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    • 3. 发明授权
    • Recovery of cesium
    • 回收铯
    • US4477377A
    • 1984-10-16
    • US389402
    • 1982-06-17
    • Reed M. IzattJames J. ChristensenRichard T. Hawkins
    • Reed M. IzattJames J. ChristensenRichard T. Hawkins
    • G21F9/00G21F9/04G21F9/12
    • G21F9/007
    • A process of recovering cesium ions from mixtures of ions containing them and other ions, e.g., a solution of nuclear waste materials, which comprises establishing a separate source phase containing such a mixture of ions, establishing a separate recipient phase, establishing a liquid membrane phase in interfacial contact with said source and recipient phases, said membrane phase containing a ligand, preferably a selected calixarene as depicted in the drawing, maintaining said interfacial contact for a period of time long enough to transport by said ligand a substantial portion of the cesium ion from the source phase to the recipient phase, and recovering the cesium ion from the recipient phase. The separation of the source and recipient phases may be by the membrane phase only, e.g., where these aqueous phases are emulsified as dispersed phases in a continuous membrane phase, or may include a physical barrier as well, e.g., an open-top outer container with an inner open-ended container of smaller cross-section mounted in the outer container with its open bottom end spaced from and above the closed bottom of the outer container so that the membrane phase may fill the outer container to a level above the bottom of the inner container and have floating on its upper surface a source phase and a recipient phase separated by the wall of the inner container as a physical barrier. A preferred solvent for the ligand is a mixture of methylene chloride and carbon tetrachloride.
    • 从含有它们的离子和其它离子的混合物(例如核废料材料)的混合物中回收铯离子的方法,其包括建立包含这种离子混合物的单独的源相,建立单独的接收相,建立液膜相 在与所述源和受体相的界面接触中,所述膜相含有配体,优选如图所示的选择的杯芳烃,将所述界面接触保持足够长的时间,以便通过所述配体输送大部分的铯离子 从源相到接收相,并从接收相中回收铯离子。 源和受体相的分离可以仅通过膜相,例如,当这些水相作为分散相乳化在连续的膜相中时,或者也可以包括物理屏障,例如开顶的外容器 其具有安装在外部容器中的较小横截面的内开口容器,其开口底端与外部容器的封闭底部间隔开并且位于外部容器的封闭底部之上,使得膜相可以将外部容器填充到位于 内部容器并且在其上表面上漂浮有源相和由内容器的壁分隔的接收体作为物理屏障。 配体的优选溶剂是二氯甲烷和四氯化碳的混合物。