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1. 发明授权

US5429769A Peroxycarboxylic acids and manganese complex catalysts 失效
标题翻译：过氧羧酸和锰配合物催化剂
公开(公告)号：US5429769A
公开(公告)日：1995-07-04
申请号：US96877
申请日：1993-07-26
申请人： John R. Nicholson , Richard G. Gary
发明人： John R. Nicholson , Richard G. Gary
IPC分类号： C11D3/39 , C01B15/10
CPC分类号： C11D3/3932 , C11D3/3945
摘要： A bleaching composition and method of using is provided wherein the composition comprises an effective amount for bleaching of an organic peroxyacid whose structure includes a percarboxylic and a carboxylic acid or a salt functional unit; an effective amount of manganese complex having a formula selected from the group consisting of:[LMnX.sub.3 ]Y (1)wherein Mn is manganese;X is a coordinating species selected from the group consisting of:RO.sup.-, Cl.sup.-, Br.sup.-, I.sup.-, F.sup.-, NCS.sup.-, N.sub.3.sup.-, I.sub.3.sup.-, NH.sub.3, NR.sub.3, RCOO.sup.-, RSO.sub.3.sup.-, RSO.sub.4.sup.-, OH.sup.-, O.sub.2.sup.2-, HOO.sup.-, H.sub.2 O, SH.sup.-, CN.sup.-, OCN.sup.-, and S.sub.4.sup.2- and combinations thereof;R is a C.sub.1 -C.sub.20 radical selected from the group consisting of alkyl, cycloalkyl, aryl, benzyl and radical combinations thereof;at least two R radicals may also be connected to one another so as to form a bridging unit between two oxygens that coordinate with the manganese;L is a ligand selected from a C.sub.3 -C.sub.60 radical having at least 3 nitrogen atoms coordinating with the manganese; andthe formula: ##STR1## wherein Mn is manganese in a +III or +IV oxidation state and X, L and Y are as defined above; and from about 0.5 to about 50 wt. % of a surfactant. The pH range of the compositions of the invention is from about 7 to about 10.
摘要翻译：提供漂白组合物和使用方法，其中所述组合物包含有效量的漂白有机过氧酸，其结构包括过羧酸和羧酸或盐官能单元; 有效量的具有选自以下的式的锰络合物：[LMnX3] Y（1）其中Mn是锰; X是选自以下的配位物：RO-，Cl-，Br-，I-，F-，NCS-，N3-，I3-，NH3，NR3，RCOO-，RSO3-，RSO4-，OH - ，O22-，HOO-，H 2 O，SH-，CN-，OCN-和S42-及其组合; R是选自烷基，环烷基，芳基，苄基和其基团组合的C1-C20基团; 至少两个R基团也可以彼此连接，以便在与锰配位的两个氧之间形成桥接单元; L是选自具有与锰配位的至少3个氮原子的C 3 -C 60基团的配体; 和式（2）其中Mn是+ III或+ IV氧化态的锰，X，L和Y如上所定义; 和约0.5至约50wt。％的表面活性剂。本发明的组合物的pH范围为约7至约10。

2. 发明授权

US5413733A Amidooxy peroxycarboxylic acids and sulfonimine complex catalysts 失效
标题翻译：酰氨氧基过氧羧酸和磺胺嘧啶配合物催化剂
公开(公告)号：US5413733A
公开(公告)日：1995-05-09
申请号：US97150
申请日：1993-07-26
申请人： John R. Nicholson , Richard G. Gary
发明人： John R. Nicholson , Richard G. Gary
IPC分类号： C07C409/00 , C07C409/40 , C11D3/39 , C01B15/10 , C11D3/395
CPC分类号： C11D3/3917 , C11D3/3902
摘要： A bleaching composition and method of using is provided wherein the composition comprises and effective amount for bleaching of an amido organic peroxyacid whose structure is: ##STR1## wherein R, R.sup.1, R.sup.2, R.sup.3, M, n, and m are defined in the specification;an effective amount of an oxygen transfer agent having a structure:R.sup.1 R.sup.2 C.dbd.NSO.sub.2 R.sup.3 (IV)wherein R.sup.1, R.sup.2, and R.sup.3 are as defined in the specification; and from about 5.0 to 50% by weight of a surfactant. The preferred pH range of the compositions of the invention is from 7 to about 10.
摘要翻译：提供了一种漂白组合物和使用方法，其中组合物包含氨基有机过氧酸的漂白有效量，其结构为：其中R，R 1，R 2，R 3，M，n和m被定义为（I）在规范中; 有效量的具有以下结构的氧转移剂：R1R2C = NSO2R3（IV）其中R1，R2和R3如说明书中所定义; 和约5.0至50重量％的表面活性剂。本发明组合物的优选pH范围为7至约10。

3. 发明授权

US5480576A 1,3-N azole containing detergent compositions 失效
标题翻译：含有1,3-氮唑的洗涤剂组合物
公开(公告)号：US5480576A
公开(公告)日：1996-01-02
申请号：US301459
申请日：1994-09-07
申请人： Richard G. Gary , Petrus A. Angevaare
发明人： Richard G. Gary , Petrus A. Angevaare
IPC分类号： C11D3/00 , C11D3/28 , C11D3/39 , C11D3/395 , C11D7/32 , C11D7/54
CPC分类号： C11D3/0073 , C11D3/28 , C11D3/3902 , C11D3/3947 , C11D3/3951 , C11D3/3956 , C23F11/149
摘要： A detergent composition which prevents tarnishing of silver and silver-plated articles comprising 1-20 weight percent of a peroxygen or hypohalite bleaching agent, 0.05 to about 10 weight percent of a 1,3-N azole compound, from 1 to 75 weight percent of a builder, and 0 to 40 weight percent of a surfactant is described, provided the pK.sub.a of the 1,3-N azole compound is lower than a pH of the aqueous solution of the composition. A method for preventing silver tarnishing of articles in an automatic dishwashing machine is also described.
摘要翻译：一种防止银和镀银制品变色的洗涤剂组合物，其包含1-20重量％的过氧或次卤酸盐漂白剂，0.05至约10重量％的1,3-N唑化合物，1至75重量％描述了助洗剂和0至40重量％的表面活性剂，条件是1,3-N唑类化合物的pKa低于组合物水溶液的pH。还描述了一种用于防止自动洗碗机中的物品的银损坏的方法。

4. 发明授权

US5624892A Process for incorporating aluminum salts into an automatic dishwashing composition 失效
标题翻译：将铝盐掺入自动洗碗组合物中的方法
公开(公告)号：US5624892A
公开(公告)日：1997-04-29
申请号：US444503
申请日：1995-05-19
申请人： Petrus A. Angevaare , Richard G. Gary
发明人： Petrus A. Angevaare , Richard G. Gary
IPC分类号： C11D3/00 , C11D3/02 , C11D3/39 , C11D3/395 , C11D11/00 , C11D1/94 , C11D7/14 , C11D7/42
CPC分类号： C11D3/046 , C11D11/0082 , C11D11/0094 , C11D3/0073 , C11D3/2075 , C11D3/2079 , C11D3/3942 , C11D3/3945 , C11D3/3955
摘要： A composition and method for inhibiting lead corrosion of fine tableware washed in automatic dishwashers is disclosed. The detergent composition comprises an aluminum-sequestrant complex formed by binding the aluminum by a sequestrant in a premix, which is then processed with other detergent components. The composition has a pH of less than about 10 and is substantially free of silicates.
摘要翻译：公开了一种用于抑制在自动洗碗机中洗涤的精细餐具的铅腐蚀的组合物和方法。洗涤剂组合物包括通过在预混物中通过螯合剂将铝结合在一起形成的铝螯合复合物，然后将其与其它洗涤剂组分一起加工。组合物的pH值小于约10，基本上不含硅酸盐。

5. 发明授权

US5468410A Purine class compounds in detergent compositions 失效
标题翻译：洗涤剂组合物中的嘌呤类化合物
公开(公告)号：US5468410A
公开(公告)日：1995-11-21
申请号：US302284
申请日：1994-09-08
申请人： Petrus A. Angevaare , Richard G. Gary
发明人： Petrus A. Angevaare , Richard G. Gary
IPC分类号： C11D3/00 , C11D3/28 , C11D3/39 , C11D3/395 , C11D7/32 , C11D7/54
CPC分类号： C11D3/3951 , C11D3/0073 , C11D3/28 , C11D3/3902 , C11D3/3947 , C11D3/3956 , C23F11/149
摘要： A detergent composition which prevents tarnishing of silver and silver-plated articles is described. The composition comprises 1-20 weight percent of a peroxygen or hypohalite bleaching agent, 0.05 to about 10 weight percent of a purine class compound used as a silver anti-tarnishing agent, from 1 to 75 weight percent of a builder, and 0 to 40 weight percent of a surfactant provided that the pK.sub.a of the purine class compound is below a pH of an aqueous solution of the composition in which it is incorporated. A method of using the composition is also described.
摘要翻译：描述了防止银和镀银制品损坏的洗涤剂组合物。该组合物包含1-20重量％的过氧或次卤酸盐漂白剂，0.05至约10重量％的用作银防变色剂的嘌呤类化合物，1至75重量％的助洗剂，和0至40 重量百分比的表面活性剂，条件是嘌呤类化合物的pKa低于其掺入组合物的水溶液的pH。还描述了使用该组合物的方法。

6. 发明授权

US5374369A Silver anti-tarnishing detergent composition 失效
标题翻译：银防晦暗洗涤剂组合物
公开(公告)号：US5374369A
公开(公告)日：1994-12-20
申请号：US136787
申请日：1993-10-14
申请人： Petrus A. Angevaare , Richard G. Gary
发明人： Petrus A. Angevaare , Richard G. Gary
IPC分类号： C11D3/28 , C11D3/39 , C11D3/395 , C11D7/54
CPC分类号： C11D3/3955 , C11D3/28 , C11D3/3907 , C11D3/3945
摘要： A detergent composition comprising 1-20 weight percent of a peroxygen or hypohalite bleaching agent, 0.05 to about 10 weight percent cyanuric acid, from 1 to 75 weight percent of a builder; and 0 to 40 weight percent of a surfactant is described. The composition prevents tarnishing of silver and silver plated articles.
摘要翻译：一种洗涤剂组合物，其包含1-20重量％的过氧或次卤酸盐漂白剂，0.05至约10重量％的氰尿酸，1至75重量％的助洗剂; 和0〜40重量％的表面活性剂。该组合物防止银和镀银制品的变色。

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