB. The hydrogen and hydrocarbons are passed through a hydrotreater reactor to convert sulfur compounds to H.sub.2 S. The hydrotreater effluent is cooled and after flashing of any excess hydrogen or light ends the cooled effluent is contacted with an adsorbent material for the removal of H.sub.2 S. A hydrotreated hydrocarbon product is withdrawn from the adsorption section. The low hydrogen to hydrocarbon ratio permits the process to be used without the recycle of hydrogen thereby eliminating the need for separators and compressors that were formly used to recycle hydrogen to the hydrotreater. The elimination of the recycle and the low hydrogen to hydrocarbon ratio simplifies the flowscheme which can use a simple separator to flash light ends, hydrogen and some H.sub.2 S from the hydrotreater effluent. This process thus eliminates the need for a stripping section that was formerly needed to remove light ends and hydrogen sulfide from the hydrotreated product. The adsorptive removal of the H.sub.2 S and the limited venting of hydrogen allows essentially all of the hydrotreated product to be preserved. In most flowschemes H.sub.2 S removal can be carried out in the adsorbers that are usually present for drying of the hydrotreated feed.
摘要翻译：加氢处理方法使用分离段，其通过在反应器中使用低的氢烃比例降低C4和高级烃的损失，并从液相加氢处理器流出物中吸附除去大部分硫化氢。亚硫酸烃进料与氢气混合以保持氢与烃的比例小于50SCFB。氢气和烃通过加氢处理反应器将硫化合物转化为H 2 S。加氢处理器流出物被冷却并且在闪蒸过量的氢气或轻馏分之后，冷却的流出物与用于除去H 2 S的吸附材料接触。加氢处理的烃产物从吸附段中排出。低氢烃比可以使得该方法不用氢再循环使用，从而消除了对正式用于将氢循环到加氢处理塔中的分离器和压缩机的需要。循环利用和低氢烃比的消除简化了可以使用简单分离器从加氢处理器流出物中闪蒸轻馏分，氢气和一些H 2 S的流程。因此，该方法不需要先前需要从加氢处理的产物中除去轻馏分和硫化氢的汽提部分。 H2S的吸附去除和氢的有限排放允许基本上所有的加氢处理产物被保存。在大多数流程中，可以在通常用于干燥加氢处理的进料的吸附器中进行H 2 S的去除。

6. 发明授权

US5043525A Paraffin isomerization and liquid phase adsorptive product separation 失效
标题翻译：石蜡异构化和液相吸附产物分离
公开(公告)号：US5043525A
公开(公告)日：1991-08-27
申请号：US560655
申请日：1990-07-30
申请人： Robert S. Haizmann , Frederick M. Hibbs , Srikantiah Raghuram
发明人： Robert S. Haizmann , Frederick M. Hibbs , Srikantiah Raghuram
IPC分类号： C10G61/06 , C10G67/06 , C10L1/06
CPC分类号： C10L1/06 , C10G61/06 , C10G2400/02
摘要： A combination isomerization and liquid phase adsorptive separation process is given increased efficiency and cost effectiveness while also improving the product quality by eliminating the columns for the separation of desorbent material from extract and raffinate streams. In this arrangement a C.sub.5 + naphtha stream is split into a heavy hydrocarbon stream comprising normal hexane and higher boiling hydrocarbons and an isomerization zone feedstream comprising isohexane and lower boiling hydrocarbons. The heavy hydrocarbon stream goes directly to a deisohexanizer column. The isomerization zone feedstream is combined with an excess desorbent stream and the extract stream from an adsorptive separation section to form a combined feed. Hydrocarbons in the combined feed are isomerized and after stabilization pass directly into the adsorption section. In the adsorption section, normal pentanes are selectively adsorbed on an adsorbent material, and a raffinate stream comprising desorbent and isoparaffins is passed to the deisohexanizer column and supplies the desorbent for the adsorption section. Any desorbent in excess of that required for the adsorption section is combined with the isomerization zone feed. The extract stream that is combined with the isomerization zone feed is recovered from adsorption section. A bottoms stream comprising C.sub.7 and higher boiling hydrocarbons is withdrawn from the bottom of the deisohexanizer column. A high octane isomerate is taken overhead from the deisohexanizer as a product stream.
摘要翻译：提供组合异构化和液相吸附分离方法提高了效率和成本效益，同时通过消除用于从萃取液和萃余液流中分离解吸剂材料的柱来提高产品质量。在这种布置中，将C5 +石脑油流分解成包含正己烷和较高沸点烃的重质烃流以及包含异己烷和低沸点烃的异构化区进料流。重质烃流直接进入脱乙烷塔。异构化区进料流与过量的解吸剂流和来自吸附分离部分的萃取物流组合以形成组合进料。合并的进料中的烃异构化，稳定后直接进入吸附段。在吸附部分，常规的戊烷被选择性地吸附在吸附剂材料上，并且包含解吸剂和异链烷烃的萃余液流被送到脱乙烷塔中并提供用于吸附段的解吸剂。超过吸附段所需的任何解吸剂与异构化区进料组合。与异构化区进料结合的萃取物流从吸附段回收。包含C7和更高沸点烃的底部物流从脱乙酸塔的底部排出。作为产物流，从脱乙酸酯塔顶馏去高辛烷异构体。

7. 发明授权

US5017541A Catalyst for the isomerization of alkanes 失效
公开(公告)号：US5017541A
公开(公告)日：1991-05-21
申请号：US544569
申请日：1990-06-27
申请人： Robert J. Schmidt , Robert S. Haizmann , Mark R. Ford , C. David Low , Frank H. Adams
发明人： Robert J. Schmidt , Robert S. Haizmann , Mark R. Ford , C. David Low , Frank H. Adams
IPC分类号： B01J23/42 , B01J27/08 , C07C5/22 , C10G35/085
CPC分类号： B01J23/42 , B01J27/08 , C07C5/226 , C10G35/085 , C07C2523/40 , C07C2527/08
摘要： An improved catalyst particle is disclosed for the conversion of hydrocarbons which comprises a refractory inorganic-oxide support, a Friedel-Crafts metal halide, and a surface-layer platinum-group metal component, wherein the concentration of platinum-group metal component on the surface layer of each catalyst particle is at least 1.5 times the concentration in the central core of the catalyst particle. An isomerization process also is disclosed which is particularly effective for the conversion of C.sub.4 -C.sub.7 alkanes.

8. 发明授权

US4929794A Hydrotreatment-isomerization without hydrogen recycle 失效
标题翻译：无氢循环的加氢处理异构化
公开(公告)号：US4929794A
公开(公告)日：1990-05-29
申请号：US292034
申请日：1988-12-30
申请人： Robert J. Schmidt , Robert S. Haizmann
发明人： Robert J. Schmidt , Robert S. Haizmann
IPC分类号： C07C5/27 , C10G49/00 , C10G65/04
CPC分类号： C10G65/043 , C07C5/2724 , C10G49/007
摘要： A combined process for hydrotreating and isomerizing a C.sub.4 -C.sub.7 feedstock is simplified and made more efficient by the use of a common hydrogen source and low hydrogen to hydrocarbon ratio in both the hydrotreating and isomerization steps of the invention. The method supplies hydrogen to a combined hydrotreatment and isomerization process for the isomerization of a feed stream comprising C.sub.4 -C.sub.7 hydrocarbons. The hydrocarbon feed stream contains sulfur and oxygen contaminants and is combined with a hydrogen-containing stream in an amount that produces a maximum hydrogen to hydrocarbon ratio of 0.9 stdm.sup.3 /m.sup.3 (50 SCFB). The hydrotreater feed is contacted in a hydrotreater reactor with a catalyst comprising a Group VIB metal and a Group VII metal on an alumina support. Effluent from the hydrotreater passes to a first separator that separates the effluent into a first gas stream comprising hydrogen, hydrogen sulfide and water and a treated stream comprising hydrocarbons having from 4-7 carbon atoms. The first gas stream is rejected from the process. The treated stream is mixed with a second hydrogen-containing stream in a proportion that produces a hydrogen to hydrocarbon ratio of from 0.9 to 1.8 stdm.sup.3 /m.sup.3 (50 to 100 SCFB) to form an isomerization zone feed. The isomerization feed is contacted in an isomerization reaction zone with an isomerization catalyst comprising alumina having from 0.01 to 0.25 wt. % of platinum and from 2 to 10 wt. % of a chloride component at isomerization conditions. The effluent from the reaction zone enters a stabilizer where it is separated into a product stream of C.sub.4 -C.sub.7 hydrocarbons and a second gas stream which is removed from the process.The common hydrogen supply source and the low hydrogen to hydrocarbon ratios permit operation of the process without hydrogen recycle facilities between the hydrotreatment and isomerization steps and downstream of the isomerization reactor.
摘要翻译：通过在本发明的加氢处理和异构化步骤中使用普通的氢源和低的氢气与烃的比例，简化了加氢处理和异构化C4-C7原料的组合方法。该方法向组合的加氢处理和异构化方法提供氢气，用于使包含C4-C7烃的进料流异构化。烃进料流含有硫和氧污染物，并与含氢物流混合，其量可产生0.9stdm3 / m3（50SCFB）的最大氢烃比。加氢处理剂进料在加氢处理反应器中与氧化铝载体上含有VIB族金属和第VII族金属的催化剂接触。来自加氢处理器的流出物流入第一分离器，其将流出物分离成包含氢气，硫化氢和水的第一气流以及包含具有4-7个碳原子的烃的处理流。第一个气流从该过程中被拒绝。将处理过的物流与第二个含氢物流以一定比例混合，其中氢与烃之比为0.9至1.8 stdm3 / m3（50至100SCFB），形成异构化区进料。异构化进料在异构化反应区中与包含氧化铝的异构化催化剂接触，所述氧化铝具有0.01至0.25wt。％的铂和2〜10wt。％的氯化物组分在异构化条件下。来自反应区的流出物进入稳定剂，在其中将其分离成C4-C7烃的产物流和从该方法中除去的第二气流。普通的氢气供应源和低的氢气与烃的比例允许在加氢处理和异构化步骤之间没有氢循环设施的操作，而异构化反应器的下游。

9. 发明授权

US08110090B2 Deasphalting of gas oil from slurry hydrocracking 有权
标题翻译：瓦斯油从浆液加氢裂化中脱沥青
公开(公告)号：US08110090B2
公开(公告)日：2012-02-07
申请号：US12410817
申请日：2009-03-25
申请人： Paul R. Zimmerman , Mark Van Wees , Robert S. Haizmann , Milan Skripek
发明人： Paul R. Zimmerman , Mark Van Wees , Robert S. Haizmann , Milan Skripek
IPC分类号： C10C3/08
CPC分类号： C10G67/049 , C10G2300/107 , C10G2300/1077 , C10G2300/206 , C10G2300/301 , C10G2300/44
摘要： Integrated slurry hydrocracking (SHC) and solvent deasphalting (SDA) methods for making slurry hydrocracking (SHC) distillates are disclosed. Representative methods involve passing a slurry comprising a vacuum column resid, a recycled, deasphalted oil obtained from SDA, and a solid particulate through an SHC reaction zone in the presence of hydrogen to obtain the SHC distillate. Fractionation or distillation in the SHC product recovery section yields a combined SHC gas oil/SHC pitch stream that is sent to SDA. In a representative embodiment, vacuum distillation in the SHC product recovery is avoided, thereby eliminating equipment that is often most susceptible to fouling.
摘要翻译：公开了用于制备浆液加氢裂化（SHC）馏出物的综合浆料加氢裂化（SHC）和溶剂脱沥青（SDA）方法。代表性的方法包括在氢气存在下通过SHC反应区使含有真空塔渣，再循环的脱沥青油从SDA得到的浆料和固体颗粒通过，得到SHC馏出物。在SHC产品回收部分中进行分馏或蒸馏，得到发送到SDA的组合SHC瓦斯油/ SHC沥青流。在代表性的实施方案中，避免了在SHC产物回收中的真空蒸馏，从而消除了经常最容易污染的设备。

10. 发明申请

US20100329936A1 APPARATUS FOR INTEGRATING SLURRY HYDROCRACKING AND DEASPHALTING 审中-公开
标题翻译：用于整合浆料水解和去除的装置
公开(公告)号：US20100329936A1
公开(公告)日：2010-12-30
申请号：US12495543
申请日：2009-06-30
申请人： Mark Van Wees , Robert S. Haizmann , Daniel B. Gillis
发明人： Mark Van Wees , Robert S. Haizmann , Daniel B. Gillis
IPC分类号： B01J8/20
CPC分类号： C10G21/003 , C10G67/049
摘要： Solvent deasphalting (SDA) is used to prepare a heavy hydrocarbon feed for further upgrading. An overhead deasphalted oil (DAO) stream is prepared for catalytic upgrading and an asphaltene stream is prepared for slurry hydrocracking (SHC). SHC product can be further deasphalted and the DAO can be separated from solvent in an upstream extraction column.
摘要翻译：溶剂脱沥青（SDA）用于制备重质烃进料进一步升级。制备用于催化提质的顶置脱沥青油（DAO）流，并为浆料加氢裂化（SHC）制备沥青质料流。 SHC产物可进一步脱沥青，DAO可在上游萃取塔中与溶剂分离。

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