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    • 1. 发明授权
    • Process for separating mixtures of 3- and 4-nitrophthalic acid
    • 分离3-和4-硝基邻苯二甲酸的混合物的方法
    • US4284797A
    • 1981-08-18
    • US44122
    • 1979-05-31
    • Peter FurrerHarry Beyeler
    • Peter FurrerHarry Beyeler
    • C07C67/00C07C201/00C07C201/16C07C205/57C07C79/46
    • C07C201/16
    • A novel improved process for separating mixtures of 3- and 4-nitrophthalic acid is described. The said process comprises treating a mixture of 3- and 4-nitrophthalic acid, which mixture is free from inorganic acid residues, in an aqueous-organic medium containing 1-20 percent by volume of water, at a temperature of between 20.degree. and 100.degree. C., stepwise with a base capable of forming salts of 3- and 4-nitrophthalic acid, which salts are essentially insoluble in the reaction medium, the treatment being carried out by adding base until a pH value of about 2.8 is obtained, separating the precipitating product consisting mainly of a 3-nitrophthalic acid mono-salt, subsequently precipitating, by the addition of further base, a product consisting principally of a 4-nitrophthalic acid salt, and finally converting the resulting nitrophthalic acid salts separately into the corresponding free acids, and optionally purifying these. The 3- and 4-nitrophthalic acid can be obtained by the process according to the invention in a simple manner in an isomer-free form and in good to very good yields.
    • 描述了一种用于分离3-和4-硝基邻苯二甲酸的混合物的改进方法。 所述方法包括在含有1-20体积%水的含水有机介质中,在20至100℃的温度下处理3-和4-硝基邻苯二甲酸的混合物,该混合物不含无机酸残基 ℃,与能够形成3-和4-硝基邻苯二甲酸盐的碱分步,该盐基本上不溶于反应介质,该处理通过加入碱进行直到获得约2.8的pH值,分离 主要由3-硝基邻苯二甲酸单盐组成的沉淀产物,随后通过加入另外的碱沉淀出主要由4-硝基邻苯二甲酸盐组成的产物,最后将所得的硝基邻苯二甲酸盐分别转化为相应的无 酸,并任选地纯化这些。 3-和4-硝基邻苯二甲酸可以通过本发明的方法以简单的方式以无异构体的形式和良好至非常好的产率获得。
    • 3. 发明授权
    • Monoazo compounds
    • 单偶氮化合物
    • US4447358A
    • 1984-05-08
    • US308691
    • 1981-10-05
    • Hansrudolf SchwanderPeter Furrer
    • Hansrudolf SchwanderPeter Furrer
    • C09B29/01C09B29/08C09B29/085C09B29/26
    • C09B29/0803C09B29/0003
    • The invention provides novel monoazo compounds of the formula I ##STR1## wherein X is hydrogen or halogen, R is hydrogen or C.sub.1 -C.sub.4 alkyl, R.sub.1 is C.sub.1 -C.sub.8 alkyl, cycloalkyl or ##STR2## wherein the phenyl radical can be monosulfonated, and R.sub.2 is C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by a sulfo group, or is cycloalkyl, with the proviso that either R.sub.1 or R.sub.2 contains a sulfo group.The invention also provides a process for the production of the compounds of the formula I, as well as an intermediate of the formula IIb ##STR3## The novel monoazo compounds can be used as dyes for dyeing and printing textile material, especially wool and polyamide.
    • 本发明提供了式I(I)的新型单偶氮化合物,其中X是氢或卤素,R是氢或C 1 -C 4烷基,R 1是C 1 -C 8烷基,环烷基或其中苯基可以是 并且R2是未被取代或被磺基取代的C1-C4烷基,或是环烷基,条件是R1或R2含有磺基。 本发明还提供了制备式I化合物的方法,以及式IIb的化合物(IIb)。新型单偶氮化合物可用作染色和印花纺织材料,特别是羊毛的染料 和聚酰胺。
    • 4. 发明授权
    • Process for joining components made of metal
    • 用于连接由金属制成的部件的方法
    • US5709952A
    • 1998-01-20
    • US758169
    • 1996-11-25
    • Jurgen TimmPeter Furrer
    • Jurgen TimmPeter Furrer
    • C09D5/06C09J5/06B32B7/12
    • C09J5/06C09D5/06Y10T156/1039Y10T428/31678
    • A process for joining components made of metal, in particular aluminum and aluminum alloys, is such that a thermally-curable (hardenable) adhesive is deposited between the close-fitting surfaces of the components that are to be joined, and one of the outer surfaces neighboring the said close-fitting surface of one of the components is radiated with infra-red radiation in order to cure the adhesive. At least the outer surface to be radiated is provided with a pattern that roughens that surface. By reducing the reflectivity of the roughened surface the capacity to absorb infra-red radiation is increased. A preferred application for the process is in the adhesive bonding of shaped parts, especially body sheet in automobile manufacture.
    • 用于连接由金属,特别是铝和铝合金制成的部件的方法是使得可热固化(可硬化)粘合剂沉积在待接合部件的紧密配合表面之间,并且其中一个外表面 邻近其中一个组件的所述紧密配合的表面以红外辐射辐射以便固化粘合剂。 至少要辐射的外表面具有粗糙表面的图案。 通过降低粗糙表面的反射率,增加了吸收红外辐射的能力。 该方法的优选应用是成型部件,特别是汽车制造中的身体片材的粘合。
    • 5. 发明授权
    • Process for joining components made of metal
    • 用于连接由金属制成的部件的方法
    • US5478424A
    • 1995-12-26
    • US209709
    • 1994-03-14
    • Jurgen TimmPeter Furrer
    • Jurgen TimmPeter Furrer
    • C09D5/06C09J5/06B32B31/00
    • C09J5/06C09D5/06Y10T156/1039Y10T428/31678
    • A process for joining components made of metal, in particular aluminum and aluminum alloys, is such that a thermally-curable (hardenable) adhesive is deposited between the close-fitting surfaces of the components that are to be joined, and one of the outer surfaces neighboring the said close-fitting surface of one of the components is radiated with infra-red radiation in order to cure the adhesive. At least the outer surface to be radiated is provided with a pattern that roughens that surface. By reducing the reflectivity of the roughened surface the capacity to absorb infrared radiation is increased. A preferred application for the process is in the adhesive bonding of shaped parts, especially body sheet in automobile manufacture.
    • 用于连接由金属,特别是铝和铝合金制成的部件的方法是使得可热固化(可硬化)粘合剂沉积在待接合部件的紧密配合表面之间,并且其中一个外表面 邻近其中一个组件的所述紧密配合的表面以红外辐射辐射以便固化粘合剂。 至少要辐射的外表面具有粗糙表面的图案。 通过降低粗糙表面的反射率,增加吸收红外辐射的能力。 该方法的优选应用是成型部件,特别是汽车制造中的身体片材的粘合。
    • 6. 发明授权
    • Process for preparing fine-grained rolled aluminum products
    • 制备细粒轧制铝制品的工艺
    • US4483719A
    • 1984-11-20
    • US537942
    • 1983-09-30
    • Peter FurrerJurgen TimmFrank Wehner
    • Peter FurrerJurgen TimmFrank Wehner
    • C22F1/04
    • C22F1/04
    • A process for the preparation of a rolled aluminum product, containing iron as the predominant alloy element, which has a grain size of less than 10 .mu.m after annealing to at least 250.degree. C., in which an alloy consisting of 0.8 to 1.5% iron, up to 0.5% by weight of each of Si and Mn, the sum of Si and Mn being between 0.2 and 0.8%, up to 0.3% by weight of any other component, the total of other components being no more than 0.8% by weight, and the remainder being aluminum, is casted at a solidification rate of 2.5 to 25 cm/min, the hot plate is cooled to less than 120.degree. C. at a rate of less than 0.5 K/sec and is then cold rolled with a thickness decrease of at least 75% without intermediate annealing, and the final annealing temperature does not exceed 380.degree. C.
    • 一种制备包含铁作为主要合金元素的轧制铝制品的方法,其在退火至至少250℃后具有小于10μm的粒度,其中由0.8至1.5% 铁,高达0.5重量%的Si和Mn,Si和Mn的总和为0.2-0.8重量%,至多0.3重量%的任何其它组分,其它组分的总量不大于0.8重量% ,其余为铝,以2.5〜25cm / min的固化速度铸造,将热板以小于0.5K /秒的速度冷却至小于120℃,然后冷轧 厚度减小至少75%而不进行中间退火,最终退火温度不超过380℃。