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1. 发明授权

US08802852B2 Azide substituted naphthylene or rylene imide derivatives and their use as reagents in click-reactions 有权
标题翻译：叠氮取代的亚萘基或亚芳基亚胺衍生物及其在点击反应中的用途
公开(公告)号：US08802852B2
公开(公告)日：2014-08-12
申请号：US14085058
申请日：2013-11-20
申请人： Thomas Gessner , Helmut Reichelt , Ingo Münster , Martin Könemann , Neil Gregory Pschirer , Jianqiang Qu , Rüdiger Sens , Anja Schwögler , Antonio Manetto
发明人： Thomas Gessner , Helmut Reichelt , Ingo Münster , Martin Könemann , Neil Gregory Pschirer , Jianqiang Qu , Rüdiger Sens , Anja Schwögler , Antonio Manetto
IPC分类号： C07D221/18 , G01N21/76
CPC分类号： C07D221/18 , C07D221/14 , C07D471/06 , C09B5/62 , C09B57/007 , C12Q1/68 , Y10T436/143333
摘要： Novel mono-azide substituted rylene-imide derivatives, their use in methods for the detection of analytes and reagents kits for the detection of analytes comprising said novel mono-azide substituted rylene-imide derivatives.
摘要翻译：新型单叠氮取代的亚芳基 - 亚胺衍生物，其用于检测分析物的方法和用于检测包含所述新型单叠氮取代的亚芳基 - 亚胺衍生物的分析物的试剂盒。

2. 发明申请

US20140073059A1 Azide Substituted Naphthylene or Rylene Imide Derivatives and their Use as Reagents in Click-Reactions 有权
公开(公告)号：US20140073059A1
公开(公告)日：2014-03-13
申请号：US14084851
申请日：2013-11-20
申请人： Thomas Gessner , Helmut Reichelt , Ingo Münster , Martin Könemann , Neil Gregory Pschirer , Jianqiang Qu , Rüdiger Sens , Anja Schwögler , Antonio Manetto
发明人： Thomas Gessner , Helmut Reichelt , Ingo Münster , Martin Könemann , Neil Gregory Pschirer , Jianqiang Qu , Rüdiger Sens , Anja Schwögler , Antonio Manetto
IPC分类号： C07D221/18 , C12Q1/68 , C07D221/14
CPC分类号： C07D221/18 , C07D221/14 , C07D471/06 , C09B5/62 , C09B57/007 , C12Q1/68 , Y10T436/143333
摘要： Novel mono-azide substituted rylene-imide derivatives, their use in methods for the detection of analytes and reagents kits for the detection of analytes comprising said novel mono-azide substituted rylene-imide derivatives.

3. 发明申请

US20130207056A1 RYLENE MONOIMIDE DERIVATIVES AND USE THEREOF AS PHOTOSENSITIZERS IN SOLAR CELLS AND PHOTODETECTORS 有权
标题翻译：单烯酰胺衍生物及其作为光敏剂在太阳能电池和光电子体中的应用
公开(公告)号：US20130207056A1
公开(公告)日：2013-08-15
申请号：US13762764
申请日：2013-02-08
申请人： Flavio Luiz Benedito , Ingmar Bruder , Peter Erk , Neil Gregory Pschirer , Robert Send , Klaus Muellen , Henrike Wonneberger , Chen Li
发明人： Flavio Luiz Benedito , Ingmar Bruder , Peter Erk , Neil Gregory Pschirer , Robert Send , Klaus Muellen , Henrike Wonneberger , Chen Li
IPC分类号： H01L51/44
CPC分类号： H01L51/44 , C09B5/62 , C09B57/001 , C09B57/08 , H01G9/2059 , H01L51/0053 , H01L51/0061 , H01L51/0068 , H01L51/0072 , H01L51/4226 , Y02E10/542 , Y02E10/549
摘要： Thin layers or films of metal oxides are used as a semiconductor material of solar cells and they are coated with a sensitizer to achieve the high absorption of sunlight. Various dyes have been used as sensitizers in solar cells. Rylene monoimide derivatives are developed as photosensitizers for dye-sensitized solar cells and as photodetectors. The Rylene monoimide derivatives have very good quantum efficiencies, particularly in the NIR region of the absorption spectrum.
摘要翻译：金属氧化物的薄层或薄膜用作太阳能电池的半导体材料，并且用敏化剂涂覆以实现太阳光的高吸收。各种染料已被用作太阳能电池中的敏化剂。 Rylene单酰亚胺衍生物作为染料敏化太阳能电池的光敏剂和光电探测器开发。 Rylene单酰亚胺衍生物具有非常好的量子效率，特别是在吸收光谱的NIR区域。

4. 发明申请

US20120000533A1 PHOTOELECTRIC CONVERSION DEVICE COMPRISING HYDROXAMIC ACID OR A SALT THEREOF AS ADDITIVE AND PROCESS FOR PRODUCING SAME 审中-公开
标题翻译：包含羟基酸或其盐的光电转换装置作为添加剂及其生产方法
公开(公告)号：US20120000533A1
公开(公告)日：2012-01-05
申请号：US13170667
申请日：2011-06-28
申请人： Neil Gregory PSCHIRER , Felix EICKEMEYER , Jan SCHOENEBOOM , Rüdiger SENS , Peter ERK , Helmut REICHELT , Hermann BERGMANN
发明人： Neil Gregory PSCHIRER , Felix EICKEMEYER , Jan SCHOENEBOOM , Rüdiger SENS , Peter ERK , Helmut REICHELT , Hermann BERGMANN
IPC分类号： H01L31/0216 , H01L51/40
CPC分类号： H01G9/2031 , H01G9/2059 , Y02E10/542
摘要： The present invention pertains to a process for producing a photoelectric conversion device comprising a dye-sensitized metal oxide semiconductor which is treated with an essentially transparent hydroxamic acid or an essentially transparent salt thereof. The invention also relates to a photoelectric conversion device obtainable by the process of the invention and to a photoelectric cell, especially a solar cell, comprising the photoelectric conversion device. Moreover, the invention relates to the use of an essentially transparent hydroxamic acid or an essentially transparent salt thereof for enhancing the energy conversion efficiency η of dye-sensitized photoelectric conversion devices.
摘要翻译：本发明涉及一种用于生产光电转换装置的方法，该光电转换装置包括用基本上透明的异羟肟酸或其基本上透明的盐处理的染料敏化金属氧化物半导体。本发明还涉及通过本发明的方法获得的光电转换装置以及包括光电转换装置的光电池，特别是太阳能电池。此外，本发明涉及使用基本上透明的异羟肟酸或其基本上透明的盐来提高能量转化效率＆的染料敏化光电转换装置。

5. 发明申请

US20100207072A1 USE OF RYLENE DERIVATIVES AS ACTIVE COMPONENTS IN SOLAR CELLS AND PHOTODETECTORS 失效
公开(公告)号：US20100207072A1
公开(公告)日：2010-08-19
申请号：US12668975
申请日：2008-07-21
申请人： Neil Gregory Pschirer , Ruediger Sens
发明人： Neil Gregory Pschirer , Ruediger Sens
IPC分类号： H01B1/12 , C07D471/06 , C07D311/78 , C07D221/18
CPC分类号： C07D471/06 , C07D221/18 , C07D311/78 , C09B5/62 , C09B57/008 , H01L51/0053 , H01L51/006 , H01L51/424 , Y02E10/549
摘要： The present invention relates to the use of compounds of the general formula (I) in which the variables are each defined as follows: X are joined to one another with formation of a six-membered ring to give a radical of the formula (x1), (x2) or (x3) both are each a —CWWM radical; Y one of the two radicals is either a radical of the formula (y1) -L-NR1R2 (y1) or a radical of the formula (y2) -L-Z—R3 (y2) and the other radical is hydrogen; are joined to one another with formation of a six-membered ring to give a radical of the formula (y3) or (y4) or both are hydrogen; W are each independently O or S; W′ is O, S or N—R′, with the proviso that at least one of the variables W or W in the general formula I is defined as S; R, P, B, A, D, M, L, Z, R1, R2, R3 and R′ are each defined as specified in the description; m is 1, 2, 3 or 4; n is 0, 2 or 4 when m=1, 2 or 3; is 0, 2, 4 or 6 when m=4; p is 0, 2 or 4 when m=1, 2 or 3, where n+p=0, 2 or 4; is 0, 2, 4 or 6 when m=4, where n+p=0, 2, 4 or 6, as active materials in solar cells or photodetectors. The present invention further relates to the use of mixtures comprising, as components, K1) compounds of the general formula (I) as electron donors or electron acceptors and K2) one or more compounds which, with respect to component K1, act correspondingly as electron acceptors or electron donors for producing photoactive layers for solar cells or photodetectors. In addition, the present invention relates to the use of compounds of the general formula (I) as photosensitizers in solar cells or photodetectors.Moreover, the present invention relates to solar cells and photodetectors which comprise compounds of the formula (I) or the aforementioned mixtures, and also to compounds of the general formula (I) and the aforementioned mixtures.

6. 发明申请

US20080188660A1 Hexarylene and Pentarylene Tetracarboxylic Acid Diimides 有权
标题翻译：六亚甲基和五亚甲基四羧酸二酰亚胺
公开(公告)号：US20080188660A1
公开(公告)日：2008-08-07
申请号：US11910944
申请日：2006-04-13
申请人： Neil Gregory Pschirer , Christopher Kohl , Klaus Mullen
发明人： Neil Gregory Pschirer , Christopher Kohl , Klaus Mullen
IPC分类号： C07D221/18
CPC分类号： C09B5/62 , C07D471/06
摘要： Rylenetetracarboximides of the general formula I in which the variables are defined as follows: R are identical or different radicals: hydrogen; alkyl, cycloalkyl, aryl or hetaryl, each substituted if desired; R′ are identical or different radicals: hydrogen; aryloxy, arylthio, hetaryloxy or hetarylthio, each substituted if desired; n is 1 or 2, and also a process for preparing the rylenetetracarboximides I and their use for coloring high molecular weight organic and inorganic materials, for preparing aqueous polymer dispersions which absorb in the near infrared region of the electromagnetic spectrum, for producing markings and inscriptions which absorb infrared light and are invisible to the human eye, as infrared absorbers for heat management, as IR laser beam-absorbing materials in fusion treatment of plastics parts, and also as active components in photovoltaics.
摘要翻译：其中变量定义如下：通式I的Ryl tetracarboximides：R是相同或不同的基团：氢; 烷基，环烷基，芳基或杂芳基，如果需要，各自被取代; R'是相同或不同的基团：氢; 芳氧基，芳硫基，杂芳氧基或杂芳硫基，如果需要，各自被取代; n为1或2，也是制备四环四甲酰亚胺I的方法及其用于着色高分子量有机和无机材料的用途，用于制备在电磁谱的近红外区域吸收的聚合物分散体，用于产生标记和铭文其吸收红外光并且对于人眼是不可见的，作为用于热管理的红外吸收剂，作为用于塑料部件的熔融处理的IR激光束吸收材料，以及作为光伏的有源组件。

7. 发明授权

US09595678B2 Dye solar cell with improved stability 有权
标题翻译：染料太阳能电池具有改善的稳定性
公开(公告)号：US09595678B2
公开(公告)日：2017-03-14
申请号：US13183631
申请日：2011-07-15
申请人： Neil Gregory Pschirer , Ingmar Bruder , Rüdiger Sens , Peter Erk
发明人： Neil Gregory Pschirer , Ingmar Bruder , Rüdiger Sens , Peter Erk
IPC分类号： H01L51/46 , H01L51/48 , H01L51/44 , H01L51/00 , H01L51/42
CPC分类号： H01L51/0059 , H01L51/0061 , H01L51/0072 , H01L51/422 , Y02E10/549
摘要： A photovoltaic element (110) is proposed for conversion of electromagnetic radiation to electrical energy. The photovoltaic element (110) may especially be a dye solar cell (112). The photovoltaic element (110) has at least one first electrode (116), at least one n-semiconductive metal oxide (120), at least one electromagnetic radiation-absorbing dye (122), at least one solid organic p-semiconductor (126) and at least one second electrode (132). The p-semiconductor (126) comprises at least one metal oxide (130).
摘要翻译：提出了用于将电磁辐射转换成电能的光电元件（110）。光电元件（110）可以特别地是染料太阳能电池（112）。光电元件（110）具有至少一个第一电极（116），至少一个n-半导体金属氧化物（120），至少一个电磁辐射吸收染料（122），至少一个固体有机p半导体）和至少一个第二电极（132）。 p半导体（126）包括至少一种金属氧化物（130）。

8. 发明申请

US20140080220A1 Azide Substituted Naphthylene or Rylene Imide Derivatives and their Use as Reagents in Click-Reactions 有权
标题翻译：叠氮取代的亚萘基或亚芳基衍生物及其作为点滴反应的试剂
公开(公告)号：US20140080220A1
公开(公告)日：2014-03-20
申请号：US14085058
申请日：2013-11-20
申请人： Thomas Gessner , Helmut Reichelt , Ingo Münster , Martin Könemann , Neil Gregory Pschirer , Jianqiang Qu , Rüdiger Sens , Anja Schwögler , Antonio Manetto
发明人： Thomas Gessner , Helmut Reichelt , Ingo Münster , Martin Könemann , Neil Gregory Pschirer , Jianqiang Qu , Rüdiger Sens , Anja Schwögler , Antonio Manetto
IPC分类号： C07D221/18 , C12Q1/68 , C07D221/14
CPC分类号： C07D221/18 , C07D221/14 , C07D471/06 , C09B5/62 , C09B57/007 , C12Q1/68 , Y10T436/143333
摘要： Novel mono-azide substituted rylene-imide derivatives, their use in methods for the detection of analytes and reagents kits for the detection of analytes comprising said novel mono-azide substituted rylene-imide derivatives.
摘要翻译：新型单叠氮取代的亚芳基 - 亚胺衍生物，其用于检测分析物的方法和用于检测包含所述新型单叠氮取代的亚芳基 - 亚胺衍生物的分析物的试剂盒。

9. 发明授权

US08609846B2 Naphthalene monoimide derivatives and use thereof as photosensitizers in solar cells and photodetectors 有权
标题翻译：萘单酰亚胺衍生物及其在太阳能电池和光电探测器中作为光敏剂的用途
公开(公告)号：US08609846B2
公开(公告)日：2013-12-17
申请号：US13331647
申请日：2011-12-20
申请人： Neil Gregory Pschirer , Jan Schoeneboom , Felix Eickemeyer , Helmut Reichelt , Ruediger Sens , Ingmar Bruder
发明人： Neil Gregory Pschirer , Jan Schoeneboom , Felix Eickemeyer , Helmut Reichelt , Ruediger Sens , Ingmar Bruder
IPC分类号： C07D221/06 , C07D471/06 , H01L31/042
CPC分类号： C07D471/06 , C07D409/14
摘要： The present invention relates to compounds of the formulae Ia and Ib in which the variables R, n, A, B, R1 and R2 are each as defined in the description. The present invention further relates to the use of compounds of the formula Ia or Ib or mixtures of compounds of the formulae Ia and Ib and/or isomers or mixtures of the isomers of the compounds of the formulae Ia and Ib as photosensitizers in solar cells and photodetectors, and to solar cells and photodetectors which comprise such compounds of the formula Ia or Ib or mixtures of compounds of the formulae Ia and Ib and/or isomers or mixtures of the isomers of the compounds of the formulae Ia and Ib as photosensitizers.
摘要翻译：本发明涉及式Ia和Ib的化合物，其中变量R，n，A，B，R 1和R 2各自如说明书中所定义。本发明还涉及式Ia或Ib化合物或式Ia和Ib化合物的混合物和/或式Ia和Ib化合物的异构体或异构体的混合物在太阳能电池中作为光敏剂的用途，以及光电检测器，以及包含式Ia或Ib的化合物或式Ia和Ib化合物的混合物和/或式Ia和Ib化合物的异构体的异构体或者混合物的太阳能电池和光电检测器作为光敏剂。

10. 发明授权

US08501046B2 Use of rylene derivatives as photosensitizers in solar cells 有权
标题翻译：在太阳能电池中使用二烯衍生物作为光敏剂
公开(公告)号：US08501046B2
公开(公告)日：2013-08-06
申请号：US13406016
申请日：2012-02-27
申请人： Neil Gregory Pschirer , Felix Eickemeyer , Jan Schoenbeboom , Jianqiang Qu , Martin Koenemann , Klaus Muellen , Chen Li , Andreas Herrmann , Peter Erk , Gero Nordmann , Alfred Kuhn , Anders Hagfeldt , Tomas Edvinsson
发明人： Neil Gregory Pschirer , Felix Eickemeyer , Jan Schoenbeboom , Jianqiang Qu , Martin Koenemann , Klaus Muellen , Chen Li , Andreas Herrmann , Peter Erk , Gero Nordmann , Alfred Kuhn , Anders Hagfeldt , Tomas Edvinsson
IPC分类号： H01C13/00 , H01L31/00 , C07D221/18
CPC分类号： H01G9/2031 , C07D221/18 , C07D311/78 , C07D311/92 , C07D405/04 , C07D405/12 , C07D409/14 , C07D413/04 , C07D417/04 , C07D417/14 , C07D471/06 , C07D491/06 , C09B5/62 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , C09K2211/1029 , C09K2211/1033 , C09K2211/1037 , C09K2211/1044 , C09K2211/1048 , C09K2211/1059 , C09K2211/1088 , H01G9/2059 , H01L51/0053 , H01L51/006 , H01L51/0067 , H01L51/0068 , H01L51/0069 , H01L51/0071 , H01L51/4226 , Y02E10/542 , Y02E10/549
摘要： Use of rylene derivatives I with the following definition of the variables: X together both —COOM; Y a radical -L-NR1R2 (y1) -L-Z—R3 (y2) the other radical hydrogen; together both hydrogen; R is optionally substituted (het)aryloxy, (het)arylthio; P is —NR1R2; B is alkylene; optionally substituted phenylene; combinations thereof; A is —COOM; —SO3M; —PO3M2; D is optionally substituted phenylene, naphthylene, pyridylene; M is hydrogen; alkali metal cation; [NR5]4+; L is a chemical bond; optionally indirectly bonded, optionally substituted (het)arylene radical; R1, R2 are optionally substituted (cyclo)alkyl, (het)aryl; together optionally substituted ring comprising the nitrogen atom; Z is —O—; —S—; R3 is optionally substituted alkyl, (het)aryl; R′ is hydrogen; optionally substituted (cyclo)alkyl, (het)aryl; R5 is hydrogen; optionally substituted alkyl (het)aryl; m is 0, 1, 2; n, p m=0: 0, 2, 4 where: n+p=2, 4, if appropriate 0; m=1: 0, 2, 4 where: n+p=0, 2, 4; m=2: 0, 4, 6 where: n+p=0, 4, 6, or of mixtures thereof as photosensitizers in solar cells.
摘要翻译：使用二烯衍生物I与以下变量的定义：X一起-COOM; Y是自由基-L-NR1R2（y1）-L-Z-R3（y2）另一个基团氢; 一起氢; R是任选取代的（het）芳氧基，（het）芳硫基; P是-NR1R2; B是亚烷基; 任选取代的亚苯基; 其组合; A是-COOM; -SO3M; -PO3M2; D是任选取代的亚苯基，亚萘基，亚吡啶基; M是氢; 碱金属阳离子; [NR5] 4+; L是化学键; 任选间接结合的，任选取代的（亚乙基）亚芳基; R1，R2是任选取代的（环）烷基，（het）芳基; 一起任选取代的包含氮原子的环; Z为-O- -S-; R3是任选取代的烷基，（het）芳基; R'是氢; 任选取代的（环）烷基，（het）芳基; R5是氢; 任选取代的烷基（het）芳基; m为0,1,2; n，p m = 0：0,2,4其中：n + p = 2,4，如果合适0; m = 1：0,2,4其中：n + p = 0,2,4; m = 2：0,4,6其中：n + p = 0,4,6或其混合物作为太阳能电池中的光敏剂。

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