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    • 1. 发明授权
    • Pre-expanded particles of propylene resin, process for preparing the
same and flow-restricting device
    • 丙烯树脂的预发泡颗粒,其制备方法和流动限制装置
    • US06130266A
    • 2000-10-10
    • US495329
    • 2000-02-01
    • Tsuyoshi MihayashiNobuhisa OtaNaruhiko AkamatsuYutaka YanagiharaTakeshi Satoh
    • Tsuyoshi MihayashiNobuhisa OtaNaruhiko AkamatsuYutaka YanagiharaTakeshi Satoh
    • C08J9/18C08L23/08C08L23/10C08J9/16C08J9/22
    • C08J9/18C08L23/10C08J2203/06C08J2323/16C08L23/0876Y10S521/917
    • There is provided pre-expanded particles of a propylene resin having a high expansion ratio and excellent molding adhesion without using a volatile blowing agent or increasing an expansion pressure. The pre-expanded particles of a propylene resin are prepared by the process comprising dispersing resin particles comprising a propylene resin composition, which contains 100 parts by weight of (A) a random copolymer of ethylene and propylene having an ethylene content of 1.5 to 4.5% by weight and 0.001 to 10 parts by weight of (B) an alkali metal salt of a copolymer of ethylene and (meth)acrylic acid, into an aqueous dispersion medium in a pressure vessel to obtain a mixture, heating the mixture to an expansion temperature higher than a softening temperature of the resin particles, introducing an inorganic gas, and releasing the mixture into a lower atmosphere than the inner pressure of the pressure vessel; said mixture is expanded after a temperature of said mixture is maintained at a temperature region of not more than the expansion temperature to at least (the expansion temperature -1.degree. C.) for at least 30 minutes.
    • 在不使用挥发性发泡剂或增加膨胀压力的情况下,提供具有高膨胀率和优异的模制粘合性的丙烯树脂的预发泡颗粒。 丙烯树脂的预发泡颗粒通过包括分散树脂颗粒的方法制备,所述树脂颗粒包含丙烯树脂组合物,其包含100重量份的(A)乙烯含量为1.5至4.5重量%的乙烯和丙烯的无规共聚物, 和(B)乙烯与(甲基)丙烯酸的共聚物的碱金属盐0.001〜10重量份,在压力容器中的水分散介质中,得到混合物,将混合物加热至膨胀温度 高于树脂颗粒的软化温度,引入无机气体,并将混合物释放到比压力容器的内部压力低的气氛中; 所述混合物在所述混合物的温度保持在不大于膨胀温度至少至(膨胀温度-1℃)的温度区域下膨胀至少30分钟。
    • 2. 发明授权
    • Pre-expanded particles of propylene resin, process for preparing the same and flow-restricting device
    • 丙烯树脂的预发泡颗粒,其制备方法和流动限制装置
    • US06273347B1
    • 2001-08-14
    • US09642025
    • 2000-08-21
    • Tsuyoshi MihayashiNobuhisa OtaNaruhiko AkamatsuYutaka YanagiharaTakeshi Satoh
    • Tsuyoshi MihayashiNobuhisa OtaNaruhiko AkamatsuYutaka YanagiharaTakeshi Satoh
    • B05B130
    • C08J9/18C08J2203/06C08J2323/16C08L23/0876C08L23/10Y10S521/917C08L2666/04
    • There is provided pre-expanded particles of a propylene resin having a high expansion ratio and excellent molding adhesion without using a volatile blowing agent or increasing an expansion pressure. The pre-expanded particles of a propylene resin are prepared by the process comprising dispersing resin particles comprising a propylene resin composition, which contains 100 parts by weight of (A) a random copolymer of ethylene and propylene having an ethylene content of 1.5 to 4.5% by weight and 0.001 to 10 parts by weight of (B) an alkali metal salt of a copolymer of ethylene and (meth)acrylic acid, into an aqueous dispersion medium in a pressure vessel to obtain a mixture, heating the mixture to an expansion temperature higher than a softening temperature of the resin particles, introducing an inorganic gas, and releasing the mixture into a lower atmosphere than the inner pressure of the pressure vessel; said mixture is expanded after a temperature of said mixture is maintained at a temperature region of not more than the expansion temperature to at least (the expansion temperature −1° C.) for at least 30 minutes.
    • 在不使用挥发性发泡剂或增加膨胀压力的情况下,提供具有高膨胀率和优异的模制粘合性的丙烯树脂的预发泡颗粒。 丙烯树脂的预发泡颗粒通过包括分散树脂颗粒的方法制备,所述树脂颗粒包含丙烯树脂组合物,其包含100重量份的(A)乙烯含量为1.5至4.5重量%的乙烯和丙烯的无规共聚物, 和(B)乙烯与(甲基)丙烯酸的共聚物的碱金属盐0.001〜10重量份,在压力容器中的水分散介质中,得到混合物,将混合物加热至膨胀温度 高于树脂颗粒的软化温度,引入无机气体,并将混合物释放到比压力容器的内部压力低的气氛中; 所述混合物在所述混合物的温度保持在不大于膨胀温度至少至(膨胀温度-1℃)的温度区域下膨胀至少30分钟。