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    • 3. 发明授权
    • High pressure process for recovery of sulphur from gases
    • 从气体回收硫的高压过程
    • US4280990A
    • 1981-07-28
    • US136789
    • 1980-04-03
    • Richard F. JagodzinskiRichard K. Kerr
    • Richard F. JagodzinskiRichard K. Kerr
    • B01D53/86C01B17/04
    • C01B17/043B01D53/8615C01B17/0439
    • A process is provided for producing elemental sulphur from a hydrogen sulphide and sulphur dioxide containing gas stream by a Claus type of catalytic reaction. The process is based on the discovery that the conventional Claus catalyst, in the presence of liquid sulphur and at pressures considerably greater than one atmosphere, is significantly active toward the Claus catalytic reaction. Thus, in accordance with the invention, increasing the pressure of the reaction in the presence of liquid sulphur increases both the catalytic activity and the elemental sulphur conversion. The process involves introducing a compressed hydrogen sulphide and sulphur dioxide containing gas stream into a catalytic reactor and reacting the gases in a Claus catalyst bed in the reactor to produce elemental sulphur under conditions of temperature and pressure such that water in the reactor exists only as water vapor and sulphur vapor is condensed in the catalyst bed, being removed therefrom as a liquid. The pressure within the reactor is preferably between 5 and 50 atmospheres absolute.
    • 提供了一种通过克劳斯型催化反应从硫化氢和含二氧化硫气流产生元素硫的方法。 该方法基于以下发现:常规的Claus催化剂在液体硫存在下并且在显着大于一个大气压的压力下对于克劳斯催化反应具有显着的活性。 因此,根据本发明,在液体硫存在下增加反应压力增加了催化活性和元素硫转化。 该方法包括将压缩的硫化氢和含二氧化硫的气流引入催化反应器中并使反应器中克劳斯催化剂床中的气体与温度和压力条件下的元素硫反应,使得反应器中的水仅存在于水中 蒸汽和硫蒸汽在催化剂床中冷凝,作为液体从其中除去。 反应器内的压力优选为5至50大气压绝对值。