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1. 发明申请

US20120277474A1 CONTINUOUS PROCESS FOR THE CARBONYLATION OF ETHYLENE 有权
标题翻译：乙烯羰基化的连续方法
公开(公告)号：US20120277474A1
公开(公告)日：2012-11-01
申请号：US13515585
申请日：2010-12-15
申请人： Eastham Graham Ronald , Neil Tindale
发明人： Eastham Graham Ronald , Neil Tindale
IPC分类号： C07C45/49 , C07C47/06
CPC分类号： C07C67/38 , C07C69/24
摘要： A continuous process for carbonylation of ethylene in a liquid phase using carbon monoxide, a co-reactant and a suitable catalyst system, including: (i) forming a liquid phase comprising the co-reactant and a suitable catalyst system obtainable by combining: (a) a group VIII metal/compound; (b) a ligand of general formula (I) and c) optionally, a source of anions; wherein Q1 is optionally phosphorous; (ii) forming a gaseous phase in contact with the liquid phase by providing at least an ethylene gas input feed stream and a carbon monoxide gas input feed stream wherein the ethylene:CO molar ratio entering the liquid phase from the input feed streams is greater than 2:1; (iii) reacting ethylene with carbon monoxide in the presence of the co-reactant, and of the suitable catalyst system in the liquid phase; wherein the ethylene:CO gas molar ratio in the gaseous phase is between 20:1 and 1000:1 or wherein the molar ratio of ethylene:CO in the liquid phase is greater than 10:1.
摘要翻译：一种使用一氧化碳，共反应物和合适的催化剂体系在液相中羰基化乙烯的连续方法，包括：（i）形成包含共反应物的液相和合适的催化剂体系，所述催化剂体系可通过以下方式获得：（a ）VIII族金属/化合物; （b）通式（I）的配体和c）任选的阴离子源; 其中Q1是任选的磷; （ii）通过提供至少一种乙烯气体输入进料流和一氧化碳气体输入进料流形成与液相接触的气相，其中从输入进料流进入液相的乙烯/ CO摩尔比大于 2：1; （iii）在共反应物和液相中合适的催化剂体系存在下使乙烯与一氧化碳反应; 其中所述气相中的乙烯:CO气体摩尔比为20:1至1000:1，或者其中液相中乙烯:CO的摩尔比大于10:1。

2. 发明授权

US08785678B2 Continuous process for the carbonylation of ethylene 有权
标题翻译：乙烯羰基化的连续工艺
公开(公告)号：US08785678B2
公开(公告)日：2014-07-22
申请号：US13515585
申请日：2010-12-15
申请人： Eastham Graham Ronald , Neil Tindale
发明人： Eastham Graham Ronald , Neil Tindale
IPC分类号： C07C67/38
CPC分类号： C07C67/38 , C07C69/24
摘要： A continuous process for carbonylation of ethylene in a liquid phase using carbon monoxide, a co-reactant and a suitable catalyst system, including: (i) forming a liquid phase comprising the co-reactant and a suitable catalyst system obtainable by combining: (a) a group VIII metal/compound; (b) a ligand of general formula (I) and c) optionally, a source of anions; wherein Q1 is optionally phosphorous; (ii) forming a gaseous phase in contact with the liquid phase by providing at least an ethylene gas input feed stream and a carbon monoxide gas input feed stream wherein the ethylene:CO molar ratio entering the liquid phase from the input feed streams is greater than 2:1; (iii) reacting ethylene with carbon monoxide in the presence of the co-reactant, and of the suitable catalyst system in the liquid phase; wherein the ethylene:CO gas molar ratio in the gaseous phase is between 20:1 and 1000:1 or wherein the molar ratio of ethylene:CO in the liquid phase is greater than 10:1.
摘要翻译：一种使用一氧化碳，共反应物和合适的催化剂体系在液相中羰基化乙烯的连续方法，包括：（i）形成包含共反应物的液相和合适的催化剂体系，所述催化剂体系可通过以下方式获得：（a ）VIII族金属/化合物; （b）通式（I）的配体和c）任选的阴离子源; 其中Q1是任选的磷; （ii）通过提供至少一种乙烯气体输入进料流和一氧化碳气体输入进料流形成与液相接触的气相，其中从输入进料流进入液相的乙烯/ CO摩尔比大于 2：1; （iii）在共反应物和液相中合适的催化剂体系存在下使乙烯与一氧化碳反应; 其中所述气相中的乙烯:CO气体摩尔比为20:1至1000:1，或者其中液相中乙烯:CO的摩尔比大于10:1。

3. 发明申请

US20090216041A1 Catalyst System 有权
标题翻译：催化剂体系
公开(公告)号：US20090216041A1
公开(公告)日：2009-08-27
申请号：US11990272
申请日：2006-08-04
申请人： Graham Ronald Eastham , Neil Tindale
发明人： Graham Ronald Eastham , Neil Tindale
IPC分类号： C07C67/38
CPC分类号： B01J31/2409 , C07C67/38 , C07C69/24
摘要： A continuous carbonylation process for high turnover carbonylation, and a carbonylation reaction medium and product stream thereof. The process comprises carbonylating an ethlenically unsaturated compound with carbon monoxide in the presence of a source of hydroxyl groups and a catalyst system. The catalyst system comprising: (a) a bidentate phosphine, arsine or stibine ligand; and (b) a catalytic metal selected from a group VIB or group VIIIB metal or a compound thereof. The catalytically active concentration of said catalytic metal, measured as the ACCF (product Kg·hr−1·Dm−3), is maintained at less than 0.5.
摘要翻译：用于高周转羰基化的连续羰基化方法，以及羰基化反应介质及其产物流。该方法包括在羟基源和催化剂体系存在的情况下将一种不饱和化合物与一氧化碳进行羰基化。催化剂体系包括：（a）二齿膦，胂或锑配体; 和（b）选自VIB族或VIIIB族金属的催化剂金属或其化合物。以ACCF（产品Kg.hr-1.Dm-3）测量的所述催化金属的催化活性浓度保持在小于0.5。

4. 发明授权

US08445711B2 Metal complexes 失效
标题翻译：金属配合物
公开(公告)号：US08445711B2
公开(公告)日：2013-05-21
申请号：US12297023
申请日：2007-04-10
申请人： Graham Ronald Eastham , Neil Tindale
发明人： Graham Ronald Eastham , Neil Tindale
IPC分类号： C07F9/02 , C07F15/00
CPC分类号： C07F17/02 , C07C67/38 , C07F15/0066 , C07C69/24
摘要： The invention concerns metal complexes and their preparation, in particular a metal complex MLnXm, where M is a metal of group 8, 9 or 10 and X is a halide, HCO3-, NO3-, CO32- or carboxylate. n is a number equal to or less than the coordination number of the metal and m is 1 or 2 and is equal to the oxidation state of the metal. The ligand L may be a bidentate phosphine of formula (I), (II), (III) or (IV) as set out herein. The process of production comprises reacting an ammine compound of metal M with a complexing compound, which is preferably a phosphine.
摘要翻译：本发明涉及金属络合物及其制备，特别是金属络合物MLnXm，其中M是第8,9或10族金属，X是卤化物，HCO 3 - ，NO 3 - ，CO 3 2-或羧酸盐。 n是金属配位数以下的数，m为1或2，与金属的氧化态相同。配体L可以是如本文所述的式（I），（II），（III）或（IV）的二齿膦。制备方法包括使金属M的氨化合物与络合化合物（其优选为膦）反应。

5. 发明申请

US20090312561A1 METAL COMPLEXES 失效
标题翻译：金属复合材料
公开(公告)号：US20090312561A1
公开(公告)日：2009-12-17
申请号：US12297023
申请日：2007-04-10
申请人： Graham Ronald Eastham , Neil Tindale
发明人： Graham Ronald Eastham , Neil Tindale
IPC分类号： C07F15/00 , C07F9/28
CPC分类号： C07F17/02 , C07C67/38 , C07F15/0066 , C07C69/24
摘要： The invention concerns metal complexes and their preparation, in particular a metal complex MLnXm, where M is a metal of group 8, 9 or 10 and X is a halide, HCO3—, NO3—, CO32— or carboxylate. n is a number equal to or less than the coordination number of the metal and m is 1 or 2 and is equal to the oxidation state of the metal. The ligand L may be a bidentate phosphine of formula (I), (II), (III) or (IV) as set out herein. The process of production comprises reacting an ammine compound of metal M with a complexing compound, which is preferably a phosphine.
摘要翻译：本发明涉及金属络合物及其制备，特别是金属络合物MLnXm，其中M是第8,9或10族金属，X是卤化物，HCO 3 - ，NO 3 - ，CO 3 2-或羧酸盐。 n是金属配位数以下的数，m为1或2，与金属的氧化态相同。配体L可以是如本文所述的式（I），（II），（III）或（IV）的二齿膦。制备方法包括使金属M的氨化合物与络合化合物（其优选为膦）反应。

6. 发明授权

US5529744A Method for the production of polymer bottles 失效
标题翻译：生产聚合物瓶的方法
公开(公告)号：US5529744A
公开(公告)日：1996-06-25
申请号：US384643
申请日：1995-02-06
申请人： Neil Tindale
发明人： Neil Tindale
IPC分类号： B29C49/04 , B29C49/00 , B29C49/06 , B29K67/00 , B29K103/04 , B29L22/00 , C08G63/86 , C08J3/20 , C08K3/08 , B29C49/64
CPC分类号： C08J3/20 , B29C49/0005 , C08K3/08 , B29B2911/1402 , B29B2911/14026 , B29B2911/14033 , B29B2911/1404 , B29B2911/14106 , B29B2911/14133 , B29K2067/00 , B29K2105/16 , B29K2705/00 , C08G63/866 , Y10S428/913 , Y10T428/1355 , Y10T428/1372 , Y10T428/256 , Y10T428/258
摘要： Bottle preforms are made by injection moulding a thermoplastic polymer, preferably a polyethylene terephthalate polymer, which contains metal particles, preferably particles of antimony, which are sufficiently fine for them not to be visible to the eye and which intrinsically absorb radiation in the wavelength region 500 nm to 2000 nm. The metal particles are present in an amount such that the reheat time of the polymer is less than the reheat time of the polymer in the absence of the metal particles. The metal particles contained in the polymer are generated in situ by incorporating into the polymer fine particles of a reducible metal compound and a reducing agent capable of reducing the metal compound to the metal and then reacting the metal compound with the reducing agent so as to produce the metal particles. Bottles are made from the bottle preforms by reheating the bottle preforms and then blow moulding bottles from the reheated preforms.
摘要翻译：瓶预成型件通过注射成型热塑性聚合物，优选聚对苯二甲酸乙二醇酯聚合物制成，该聚合物包含金属颗粒，优选锑颗粒，其对于它们而言是非常细小的，使得它们不被眼睛可见，并且本体吸收波长区域500中的辐射 nm至2000nm。金属颗粒的存在量使得聚合物的再热时间小于在不存在金属颗粒的情况下聚合物的再热时间。包含在聚合物中的金属颗粒是通过将可还原金属化合物的聚合物细颗粒和能够将金属化合物还原成金属的还原剂并且然后使金属化合物与还原剂反应而原位生成的，以便产生金属颗粒。瓶子由瓶子预成型件制成，通过对瓶坯进行再加热，然后从再加热的预制件吹塑瓶子。

7. 发明授权

US5419936A Polyester bottles 失效
标题翻译：聚酯瓶
公开(公告)号：US5419936A
公开(公告)日：1995-05-30
申请号：US88097
申请日：1993-07-06
申请人： Neil Tindale
发明人： Neil Tindale
IPC分类号： B29C49/04 , B29C49/00 , B29C49/06 , B29K67/00 , B29K103/04 , B29L22/00 , C08G63/86 , C08J3/20 , C08K3/08 , B29C45/16
CPC分类号： C08J3/20 , B29C49/0005 , C08K3/08 , B29B2911/1402 , B29B2911/14026 , B29B2911/14033 , B29B2911/1404 , B29B2911/14106 , B29B2911/14133 , B29K2067/00 , B29K2105/16 , B29K2705/00 , C08G63/866 , Y10S428/913 , Y10T428/1355 , Y10T428/1372 , Y10T428/256 , Y10T428/258
摘要： Bottles can be made, especially by extrusion stretch blow moulding, using a thermoplastic polymer composition comprising a polymer, preferably a polyester, which contains metal particles especially of sb, which intrinsically absorb radiation in the wavelength region 500 nm to 2000 nm, in a quantity such that the reheat time of the polymer is less than the reheat time of the polymer in the absence of that quantity of particles. A method of making such metal containing polymer compositions by reducing a metal compound in situ is also described.
摘要翻译：可以使用包含聚合物，优选聚酯的热塑性聚合物组合物，其特别是通过挤出拉伸吹塑成型，其含有特别是sb的金属颗粒的热塑性聚合物组合物，其固有地吸收500nm至2000nm的波长区域中的辐射量使得聚合物的再热时间小于在不存在该量的颗粒的情况下聚合物的再加热时间。还描述了通过原位还原金属化合物制备这种含金属的聚合物组合物的方法。

8. 发明授权

US5409983A Refillable bottle of polyethylene terephthalate copolymer and its manufacture 失效
标题翻译：可再填充的聚对苯二甲酸乙二醇酯共聚物及其制造
公开(公告)号：US5409983A
公开(公告)日：1995-04-25
申请号：US194641
申请日：1994-02-10
申请人： Kenneth M. Jones , Graeme P. Kerr , Neil Tindale
发明人： Kenneth M. Jones , Graeme P. Kerr , Neil Tindale
IPC分类号： B29C49/06 , B29C49/00 , B29C49/08 , B29K67/00 , B29L22/00 , C08G63/181 , C08G63/83 , C08G63/85 , C08G63/86 , C08K3/08 , C08J5/10 , C08L31/08
CPC分类号： C08G63/181 , B29C49/0005 , C08K3/08 , B29B2911/1402 , B29B2911/14026 , B29B2911/14033 , B29B2911/1404 , B29B2911/14106 , B29B2911/14133 , B29C49/06 , B29K2067/00 , B29K2105/16 , B29K2995/003 , C08G63/83 , C08G63/85 , C08G63/866
摘要： Refillable polyethylene terephthalate (PET) bottles are made by injection stretch blow moulding and comprise a threaded neck of transparent amorphous substantially non-oriented PET; a substantially cylindrical body of transparent biaxially oriented amorphous PET from 0.4 to 0.9 mm thick and an area expansion ratio of at least 7; and a base of transparent amorphous substantially non-oriented or partly oriented PET in which the PET is a polyethylene terephthalate polymer randomly modified by replacing from 1 to 6 mole % of the terephthalate units with units of a chain orientation disrupting aromatic dicarboxylic acid, such as iso-phthalic acid, having an Intrinsic Viscosity of at least 0.75. The polymer particularly includes fine metal particles especially of antimony to reduce the reheat, and optionally includes a level of diethylene glycol residues greater than normally present in PET to improve the blowing performance of the polymer.
摘要翻译：可再填充的聚对苯二甲酸乙二醇酯（PET）瓶子通过注射拉伸吹塑成型制成，并且包括透明无定形基本无取向PET的螺纹颈部; 透明双轴取向无定形PET的圆柱形体，其厚度为0.4-0.9mm，面积膨胀率至少为7; 和透明无定形基本上未取向或部分取向的PET的基底，其中PET是通过用单取代单分子链取代芳族二羧酸的单体，例如，异邻苯二甲酸，其特性粘度至少为0.75。聚合物特别包括特别是锑的细金属颗粒以减少再热，并且任选地包括比通常存在于PET中的二甘醇残余物水平以提高聚合物的吹塑性能。

9. 发明授权

US09040445B2 Catalyst system 有权
标题翻译：催化剂体系
公开(公告)号：US09040445B2
公开(公告)日：2015-05-26
申请号：US10589971
申请日：2005-02-17
申请人： Graham Eastham , Neil Tindale
发明人： Graham Eastham , Neil Tindale
IPC分类号： B01J29/22 , C07C67/36 , B01J31/24 , B01J31/02 , B01J31/18 , B01J31/22 , C07C51/14 , C07C67/38
CPC分类号： B01J31/2433 , B01J31/0225 , B01J31/1895 , B01J31/2295 , B01J31/24 , B01J31/2457 , B01J31/2485 , B01J2231/321 , B01J2531/0205 , B01J2531/80 , B01J2531/824 , B01J2531/842 , C07C51/14 , C07C67/38 , C07C69/24
摘要： The present invention provides a catalyst system capable of catalyzing the carbonylation of an ethylenically unsaturated compound, which system is obtainable by combining: a) a metal of Group VIB or Group VIIIB or a compound thereof, b) a bidentate phosphine, arsine or stibine ligand, and c) an acid, wherein said ligand is present in at least a 2:1 molar excess compared to said metal or said metal in said metal compound, and that said acid is present in at least a 2:1 molar excess compared to said ligand, a process for the carbonylation of an ethylenically unsaturated compound, a reaction medium, and use of the system.
摘要翻译：本发明提供能够催化烯键式不饱和化合物羰基化的催化剂体系，该体系可通过以下方式获得：a）VIB族或VIIIB族金属或其化合物，b）二齿膦，胂或锑配体，和c）酸，其中所述配体与所述金属化合物中的所述金属或所述金属相比以至少2:1摩尔过量存在，并且所述酸以至少2:1的摩尔过量存在，相比于所述配体，烯属不饱和化合物的羰基化方法，反应介质以及该体系的用途。

10. 发明授权

US08604236B2 Catalyst system 有权
标题翻译：催化剂体系
公开(公告)号：US08604236B2
公开(公告)日：2013-12-10
申请号：US11990272
申请日：2006-08-04
申请人： Ronald Graham Eastham , Neil Tindale
发明人： Ronald Graham Eastham , Neil Tindale
IPC分类号： C07C67/38
CPC分类号： B01J31/2409 , C07C67/38 , C07C69/24
摘要： A continuous carbonylation process for high turnover carbonylation, and a carbonylation reaction medium and product stream thereof. The process comprises carbonylating an ethlenically unsaturated compound with carbon monoxide in the presence of a source of hydroxyl groups and a catalyst system. The catalyst system comprising: (a) a bidentate phosphine, arsine or stibine ligand; and (b) a catalytic metal selected from a group VIB or group VIIIB metal or a compound thereof. The catalytically active concentration of said catalytic metal, measured as the ACCF (product Kg·hr−1·Dm−3), is maintained at less than 0.5.
摘要翻译：用于高周转羰基化的连续羰基化方法，以及羰基化反应介质及其产物流。该方法包括在羟基源和催化剂体系存在的情况下将一种不饱和化合物与一氧化碳进行羰基化。催化剂体系包括：（a）二齿膦，胂或锑配体; 和（b）选自VIB族或VIIIB族金属的催化剂金属或其化合物。以ACCF（产品Kg·hr-1·Dm-3）测量的所述催化金属的催化活性浓度保持在小于0.5。

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