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1. 发明申请

US20130248087A1 PROCESS FOR PRODUCING FIBROUS MATERIAL PRE-IMPREGNATED WITH THERMOSETTING POLYMER 审中-公开
标题翻译：用热成型聚合物预先制备纤维材料的方法
公开(公告)号：US20130248087A1
公开(公告)日：2013-09-26
申请号：US13885700
申请日：2011-11-17
申请人： Patrice Gaillard , Mickael Havel , Alexander Korzhenko
发明人： Patrice Gaillard , Mickael Havel , Alexander Korzhenko
IPC分类号： B32B37/02
CPC分类号： B32B37/02 , B29B15/12 , B29B15/125 , B29C70/025 , B29K2105/167 , B82Y30/00 , C08J3/242 , C08J5/24 , D06M11/74 , D06M15/55
摘要： A method for producing a fibrous material including carbon fibres or glass fibres or plant fibres or polymer-based fibres, that are used alone or in a mixture, and are impregnated by a thermohardenable polymer using a mixture containing a hardener and carbon nanofillers, such as carbon nanotubes (CNT). A mixture containing said nanofillers, such as CNTs, and the hardener is used to introduce said nanofillers into the fibrous material. A continuous production line (L) for producing the material in the form of at least one calibrated and homogeneous strip (20) of reinforcing fibres impregnated with a thermohardenable polymer, includes the device (100) for arranging two series of fibres (1, 2) used to form a strip in such a way as to arrange the two series of fibres such that they are brought into contact with each other by means of two calendering devices.
摘要翻译：一种用于生产包含碳纤维或玻璃纤维或植物纤维或聚合物基纤维的纤维材料的方法，其单独使用或混合使用，并且使用含有硬化剂和碳纳米填料的混合物，由可热硬化的聚合物浸渍，例如碳纳米管（CNT）。使用含有所述纳米填料（例如CNT）和硬化剂的混合物将所述纳米填料引入纤维材料中。用于生产以至少一种经过可热固化的聚合物浸渍的增强纤维的校准的均质带（20）形式的材料的连续生产线（L）包括用于布置两系列纤维（1,2）的装置（100））用于形成条带，以便布置两束光纤，使得它们通过两个压延装置相互接触。

2. 发明申请

US20120149551A1 TWO-LAYER CATALYST, PROCESS FOR PREPARING SAME AND USE FOR THE MANUFACTURE OF NANOTUBES 审中-公开
标题翻译：两层催化剂，其制备方法和用于制备纳米管的方法
公开(公告)号：US20120149551A1
公开(公告)日：2012-06-14
申请号：US13391100
申请日：2010-08-16
申请人： Patrice Gaillard , Serge Bordere , Philippe Serp , Brigitte Caussat , Julien Beausoleil
发明人： Patrice Gaillard , Serge Bordere , Philippe Serp , Brigitte Caussat , Julien Beausoleil
IPC分类号： D01F9/127 , B01J23/881 , B01J21/04 , B01J21/18 , B01J21/08 , B01J21/06 , B01J29/04 , D01F9/12 , H01B1/24 , B01J23/85 , B01J21/10 , B82Y30/00 , B82B1/00 , B82B3/00
CPC分类号： B01J37/0244 , B01J21/04 , B01J23/85 , B01J23/881 , B01J35/023 , B01J37/0205 , B82Y30/00 , B82Y40/00 , C01B32/162
摘要： A catalyst material for preparing nanotubes, especially carbon nanotubes, said material being in the form of solid particles, said particles including a porous substrate supporting two superposed catalytic layers, a first layer, directly positioned on the substrate, including at least one transition metal from column VIB of the Periodic Table, preferably molybdenum, and a second catalytic layer, positioned on the first layer, comprising iron. Also, a process for preparing same and to a process for the synthesis of nanotubes using this catalyst material.
摘要翻译：一种用于制备纳米管，特别是碳纳米管的催化剂材料，所述材料为固体颗粒的形式，所述颗粒包括支撑两个重叠的催化层的多孔基材，直接位于基材上的第一层，包括至少一种过渡金属周期表的VIB柱，优选钼，以及位于第一层上的第二催化剂层，包含铁。另外，其制备方法和使用该催化剂材料合成纳米管的方法。

3. 发明申请

US20120077403A1 MULTILAYER CONDUCTIVE FIBER AND METHOD FOR PRODUCING THE SAME BY COEXTRUSION 审中-公开
标题翻译：多层导电纤维及其制造方法
公开(公告)号：US20120077403A1
公开(公告)日：2012-03-29
申请号：US13320959
申请日：2010-05-27
申请人： Patrice Gaillard , Alexander Korzhenko , Philippe Poulin , Nour Eddine El Bounia
发明人： Patrice Gaillard , Alexander Korzhenko , Philippe Poulin , Nour Eddine El Bounia
IPC分类号： B32B27/02 , D02G3/04 , D01D5/253 , D03D15/00 , D04H13/00 , D02G3/36 , D01D5/34 , B82Y30/00
CPC分类号： D01F8/04 , D01F1/09 , Y10T428/2916 , Y10T428/2918 , Y10T428/2929 , Y10T442/3154 , Y10T442/641
摘要： The present invention relates to a multilayer conductive fiber having a core/shell structure, wherein the core contains nanotubes, in particular carbon nanotubes. The invention also relates to a method for producing said fiber by coextrusion and to the uses thereof The invention finally relates to a composite material including the aforementioned multilayer composite fibers bonded together by weaving or using a polymer matrix.
摘要翻译：本发明涉及一种具有核/壳结构的多层导电纤维，其中芯包含纳米管，特别是碳纳米管。本发明还涉及通过共挤出生产所述纤维的方法及其用途。本发明最终涉及包含通过编织或使用聚合物基体结合在一起的上述多层复合纤维的复合材料。

4. 发明申请

US20120077398A1 FIBROUS SUBSTRATE, MANUFACTURING PROCESS AND USES OF SUCH A FIBROUS SUBSTRATE 审中-公开
标题翻译：纤维基材，制造工艺和这种纤维基材的用途
公开(公告)号：US20120077398A1
公开(公告)日：2012-03-29
申请号：US13319557
申请日：2010-05-07
申请人： Patrice Gaillard , Alexander Korzhenko
发明人： Patrice Gaillard , Alexander Korzhenko
IPC分类号： B32B5/02 , H05B6/64 , B82Y40/00
CPC分类号： D06M10/003 , B29B13/02 , B29B15/10 , B29B15/105 , B29B15/12 , B29B15/125 , B29C70/025 , B29C70/30 , B29C70/48 , B29K2101/12 , B29K2105/167 , B29K2105/25 , B29K2307/04 , B29K2313/00 , B29L2031/30 , C08J5/10 , C08J5/24 , D06M10/006 , D06M11/74 , D06M15/256 , D06M15/55 , D06M15/59 , D06M15/61 , D06M15/63 , D06M23/08 , Y10T442/20
摘要： The invention relates to a fibrous substrate such as woven fabrics, felts, nonwoven fabrics that may be in the form of strips, laps or braids, said substrate being impregnated with an organic polymer or blend of organic polymers containing carbon nanotubes (CNTs). Another subject of the invention is a process for manufacturing said substrate, and the various uses thereof for the manufacture of 3D mechanical components.
摘要翻译：本发明涉及一种纤维基质，例如机织织物，毡，非织造织物，其可以是条带，绒毛或编织物，所述基底用含有碳纳米管（CNT）的有机聚合物或共混物浸渍。本发明的另一主题是用于制造所述基底的方法及其用于制造3D机械部件的各种用途。

5. 发明申请

US20090194189A1 METHOD FOR SAFE FILLING WITH CARBON NANOTUBES, FILLING SYSTEM AND INDUSTRIAL PLANT EMPLOYING THIS METHOD 有权
标题翻译：使用碳纳米管进行安全填充的方法，填充系统和使用本方法的工业设备
公开(公告)号：US20090194189A1
公开(公告)日：2009-08-06
申请号：US12361652
申请日：2009-01-29
申请人： Serge Bordere , Patrice Gaillard
发明人： Serge Bordere , Patrice Gaillard
IPC分类号： B65B1/04 , B65B1/16 , B65B1/30 , B65B57/00
CPC分类号： B65B1/16 , B65B1/28 , B65G69/182 , B65G69/183 , Y10T137/87925
摘要： The invention relates to a method for filling a receptacle (200) with carbon nanotubes from another receptacle (106) whereby the CNTs are passed from one receptacle to the other by means of a coupling (300) comprising a double-valve device (30), each valve being coupled to one of the receptacles, the valves (31, 32) closing independently and tightly and being openable only when they are coupled to one another.
摘要翻译：本发明涉及一种用于从另一容器（106）向碳纳米管填充容器（200）的方法，由此通过包括双阀装置（30）的联接器（300）使CNT从一个容器传递到另一容器，每个阀联接到所述容器之一，所述阀（31,32）独立且紧密地封闭，并且只有当它们彼此联接时才可打开。

6. 发明授权

US5494973A Process for the production of a cast sheet based on thermoplastic resin 失效
标题翻译：用于生产基于热塑性树脂的流延片的方法
公开(公告)号：US5494973A
公开(公告)日：1996-02-27
申请号：US370237
申请日：1995-01-09
申请人： Philippe Heim , Patrice Gaillard
发明人： Philippe Heim , Patrice Gaillard
IPC分类号： B29C39/02 , B29K33/04 , B29L7/00 , C08F2/00 , C08F2/02 , C08F291/02 , C08L101/00 , C08F257/02 , C08F265/06
CPC分类号： C08F291/02
摘要： In a first step of this process an elastomer latex is prepared in aqueous emulsion in the presence of at least one ionic surfactant and at least one ethylenically unsaturated monomer; then in a second step at least one vinyl monomer, which is insoluble in water or sparingly soluble in water, is added to the latex thus obtained and the ionic charges introduced by the said latex are neutralised by adding to the mixture of latex and monomer at least one transfer agent carrying ionic charges opposite to those of the surfactant used in the first step, in order to effect the transfer of particles of the latex into the vinyl monomer; then in a third step the aqueous phase is separated from the organic phase comprising the latex and the vinyl monomer; and in a fourth step the bulk polymerisation of the organic phase is carried out in such a way as to obtain the cast sheet after cooling and release from the mould.
摘要翻译：在该方法的第一步中，在至少一种离子表面活性剂和至少一种烯键式不饱和单体的存在下，在水乳液中制备弹性体胶乳; 然后在第二步骤中，将至少一种不溶于水或微溶于水的乙烯基单体加入到由此获得的胶乳中，由所述胶乳引入的离子电荷通过向胶乳和单体的混合物中加入至少一个转运剂携带与第一步骤中使用的表面活性剂相反的离子电荷，以实现将胶乳颗粒转移到乙烯基单体中; 然后在第三步骤中，将水相与包含胶乳和乙烯基单体的有机相分离; 并且在第四步中，有机相的本体聚合以这样的方式进行，以便在冷却和从模具中释放之后获得流延片。

7. 发明授权

US5420209A Preparation of (meth) acrylic/glutarimide copolymers 失效
标题翻译：（甲基）丙烯酸/戊二酰亚胺共聚物的制备
公开(公告)号：US5420209A
公开(公告)日：1995-05-30
申请号：US130127
申请日：1993-10-04
申请人： Bernard Boutevin , Jean-Pierre Parisi , Richard Legay , Bachar Hamoui , Stephane Nowe , Philippe Heim , Patrice Gaillard
发明人： Bernard Boutevin , Jean-Pierre Parisi , Richard Legay , Bachar Hamoui , Stephane Nowe , Philippe Heim , Patrice Gaillard
IPC分类号： C08F8/14 , C08F8/32 , C08F8/48 , C08F220/04 , C08F220/06 , C08F220/10 , C08F220/18
CPC分类号： C08F8/14 , C08F8/32
摘要： (Meth)acrylic/glutarimide copolymers, well suited, e.g., for optical applications, having enhanced glass transition temperatures (Tg), are prepared by salifying the acid functions of (meth)acrylic ester/(meth)acrylic acid copolymers, and then imidifying such "intermediate" salified copolymers into the subject (meth)acrylic/glutarimide polymers.
摘要翻译：通过对（甲基）丙烯酸酯/（甲基）丙烯酸共聚物的酸性功能进行成盐，然后酰亚胺化来制备具有增强的玻璃化转变温度（Tg）的非常适合于例如光学应用的（甲基）丙烯酸/戊二酰亚胺共聚物这种“中间”成盐共聚物成为本发明的（甲基）丙烯酸/戊二酰亚胺聚合物。

8. 发明授权

US5391628A Functionalized multiblock macromonomers and process for their production 失效
标题翻译：功能化多嵌段大分子单体及其制备方法
公开(公告)号：US5391628A
公开(公告)日：1995-02-21
申请号：US916875
申请日：1992-09-03
申请人： Patrice Gaillard , Yves Barbier , Sunil K. Varshney , Philippe Teyssie , Christian Jacobs , Roger Fayt
发明人： Patrice Gaillard , Yves Barbier , Sunil K. Varshney , Philippe Teyssie , Christian Jacobs , Roger Fayt
IPC分类号： C08F8/00 , C08F290/00 , C08F290/04 , C08F297/02 , C08F299/00
CPC分类号： C08F290/04 , C08F297/026
摘要： The application discloses a functionalized multiblock macromonomer of formula: ##STR1## or of formula: ##STR2## in which formulae: each of the blocks A, B and C represents a sequence of a monomer chosen from the acrylic, vinylaromatic, methacrylic, diene, vinylpyridine, vinylpyrrolidone, alkylene oxide, lactam, lactone and maleimide monomer classes, on condition that at least one of the blocks A and C is chosen from a different class to that of block B and that at least one of the blocks A, B or C is a (meth)acrylic sequence,m, n and p are integers representing the number of monomer units in the sequence under consideration, such that 3.ltoreq.n.ltoreq.1000, 0.ltoreq.m.ltoreq.1000 and 0.ltoreq.p.ltoreq.1000, on condition that m and p are not 0 at the same time, andF is a group terminated by O.sup.-, by OH, by an .alpha.,.beta.-ethylenic unsaturation, or by an oxirane groups.Also disclosed are processes for preparing the functionalized multiblock macromonomer which macromonomer combines the advantages of multiblock polymers containing acrylic sequences with the reactivity of macromonomers.
摘要翻译： PCT No.PCT / FR91 / 00110 Sec。 371日期：1992年9月3日 102（e）日期1992年9月3日PCT 1991年2月14日提交PCT公布。公开号WO91 / 12284 日期：1991年8月22日。该申请公开了下式的功能化多嵌段大分子单体：其中式A，B和C各自表示选自丙烯酸，乙烯基芳香族，甲基丙烯酸，二烯，乙烯基吡啶，乙烯基吡咯烷酮，环氧烷，内酰胺，内酯和马来酰亚胺单体类的单体，条件是块A和C中的至少一个选自与块的不同的类别并且至少一个嵌段A，B或C是（甲基）丙烯酸序列，m，n和p是表示所考虑的序列中的单体单元数目的整数，使得3≤n< 条件是m和p不同时为0，F为以O取代的基团，通过OH，= 1000，0

9. 发明申请

US20110123429A1 Process for Producing Carbon Nanotubes from Renewable Raw Materials 审中-公开
标题翻译：从可再生原料生产碳纳米管的工艺
公开(公告)号：US20110123429A1
公开(公告)日：2011-05-26
申请号：US13017601
申请日：2011-01-31
申请人： Serge Bordere , Daniel Cochard , Eric Dutilh , Patrice Gaillard , André Lozowski , Dominique Plee
发明人： Serge Bordere , Daniel Cochard , Eric Dutilh , Patrice Gaillard , André Lozowski , Dominique Plee
IPC分类号： D01F9/12 , B82Y30/00 , B82Y40/00
CPC分类号： B82Y40/00 , B82Y30/00 , C01B32/162
摘要： A subject of the present invention is a process for producing carbon nanotubes, the process comprising: a) the synthesis of alcohol(s) by fermentation of at least one vegetable matter and optionally the purification of the product obtained; b) the dehydration of the alcohol or alcohols obtained in a) in order to produce, in a first reactor, a mixture of alkene(s) and water and optionally the purification of the product obtained; c) the introduction, in particular the introduction into a fluidized bed, in a second reactor, of a powdery catalyst at a temperature ranging from 450 to 850° C., this catalyst comprising at least one catalytic metal supported by an inert solid substrate, the grains of catalyst having a d50 of less than 300 μm; d) bringing the alkene produced in b) into contact with the powdery catalyst of stage c), optionally in a fluidized bed, in order to form carbon nanotubes and hydrogen on the surface of said catalyst by catalytic decomposition of said alkene; e) the recovery of the carbon nanotubes produced in d). The invention also relates to nanotubes capable of being obtained according to the abovementioned process, which can be advantageously used in all the known fields of application of carbon nanotubes.
摘要翻译：本发明的主题是一种生产碳纳米管的方法，该方法包括：a）通过至少一种植物物质的发酵和任选的所得产物的纯化来合成醇; b）在a）中获得的醇或醇的脱水，以便在第一反应器中产生烯烃和水的混合物，并任选地纯化获得的产物; c）引入，特别是在第二反应器中引入粉末状催化剂在450-850℃的温度下引入流化床，该催化剂包含至少一种由惰性固体基质负载的催化金属， d50小于300μm的催化剂颗粒; d）使b）中产生的烯烃与阶段c）的粉末催化剂任选地在流化床中接触，以便通过所述烯烃的催化分解在所述催化剂的表面上形成碳纳米管和氢; e）在d）中生产的碳纳米管的回收。本发明还涉及能够根据上述方法获得的纳米管，其可有利地用于所有已知的碳纳米管应用领域。

10. 发明申请

US20110017957A1 METHOD OF MANUFACTURING CONDUCTIVE COMPOSITE FIBRES WITH A HIGH PROPORTION OF NANOTUBES 审中-公开
标题翻译：制造具有高比例的纳米管的导电复合纤维的方法
公开(公告)号：US20110017957A1
公开(公告)日：2011-01-27
申请号：US12787917
申请日：2010-05-26
申请人： Patrice Gaillard , Philippe Poulin , Célia Mercader , Maryse Maugey , Sandy Moisan , Alain Derre , Cécile Zakri
发明人： Patrice Gaillard , Philippe Poulin , Célia Mercader , Maryse Maugey , Sandy Moisan , Alain Derre , Cécile Zakri
IPC分类号： H01B1/24 , B29B9/12
CPC分类号： D01F1/09 , D01F6/14
摘要： This invention relates to a method of obtaining vinyl alcohol homo- or copolymer-based conductive composite fibres with a high proportion of nanotubes, particularly carbon nanotubes, which are capable of ensuring thermal and/or electric conduction. It likewise relates to the conductive composite fibres obtainable by this method as well as the uses thereof.
摘要翻译：本发明涉及一种获得能够确保热和/或电传导的具有高比例的纳米管，特别是碳纳米管的乙烯醇均聚物或共聚物导电复合纤维的方法。它同样涉及通过该方法获得的导电复合纤维及其用途。

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