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    • 1. 发明授权
    • Fiber-optic spectroscopic probe with interchangeable sampling heads
    • 具有可互换采样头的光纤光谱探头
    • US5754722A
    • 1998-05-19
    • US380078
    • 1995-01-30
    • Peter J. Melling
    • Peter J. Melling
    • G01N21/85G02B6/24G02B6/04
    • G01N21/8507G02B6/241G01N21/552
    • A fiber-optic spectroscopic probe for use with a Fourier Transform Infrared (FTIR) spectrometer for sensing the absorption of infrared energy by a sample has a shaft containing a fiber optic bundle which terminates proximate the end of the shaft for transmitting and receiving infrared energy from the sample being measured by a measuring head. The shaft has means for detachably attaching interchangeable measuring heads for measuring attenuated total reflectance, diffuse or specular reflectance of the sample, or for measuring the infrared energy transmitted through the sample. The interchangeable heads are coupled to the shaft without the use of additional optics or mechanical positioning devices. The shaft assembly may include a cooling jacket for measuring samples at elevated temperatures. Having different, interchangeable spectral sampling heads makes it possible to obtain quantitative spectral data from a wide range of samples in varying states of agglomeration and homogeneity using a single device.
    • 用于用于感测样品对红外能量的吸收的傅立叶变换红外(FTIR)光谱仪的光纤光谱探测器具有包含光纤束的轴,该光纤束在轴的端部附近终止,用于发射和接收红外能量 样品由测量头测量。 轴具有用于可拆卸地附接可互换的测量头的装置,用于测量样品的衰减的全反射率,漫反射或镜面反射率,或用于测量透过样品的红外能量。 可互换的头部连接到轴上,而不使用附加的光学元件或机械定位装置。 轴组件可以包括用于在升高的温度下测量样品的冷却套。 具有不同的,可互换的光谱采样头使得可以使用单个装置从变化的聚集状态和均匀性的广泛范围的样品获得定量光谱数据。
    • 6. 发明授权
    • Process for making sol-gel deposited ferroelectric thin films
insensitive to their substrates
    • 制造对其基材不敏感的溶胶 - 凝胶沉积铁电薄膜的方法
    • US5198269A
    • 1993-03-30
    • US399724
    • 1989-08-28
    • Scott L. SwartzPeter J. Melling
    • Scott L. SwartzPeter J. Melling
    • C01G23/00C01G25/00C01G35/00C03C17/34C04B41/50C04B41/52C04B41/87C04B41/89C23C18/04C23C18/12C30B29/30C30B29/32H01L21/8242H01L27/10H01L27/108
    • C23C18/04C03C17/3417C04B41/009C04B41/5025C04B41/52C04B41/87C04B41/89C23C18/1216C23C18/1225C23C18/1254C04B2111/00405C04B2111/90
    • A method for producing a thin film of a ferroelectric perovskite material having the steps of providing a first substrate; depositing a first layer of a sol-gel perovskite precursor material wherein the crystallization of this precursor material to the pervoskite phase is insensitive to the first substrate; depositing a second layer of a sol-gel perovskite precursor material wherein the crystallization is sensitive to the first substrate; and heat-treating the deposited layers to form ferroelectric perovskites. A heat treatment step to form perovskites may optionally follow the deposition of the first layer. The first layer of sol-gel perovskite precursor material is selected to produce a perovskite upon heat treatment of: lead titanate (PbTiO.sub.3), or strontium titanate (SrTiO.sub.3). The second layer of sol-gel perovskite precursor material is selected to produce a perovskite upon heat treatment of: lead zirconate titanate (Pb(Zr,Ti)O.sub.3), lead zirconate (PbZrO.sub.3), lead lanthanum titanate ((Pb,La)TiO.sub.3), lead lanthanum zirconate ((Pb,La)ZrO.sub.3), lead lanthanum zirconate titanate ((Pb,La)(Zr,Ti)O.sub.3), lead magnesium niobate (Pb(Mg.sub.1/3 Nb.sub.2/3)O.sub.3), lead zinc niobate (Pb(Zn.sub.1/3 Nb.sub.2/3)O.sub.3), barium titanate (BaTiO.sub.3), strontium barium titanate ((Sr,Ba)TiO.sub.3), barium titanate zirconate (Ba(Ti,Zr)O.sub.3), potassium niobate (KNbO.sub.3), potassium tantalate (KTaO.sub.3), or potassium tantalate niobate (K(Ta,Nb)O.sub.3).
    • 一种铁电体钙钛矿材料薄膜的制造方法,具有提供第一基板的工序。 沉积溶胶 - 凝胶钙钛矿前体材料的第一层,其中该前体材料结晶到渗透相中对第一基底不敏感; 沉积第二层溶胶 - 凝胶钙钛矿前体材料,其中结晶对第一基底敏感; 并对沉积的层进行热处理以形成铁电体钙钛矿。 形成钙钛矿的热处理步骤可以任选地遵循第一层的沉积。 选择第一层溶胶 - 凝胶钙钛矿前体材料,以便在热处理时产生钛酸铅(PbTiO3)或钛酸锶(SrTiO3)时产生钙钛矿。 选择第二层溶胶 - 凝胶钙钛矿前体材料,在热处理后生成钙钛矿:锆钛酸铅(Pb(Zr,Ti)O3),锆酸铅(PbZrO3),铅镧钛酸铅((Pb,La)TiO3 ),锆酸锆铅((Pb,La)ZrO 3),锆钛酸铅((Pb,La)(Zr,Ti)O 3),铌酸铅镁(Pb(Mg1 / 3Nb2 / 3)O3),铌酸铅锌 (Pb(Zn1 / 3Nb2 / 3)O3),钛酸钡(BaTiO3),钛酸锶钡((Sr,Ba)TiO3),钛酸钡(Ba(Ti,Zr)O3),铌酸钾(KNbO3) 钽酸钾(KTaO3)或钽酸钾(K(Ta,Nb)O 3)。