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1. 发明授权

US06608151B1 Method for producing supported chrome catalysts and the use thereof for the polymerization of olefins 有权
标题翻译：负载型铬催化剂的制备方法及其在烯烃聚合中的应用
公开(公告)号：US06608151B1
公开(公告)日：2003-08-19
申请号：US10070341
申请日：2002-02-28
申请人： Paulus de Lange , Guido Funk , Andreas Deckers , Peter Kölle
发明人： Paulus de Lange , Guido Funk , Andreas Deckers , Peter Kölle
IPC分类号： C08F424
CPC分类号： C08F10/02 , B01J23/26 , B01J37/0203 , C08F210/16 , C08F4/24 , C08F4/025 , C08F210/14 , C08F2500/12 , C08F2500/13
摘要： The invention relates to a method for producing supported chromium catalysts for the polymerisation of olefins by loading a xerogel support with chromium by adding to the xerogel support a volume of a 0.025 to 15% by weight solution of a chromium compound or a volume of a solution comprising from 0.025 to 7.8% by weight of Cr which is essentially converted into a chromium(VI) compound on heating in a water-free stream of gas under oxidizing conditions at temperatures in the range from 300 to 1100° C. for a period of from 10 to 1000 minutes in a solvent which comprises a maximum of 20% by weight of water, and subsequently evaporating the solvent, where the volume of the chromium salt solution employed is smaller than the pore volume of the xerogel support.
摘要翻译：本发明涉及通过向干凝胶载体中加入0.025至15重量％的铬化合物或一定体积的溶液的体积来生产用于使烯烃聚合的负载型铬催化剂的方法，包括0.025至7.8重量％的Cr，其在氧化条件下在300至1100℃的温度范围内在无水气体流中加热，基本上转化为铬（VI）化合物一段时间在包含最多20重量％的水的溶剂中10至1000分钟，然后蒸发溶剂，其中所用的铬盐溶液的体积小于干凝胶载体的孔体积。

2. 发明授权

US08034884B2 Gaseous phase fluidized-bed reactor 失效
标题翻译：气相流化床反应器
公开(公告)号：US08034884B2
公开(公告)日：2011-10-11
申请号：US12554964
申请日：2009-09-07
申请人： Rainer Karer , Kaspar Evertz , Wolfgang Micklitz , Hans-Jacob Feindt , Philipp Rosendorfer , Peter Kölle
发明人： Rainer Karer , Kaspar Evertz , Wolfgang Micklitz , Hans-Jacob Feindt , Philipp Rosendorfer , Peter Kölle
IPC分类号： C08F2/00 , B01J8/18
CPC分类号： B01J8/1827 , B01J8/44 , B01J2208/00256 , B01J2208/00274 , C08F10/00 , C08F2/34 , C08F2/01
摘要： Gas-phase fluidized-bed reactor for polymerizing ethylenically unsaturated monomers, comprising a reactor chamber (1) in the form of a vertical tube, if desired a calming zone (2) following the upper section of the reactor chamber, a circulation gas line (3), a circulation gas compressor (4) and a cooling device (5), where, in the region of transition of the reaction gas from the circulation gas line into the reactor chamber and in the lower section of the reactor chamber itself, there is either no gas distributor plate at all or only a gas distributor plate the total surface area of whose gas orifices is more than 20% of the total surface area of said gas distributor plate.
摘要翻译：用于聚合烯键式不饱和单体的气相流化床反应器，包括垂直管形式的反应器室（1），如果需要，在反应器室的上部之后的平静区域（2），循环气体管线 3），循环气体压缩机（4）和冷却装置（5），其中在反应气体从循环气体管线进入反应器室和反应器室本身的下部的过渡区域完全不是气体分配器板，或者只有气体分配器板，其气体孔的总表面积大于所述气体分布板的总表面积的20％。

3. 发明授权

US07517938B2 Loop reactor with varying diameter for olefin polymerization 有权
标题翻译：具有不同直径的环烯烃反应器用于烯烃聚合
公开(公告)号：US07517938B2
公开(公告)日：2009-04-14
申请号：US10572817
申请日：2004-09-16
申请人： Shahram Mihan , Wolfgang Gsella , Peter Kölle , Joachim Wulff-Döring , Markus Meierhöfer
发明人： Shahram Mihan , Wolfgang Gsella , Peter Kölle , Joachim Wulff-Döring , Markus Meierhöfer
IPC分类号： C08F2/12 , B01J19/18
CPC分类号： B01J19/2435 , B01J8/007 , B01J2208/00212 , B01J2208/00584 , B01J2219/00094 , B01J2219/00173 , C08F10/02 , C08F210/16 , Y02P20/544 , C08F2/01 , C08F2/14 , C08F210/14 , C08F2500/08 , C08F2500/24
摘要： Process for polymerizing at least one olefinic monomer selected from ethylene, propylene and 1-butene in a loop reactor in the presence of a polymerization catalyst at from 20 to 150° C., but below the melting point of a polymer to be formed, and a pressure of from 43 to 80 bar, where the polymer formed is present in a suspension in a liquid or supercritical suspension medium and wherein the suspension is circulated by means of an axial pump, wherein the polymerization is carried out at an average solids concentration in the reactor of more than 53% by weight, in the case of continuous product discharge, and at an average solids concentration in the reactor of more than 45% by weight, in the case of discontinuous product discharge, and wherein the polymerization is carried out at an ethylene concentration of at least 10 mol %, based on the suspension medium.
摘要翻译：在聚合催化剂存在下，在环状反应器中，在20〜150℃，但低于待形成的聚合物的熔点，聚合至少一种选自乙烯，丙烯和1-丁烯的烯烃单体的方法，以及其中形成的聚合物存在于液体或超临界悬浮介质中的悬浮液中，并且其中悬浮液通过轴向泵循环，其中聚合以平均固体浓度进行反应器在连续产物排出的情况下大于53重量％，反应器中的平均固体浓度大于45重量％，在不连续的产物排出的情况下，并且其中进行聚合基于悬浮介质，乙烯浓度至少为10摩尔％。

4. 发明授权

US06683018B1 Method for producing a supported catalyst system 失效
标题翻译：负载催化剂体系的制备方法
公开(公告)号：US06683018B1
公开(公告)日：2004-01-27
申请号：US09622211
申请日：2000-08-14
申请人： Marc Oliver Kristen , Laurent Deloux , Peter Kölle , Ulrich Moll , Ursula Rief
发明人： Marc Oliver Kristen , Laurent Deloux , Peter Kölle , Ulrich Moll , Ursula Rief
IPC分类号： B01J3100
CPC分类号： B01J31/1616 , B01J31/2295 , B01J37/0203 , B01J2531/48 , C08F4/61908 , C08F4/61912 , C08F10/00 , C08F210/16 , C08F4/61916 , C08F210/14 , C08F2500/17
摘要： A process for the preparation of a supported catalyst system, an inorganic carrier material being reacted with a metal compound of the formula M1(R1)r(R2)5(R3)t(R4)u I in the presence of an inert solvent in a first step and, in a subsequent step, the suspension thus obtained being reacted with a metallocene complex and a compound forming metallocenium ions, in which process the solvent is not removed after the first step and the subsequent step is carried out without isolation of the pretreated carrier material thus obtained.
摘要翻译：一种制备负载型催化剂体系的方法，无机载体材料与第一步惰性溶剂的存在下的金属化合物反应，在随后的步骤中，将由此获得的悬浮液与茂金属络合物和形成金属茂离子的化合物，其中在第一步骤之后不除去溶剂，并且在不分离由此获得的预处理载体材料的情况下进行随后的步骤。

5. 发明授权

US06359086B1 Non self-igniting solid 失效
标题翻译：非自燃固体
公开(公告)号：US06359086B1
公开(公告)日：2002-03-19
申请号：US09341517
申请日：1999-07-13
申请人： Marc Oliver Kristen , Patrik Müller , Ulrich Moll , Peter Kölle
发明人： Marc Oliver Kristen , Patrik Müller , Ulrich Moll , Peter Kölle
IPC分类号： C08F442
CPC分类号： B01J31/143 , B01D53/28 , B01J31/12 , B01J31/1616 , B01J31/165 , B01J31/2295 , B01J2531/48 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F110/02 , Y10S526/943 , C08F4/61916 , C08F2500/17
摘要： A free-flowing solid which does not self-ignite, comprising: a) at least one support component, b) at least one chemical compound which per se is self-igniting, c) at least one inert liquid and d) further components.
摘要翻译：一种不自燃的自由流动的固体，包括：a）至少一种载体组分，b）至少一种本身是自燃的化合物，c）至少一种惰性液体，和d）其它组分。

6. 发明授权

US08148588B2 Process for preparing polyolefins in suspension 有权
标题翻译：悬浮液中制备聚烯烃的方法
公开(公告)号：US08148588B2
公开(公告)日：2012-04-03
申请号：US10589048
申请日：2005-01-25
申请人： Joachim Berthold , Frank Peter Alt , Kaspar Evertz , Peter Kölle
发明人： Joachim Berthold , Frank Peter Alt , Kaspar Evertz , Peter Kölle
IPC分类号： C08F10/00 , C08L23/08 , C08L23/14
CPC分类号： C08F10/00 , C08F210/16 , C08F2/34 , C08F2/14 , C08F2/001 , C08F210/06
摘要： The invention relates to a continuous process for preparing polyolefins having a bimodal or multimodal molar mass distribution in suspension in at least two reactors R1, R2.x, R3.y which are connected in series and in which different reaction conditions are set. In this process, the offgases A1, A2.x, A3.y, A4 and A5 leaving all the reactors connected in series are firstly collected, the collected offgases are then compressed in a compression stage 10, the compressed offgases are subsequently cooled and the cooled material is separated into a gaseous fraction and a liquid fraction. The separated fractions are then recirculated to the polymerization process at different points. The process of the invention allows the total conversion of the polymerization, based on monomer and comonomer used, to be increased to a surprising extent.
摘要翻译：本发明涉及一种用于制备在至少两个串联连接并且设定不同反应条件的反应器R1，R2.x，R3.y中的悬浮液中具有双峰或多峰摩尔质量分布的聚烯烃的连续方法。在该过程中，首先收集离开所有串联的反应器的废气A1，A2.x，A3.y，A4和A5，然后将收集的废气在压缩级10中压缩，然后将压缩的废气冷却，冷却的材料被分离成气体馏分和液体馏分。然后将分离的级分在不同的点再循环到聚合过程中。本发明的方法允许基于使用的单体和共聚单体的聚合的总转化率增加到惊人的程度。

7. 发明授权

US07553916B2 Loop reactor with varying diameter for olefin polymerization 有权
标题翻译：具有不同直径的环烯烃反应器用于烯烃聚合
公开(公告)号：US07553916B2
公开(公告)日：2009-06-30
申请号：US10572816
申请日：2004-09-16
申请人： Shahram Mihan , Wolfgang Gsella , Peter Kölle , Joachim Wulff-Döring
发明人： Shahram Mihan , Wolfgang Gsella , Peter Kölle , Joachim Wulff-Döring
IPC分类号： C08F2/12 , B01J19/18
CPC分类号： B01J19/1837 , B01J3/008 , B01J8/007 , B01J2208/00212 , B01J2208/00584 , B01J2219/00094 , B01J2219/00173 , C08F10/02 , C08F210/16 , Y02P20/544 , Y10S526/92 , C08F2/14 , C08F2/01 , C08F210/14
摘要： Process for polymerizing at least one olefinic monomer in a loop reactor at from 20 to 150° C., but below the melting point of the polymer to be formed, and a pressure of from 5 to 100 bar, where the polymer formed is present in a suspension in a liquid or supercritical suspension medium and this suspension is circulated by means of an axial pump, wherein the loop reactor comprises a cyclic reactor tube whose diameter varies by at least 10%, based on the predominant reactor tube diameter, and in which there is at least one widening and narrowing in a region other than that of the axial pump.
摘要翻译：在环管反应器中在20-150℃下聚合至少一种烯属单体的方法，但低于待形成的聚合物的熔点，压力为5-100巴，其中所形成的聚合物存在于在液体或超临界悬浮介质中的悬浮液，并且该悬浮液通过轴向泵循环，其中环流反应器包括基于主要的反应器管直径，其直径变化至少10％的循环反应器管，其中在轴向泵以外的区域中至少有一个变宽和变窄。

8. 再颁专利

USRE40140E1 Polymerization catalyst used for producing polyolefins that have excellent combined properties 有权
标题翻译：用于生产具有优异组合性能的聚烯烃的聚合催化剂
公开(公告)号：USRE40140E1
公开(公告)日：2008-03-04
申请号：US11541519
申请日：2001-05-14
申请人： Shahram Mihan , Martin Lux , Wolfgang Rohde , Andreas Deckers , Peter Kölle , Heinz Vogt
发明人： Shahram Mihan , Martin Lux , Wolfgang Rohde , Andreas Deckers , Peter Kölle , Heinz Vogt
IPC分类号： B01J27/06 , B01J21/08 , B01J35/08 , B01J13/00 , C01B33/12
CPC分类号： C08F10/02 , C08F4/24
摘要： The invention relates to a process for preparing a catalyst for the polymerization of olefins, which comprises: a) preparation of a finely divided silica xerogel, b) loading of the xerogel with chromium from a solution of chromium trioxide or a chromium compound which is converted into chromium trioxide under the conditions of step c), and c) activation of the resulting product at from 400 to 1100° C. in a water-free gas stream comprising oxygen in a concentration of above 10% by volume, wherein a fluoride doping with a fluorinating agent is carried out in step b) or in step c). Furthermore, the invention relates to a catalyst for the polymerization of olefins which is obtainable by the process of the invention and to a process for the polymerization of olefins in which an olefin or an olefin mixture is polymerized in the presence of a catalyst according to the invention.
摘要翻译：本发明涉及一种制备烯烃聚合催化剂的方法，该方法包括：a）制备细碎的二氧化硅干凝胶，b）用铬从三氧化铬溶液或铬化合物的溶液中加载干凝胶，在步骤c）的条件下转化为三氧化铬，和c）在含有浓度高于10体积％的氧的无水气流中，在400至1100℃下活化所得产物，其中氟化物掺杂在步骤b）或步骤c）中进行氟化剂。此外，本发明涉及可通过本发明的方法获得的烯烃聚合催化剂和烯烃聚合方法，其中烯烃或烯烃混合物在催化剂存在下聚合，根据发明。

9. 发明申请

US20100056734A1 GASEOUS PHASE FLUIDIZED-BED REACTOR 失效
标题翻译：气相流化床反应器
公开(公告)号：US20100056734A1
公开(公告)日：2010-03-04
申请号：US12554964
申请日：2009-09-07
申请人： Rainer KARER , Kaspar Evertz , Wolfgang Micklitz , Hans-Jacob Feindt , Philipp Rosendorfer , Peter Kölle
发明人： Rainer KARER , Kaspar Evertz , Wolfgang Micklitz , Hans-Jacob Feindt , Philipp Rosendorfer , Peter Kölle
IPC分类号： C08F2/01
CPC分类号： B01J8/1827 , B01J8/44 , B01J2208/00256 , B01J2208/00274 , C08F10/00 , C08F2/34 , C08F2/01
摘要： Gas-phase fluidized-bed reactor for polymerizing ethylenically unsaturated monomers, comprising a reactor chamber (1) in the form of a vertical tube, if desired a calming zone (2) following the upper section of the reactor chamber, a circulation gas line (3), a circulation gas compressor (4) and a cooling device (5), where, in the region of transition of the reaction gas from the circulation gas line into the reactor chamber and in the lower section of the reactor chamber itself, there is either no gas distributor plate at all or only a gas distributor plate the total surface area of whose gas orifices is more than 20% of the total surface area of said gas distributor plate.
摘要翻译：用于聚合烯键式不饱和单体的气相流化床反应器，包括垂直管形式的反应器室（1），如果需要，在反应器室的上部之后的平静区域（2），循环气体管线 3），循环气体压缩机（4）和冷却装置（5），其中在反应气体从循环气体管线进入反应器室和反应器室本身的下部的过渡区域完全不是气体分配器板，或者只有气体分配器板，其气体孔的总表面积大于所述气体分布板的总表面积的20％。

10. 发明授权

US07534341B2 Discontinuous metering of catalysts and process auxilliaries into a gas-phase fluidized-bed reactor 失效
标题翻译：催化剂和工艺助剂不连续计量进入气相流化床反应器
公开(公告)号：US07534341B2
公开(公告)日：2009-05-19
申请号：US10552853
申请日：2004-04-15
申请人： Rainer Karer , Kaspar Evertz , Peter Kölle , Hans-Jacob Feindt
发明人： Rainer Karer , Kaspar Evertz , Peter Kölle , Hans-Jacob Feindt
IPC分类号： C10G35/00 , C10G35/10
CPC分类号： B01J4/002 , B01J4/007 , B01J4/02 , B01J8/0035 , B01J8/004 , B01J8/1872 , B01J2208/00752 , C08F10/00 , C08F110/02 , C08F210/16 , C08F2/00 , C08F2/01 , C08F2/34 , C08F2500/07 , C08F2500/12
摘要： Method of metering at least one solid, particulate catalyst into a reactor containing a fluidized bed (11) of particles in an at least partly gaseous medium, in which the catalyst is metered discontinuously at prescribed time intervals into the fluidized bed (11) at at least one metering point (10). According to the present invention, a fluid stream is firstly introduced into the reactor (5) so that a region having a reduced particle density is formed in the fluidized bed (11) around the metering point (10) and the catalyst is subsequently metered into this region. As a result of the prior introduction of a fluid stream (“preblowing”) before the actual introduction of the catalyst, the catalyst can penetrate significantly deeper into the fluidized bed from the metering point due to the reduced particle density and is dispersed better.
摘要翻译：将至少一种固体颗粒催化剂计量到含有至少部分气体介质中的颗粒流化床（11）的反应器的方法，其中催化剂以规定的时间间隔不连续地计量加入流化床（11）中至少一个计量点（10）。根据本发明，首先将流体流引入反应器（5），使得在流化床（11）周围形成具有减小的颗粒密度的区域，并将催化剂随后计量加入这个地区。由于在实际引入催化剂之前先前引入流体物流（“预吹扫”），由于颗粒密度降低，催化剂可以从计量点深入到流化床中，并且分散得更好。

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