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1. 发明授权

US07537678B2 Detecting electrode and nitrogen oxide sensor using the same 有权
标题翻译：氮氧化物传感器电极和含有氧氮传感器的氮氧化物传感器
公开(公告)号：US07537678B2
公开(公告)日：2009-05-26
申请号：US10512307
申请日：2003-04-18
申请人： Nobuhito Imanaka
发明人： Nobuhito Imanaka
IPC分类号： G01N27/26
CPC分类号： G01N27/4074 , G01N33/0037 , G01V9/007 , Y02A50/245
摘要： The present invention uses a sensor electrode (3) in a nitrogen oxide sensor (10) which includes a nitrate or nitrite of an alkali metal and an oxide of a rare-earth element. The nitrate/nitrite of the alkali metal replaces part of the lattice of the oxide of the rare-earth element, forming a solid solution. The sensor electrode (3) therefore exhibits highly practical features, especially high water-insolubility and capability of nitrogen oxide measurement in a hot and humid atmosphere containing water vapor. Thus, a highly practical nitrogen oxide sensor electrode and nitrogen oxide sensor are provided which are usable in measurement in a hot and humid atmosphere containing water vapor.
摘要翻译：本发明在氮氧化物传感器（10）中使用传感器电极（3），其包括碱金属的硝酸盐或亚硝酸盐和稀土元素的氧化物。碱金属的硝酸盐/亚硝酸盐代替稀土元素氧化物的一部分晶格，形成固溶体。因此，传感器电极（3）在含有水蒸气的热湿气氛中表现出高度实用的特征，特别是高水不溶性和氮氧化物测量能力。因此，提供了一种高度实用的氮氧化物传感器电极和氮氧化物传感器，其可用于在含有水蒸气的热和湿气氛中的测量。

2. 发明授权

US4985317A Lithium ion-conductive solid electrolyte containing lithium titanium phosphate 失效
标题翻译：含锂磷酸锂的锂离子导电固体电解质
公开(公告)号：US4985317A
公开(公告)日：1991-01-15
申请号：US372075
申请日：1989-06-28
申请人： Ginya Adachi , Nobuhito Imanaka , Hiromichi Aono , Eisuke Sugimoto , Yoshihiko Sadaoka , Naoshi Yasuda , Takeo Hara , Masaki Nagata
发明人： Ginya Adachi , Nobuhito Imanaka , Hiromichi Aono , Eisuke Sugimoto , Yoshihiko Sadaoka , Naoshi Yasuda , Takeo Hara , Masaki Nagata
IPC分类号： C01B25/45 , C01B33/20 , H01M6/18
CPC分类号： H01M6/185 , C01B25/45 , C01B33/20 , C04B35/16 , C04B35/447 , H01M6/18 , C04B2235/3203 , C04B2235/3217 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3232 , C04B2235/3272 , C04B2235/3418 , C04B2235/447 , C04B2235/77 , C04B2235/80
摘要： A lithium ion-conductive solid electrolyte consisting of a compound represented by the chemical formula, Li.sub.1+x M.sub.x Ti.sub.2-x (PO.sub.4).sub.3 (M is at least one element selected from the group consisting of Fe, Al and rare earth elements and x is a number of 0.1 to 1.9), a compound represented by the chemical formula, Li.sub.1+y Ti.sub.2 Si.sub.y P.sub.3-y O.sub.12 (Y is a number of 0.1 to 2.9), or a compound obtained by mixing a compound represented by the chemical formula, LiTi.sub.2 (PO.sub.4).sub.3 with a lithium compound other than LiTi.sub.2 (PO.sub.4).sub.3 and sintering the resulting mixture. Said lithium ion-conductive solid electrolyte can be produced by subjecting to solid phase reaction a mixture of a titanium oxide, a lithium salt, a phosphoric salt and M.sub.2 O.sub.3 (M is at least one element selected from the group consisting of Fe, Al and rare earth elements) or a silicon oxide or a mixture of LiTi.sub.2 (PO.sub.4).sub.3 and other lithium compound. Said lithium ion-conductive electrolyte can be used in the form of a lithium ion-conductive electrolyte sheet to prepare a structure suitable for solid electrochemical elements.
摘要翻译：由化学式Li1 + xMxTi2-x（PO4）3表示的化合物组成的锂离子传导性固体电解质（M为选自Fe，Al和稀土元素中的至少一种元素，x为数为0.1〜1.9），由化学式Li1 + yTi2SiyP3-yO12表示的化合物（Y为0.1〜2.9的数），或将化学式表示的化合物LiTi2（PO4）3 与LiTi 2（PO 4）3之外的锂化合物并烧结所得混合物。所述锂离子传导性固体电解质可以通过将氧化钛，锂盐，磷酸盐和M 2 O 3的混合物进行固相反应来制造（M为选自Fe，Al和稀土元素中的至少一种元素地球元素）或氧化硅或LiTi 2（PO 4）3与其它锂化合物的混合物。所述锂离子传导性电解质可以以锂离子传导电解质片的形式使用，以制备适用于固体电化学元件的结构。

3. 发明申请

US20050205423A1 Detecting electrode and nitrogen oxide sensor using the same 有权
标题翻译：氮氧化物传感器电极和含有氧氮传感器的氮氧化物传感器
公开(公告)号：US20050205423A1
公开(公告)日：2005-09-22
申请号：US10512307
申请日：2003-04-18
申请人： Nobuhito Imanaka
发明人： Nobuhito Imanaka
IPC分类号： G01N27/407 , G01N33/00 , G01V9/00 , G01N27/26
CPC分类号： G01N27/4074 , G01N33/0037 , G01V9/007 , Y02A50/245
摘要： The present invention uses a sensor electrode (3) in a nitrogen oxide sensor (10) which includes a nitrate or nitrite of an alkali metal and an oxide of a rare-earth element. The nitrate/nitrite of the alkali metal replaces part of the lattice of the oxide of the rare-earth element, forming a solid solution. The sensor electrode (3) therefore exhibits highly practical features, especially high water-insolubility and capability of nitrogen oxide measurement in a hot and humid atmosphere containing water vapor. Thus, a highly practical nitrogen oxide sensor electrode and nitrogen oxide sensor are provided which are usable in measurement in a hot and humid atmosphere containing water vapor.
摘要翻译：本发明在氮氧化物传感器（10）中使用传感器电极（3），其包括碱金属的硝酸盐或亚硝酸盐和稀土元素的氧化物。碱金属的硝酸盐/亚硝酸盐代替稀土元素氧化物的一部分晶格，形成固溶体。因此，传感器电极（3）在含有水蒸气的热湿气氛中表现出高度实用的特征，特别是高水不溶性和氮氧化物测量能力。因此，提供了一种高度实用的氮氧化物传感器电极和氮氧化物传感器，其可用于在含有水蒸气的热和湿气氛中的测量。

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