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    • 3. 发明申请
    • THERMOPLASTIC COMPOSITION HAVING IMPROVED SCRATCH RESISTANCE, AND ARTICLES FORMED THEREFROM
    • 具有改进的耐刮擦性的热塑性组合物及其形成的制品
    • US20080004404A1
    • 2008-01-03
    • US11427102
    • 2006-06-28
    • Robert Dirk van de GrampelJan-Pleun LensDake Shen
    • Robert Dirk van de GrampelJan-Pleun LensDake Shen
    • C08L69/00C08L53/00C08L67/00
    • C08L69/00C08L69/005C08L2666/18
    • A thermoplastic composition comprises A) 25 to 95 parts by weight of a first polycarbonate consisting essentially of i) 25 to 100 mole percent of a first carbonate unit comprising an alkyl-substituted bisphenol carbonate unit, ii) 0 to 75 mole percent of a second carbonate unit where the first and second carbonate units are not identical, and the sum of the mole percentages of the first and second carbonate units in the first polycarbonate is 100 mole percent; B) 5 to 75 parts by weight of a polyester-polycarbonate where the molar ratio of carbonate unit to arylate ester unit is 95:5 to 10:90; and C) 0 to 65 parts by weight of a second polycarbonate, where the first polycarbonate and second polycarbonate are not identical, and the sum of the parts by weight of the first polycarbonate, the polyester-polycarbonate, and the second polycarbonate is 100 parts by weight.
    • 热塑性组合物包含A)25至95重量份的第一聚碳酸酯,其基本上由以下组成:i)25至100摩尔%的包含烷基取代的双酚碳酸酯单元的第一碳酸酯单元,ii)0至75摩尔%的第二 碳酸酯单元,其中第一和第二碳酸酯单元不相同,第一和第二碳酸酯单元在第一聚碳酸酯中的摩尔百分比之和为100摩尔%; B)5〜75重量份碳酸酯单元与芳基酯单元的摩尔比为95:5〜10:90的聚酯 - 聚碳酸酯; 和C)0至65重量份的第二聚碳酸酯,其中第一聚碳酸酯和第二聚碳酸酯不相同,并且第一聚碳酸酯,聚酯 - 聚碳酸酯和第二聚碳酸酯的重量份之和为100份 重量。
    • 6. 发明申请
    • WEATHERABLE RESINOUS COMPOSITIONS
    • 耐候性组合物
    • US20090099297A1
    • 2009-04-16
    • US11873084
    • 2007-10-16
    • Franciscus Maria HuijsRobert Dirk van de GrampelRonald Akkermans
    • Franciscus Maria HuijsRobert Dirk van de GrampelRonald Akkermans
    • C08L51/00
    • C08L53/00C08L25/02C08L25/12C08L25/14C08L33/04C08L33/20C08L51/003C08L55/02C08L69/005C08L2205/03C08L2666/02C08L2666/24C08L2666/14C08L2666/04
    • Disclosed are compositions comprising: (i) 5-45 wt. % of an acrylonitrile-styrene-acrylate (ASA) graft copolymer or acrylate-modified ASA, (ii) 2-82 wt. % of at least one polyestercarbonate which is a block polyestercarbonate comprising organic carbonate blocks alternating with arylate blocks, said arylate blocks comprising ester structural units derived from at least one 1,3-dihydroxybenzene moiety and at least one aromatic dicarboxylic acid, and having a degree of polymerization of at least about 4; and (iii) 5-60 wt. % of at least one rigid thermoplastic polymer comprising structural units derived from styrene and acrylonitrile; alpha-methylstyrene and acrylonitrile; alpha-methylstyrene, styrene, and acrylonitrile; styrene, acrylonitrile, and methyl methacrylate; alpha-methyl styrene, acrylonitrile, and methyl methacrylate; or alpha-methylstyrene, styrene, acrylonitrile, and methyl methacrylate, or mixtures thereof, wherein wt. % values are based on the weight of components (i)-(iii) and wherein a molded article made from the composition has a notched Izod impact strength of at least 5 kilojoules per square meter (kJ/m2) as determined according to ISO 180 at room temperature and a Vicat B value of at least 101° C. determined at 120° C. according to ISO 306. Articles made from said compositions are also disclosed.
    • 公开的组合物包含:(i)5-45wt。 丙烯腈 - 苯乙烯 - 丙烯酸酯(ASA)接枝共聚物或丙烯酸酯改性的ASA的%,(ii)2-82wt。 至少一种聚酯碳酸酯,其是包含与芳基化物嵌段交替的有机碳酸酯嵌段的嵌段聚酯碳酸酯,所述芳基化物嵌段包含衍生自至少一种1,3-二羟基苯部分和至少一种芳族二羧酸的酯结构单元, 的聚合度至少约4; 和(iii)5-60重量% 至少一种含有衍生自苯乙烯和丙烯腈的结构单元的刚性热塑性聚合物的% α-甲基苯乙烯和丙烯腈; α-甲基苯乙烯,苯乙烯和丙烯腈; 苯乙烯,丙烯腈和甲基丙烯酸甲酯; α-甲基苯乙烯,丙烯腈和甲基丙烯酸甲酯; 或α-甲基苯乙烯,苯乙烯,丙烯腈和甲基丙烯酸甲酯,或其混合物。 %值基于组分(i) - (iii)的重量,并且其中由组合物制成的模制品具有根据ISO 180测定的至少5千焦/平方米(kJ / m 2)的缺口伊佐德冲击强度 并且根据ISO 306在120℃下测定至少101℃的维卡B值。还公开了由所述组合物制成的制品。
    • 8. 发明授权
    • Method of making a thermoplastic composition containing an antistatic agent
    • 制备含有抗静电剂的热塑性组合物的方法
    • US07309735B2
    • 2007-12-18
    • US11674373
    • 2007-02-13
    • Theodorus Lambertus HoeksChiel Albertus LeendersRobert Dirk van de Grampel
    • Theodorus Lambertus HoeksChiel Albertus LeendersRobert Dirk van de Grampel
    • C08J7/00
    • C07C303/32C08K5/50Y10S524/912C07C309/06
    • A method for preparing a thermoplastic composition containing an antistatic agent is described. The antistatic agent is a phosphonium sulfonate salt of generic formula (1) wherein each X is independently a halogen or hydrogen, provided that the molar ratio of halogen to hydrogen is greater than about 0.90; p is 0 or 1 and q and r are integers of 0 to about 7 provided that q+r is less than 8 and that if p is not zero then r is greater than zero; and each R is the same or different hydrocarbon radical containing 1 to about 18 carbon atoms. The phosphonium sulfonate salt is prepared by a method that includes combining in an aqueous medium a compound of generic formula (2) wherein M is Li or Na, and X, q, p, and r are as defined above, with a stoichiometric excess of a compound of the generic formula (3) (R)4P-Z  (3) wherein Z is a halogen and R is as defined above; and separating the product of formula (1) from the medium. The phosphonium sulfonate salt is then combined with a thermoplastic resin.
    • 描述了制备含有抗静电剂的热塑性组合物的方法。 抗静电剂是通式(1)的鏻磺酸盐,其中每个X独立地是卤素或氢,条件是卤素与氢的摩尔比大于约0.90; p为0或1,q和r为0至约7的整数,条件是q + r小于8,如果p不为零,则r大于零; 并且每个R是含有1至约18个碳原子的相同或不同的烃基。 鏻磺酸盐的制备方法包括在水性介质中将通式(2)的化合物(其中M为Li或Na,X,q,p和r如上定义)与化学计量过量的 通式(3)的化合物<?in-line-formula description =“In-line Formulas”end =“lead”?(R)4 PZ(3) line-formula description =“In-line Formulas”end =“tail”?>其中Z是卤素,R如上定义; 和将式(1)的产物与介质分离。 然后将鏻磺酸盐与热塑性树脂组合。