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1. 发明授权

US06515095B1 Nitrogen atom-containing polysiloxanes, their preparation, and fiber and fabric finishing agent compositions 有权
标题翻译：含氮原子的聚硅氧烷，其制备方法，以及纤维和织物整理剂组合物
公开(公告)号：US06515095B1
公开(公告)日：2003-02-04
申请号：US09599023
申请日：2000-06-21
申请人： Naoki Omura , Kenichi Isobe
发明人： Naoki Omura , Kenichi Isobe
IPC分类号： C08G7726
CPC分类号： D06M15/6436 , C08G77/18 , C08G77/26 , C08G77/38 , C08G77/70 , C08L83/04 , D06M2200/50 , Y10S8/01 , C08L2666/44
摘要： Novel nitrogen atom-containing polysiloxanes having residual alkoxy groups are provided. Compositions comprising the same are effective for treating fibers or fibrous materials for imparting softness and durability of home laundering and preventing yellowing.
摘要翻译：提供具有残留烷氧基的新的含氮原子的聚硅氧烷。包含它们的组合物对于处理纤维或纤维材料是有效的，以赋予家庭洗涤的柔软度和耐久性并防止黄化。

2. 发明授权

US5856392A Higher order star polymers having multiple polyisobutylene arms radiating from a condensed core of siloxanes and a method for the synthesis thereof 失效
标题翻译：具有从硅氧烷的凝聚核心辐射的多个聚异丁烯臂的高级星形聚合物及其合成方法
公开(公告)号：US5856392A
公开(公告)日：1999-01-05
申请号：US861395
申请日：1997-05-21
申请人： Joseph P. Kennedy , Naoki Omura , Alexander Lubnin
发明人： Joseph P. Kennedy , Naoki Omura , Alexander Lubnin
IPC分类号： C08L83/05 , C08G77/04 , C08G77/12 , C08G77/442 , C08G81/02
CPC分类号： C08G81/024 , C08G77/442
摘要： The synthesis and characterization of novel higher order, multi-arm star polymers comprising polyisobutylene arms connected to condensed cyclosiloxane cores are described. The synthesis has been achieved by hydrosilating olefin-capped (e.g., allyl- or isopropenyl-terminated) polyisobutylene with hydrogencyclosiloxanes carrying a plurality of Si--H groups and simultaneously and competitively converting SiH functions, in the presence of moisture, to Si--OH groups to rapidly self-condense or react with SiH groups to form coupled cyclosiloxane cores via core-core coupling. Thus, higher order stars having many more arms than first order stars can be formed.
摘要翻译：描述了包含连接到缩合环硅氧烷核心的聚异丁烯臂的新型高级多臂星形聚合物的合成和表征。合成已经通过将烯烃封端（例如，烯丙基或异丙烯基封端的）聚异丁烯与携带多个Si-H基团的水合羟基硅氧烷进行氢化硅烷化，并且在水分存在下同时并且竞争性地将SiH官能团转化为Si-OH基团快速自我冷凝或与SiH基团反应，通过芯 - 芯耦合形成偶联的环硅氧烷核心。因此，可以形成具有比一阶恒星多的臂的高阶恒星。

3. 发明授权

US5663245A Star polymers having a well-defined siloxane core and multiple polyisobutylene arms and a method for the synthesis thereof 失效
标题翻译：具有明确限定的硅氧烷芯和多个聚异丁烯臂的星形聚合物及其合成方法
公开(公告)号：US5663245A
公开(公告)日：1997-09-02
申请号：US620421
申请日：1996-03-22
申请人： Joseph P. Kennedy , Naoki Omura , Alexander Lubnin
发明人： Joseph P. Kennedy , Naoki Omura , Alexander Lubnin
IPC分类号： C08L83/05 , C08G77/04 , C08G77/12 , C08G77/442 , C08G81/02
CPC分类号： C08G81/024 , C08G77/442
摘要： The synthesis and characterization of novel multi-arm star polymers comprising polyisobutylene arms connected to a well-defined, siloxane core are described. The synthesis has been achieved by hydrosilating olefin-capped (e.g., allyl- or isopropenyl-terminated) polyisobutylene with siloxanes carrying a plurality of Si--H groups.
摘要翻译：描述了包含与良好限定的硅氧烷核心连接的聚异丁烯臂的新型多臂星形聚合物的合成和表征。已经通过将含烯烃封端（例如烯丙基或异丙烯基封端的）聚异丁烯与携带多个Si-H基团的硅氧烷氢化硅烷来实现合成。

4. 发明授权

US5240984A Silicon rubber composition 失效
标题翻译：硅胶组合物
公开(公告)号：US5240984A
公开(公告)日：1993-08-31
申请号：US689524
申请日：1991-04-23
申请人： Masaharu Takahashi , Naoki Omura
发明人： Masaharu Takahashi , Naoki Omura
IPC分类号： C08K3/00 , C08L83/04 , C08L83/06
CPC分类号： C08L83/04 , C08G77/12 , C08G77/16 , C08G77/70
摘要： The silicone rubber composition of the present invention is characterized by using a diorganopolysiloxane having an average degree of polymerization of 3,000 to 30,000 in combination with a low-molecular weight of phenyl-group-containing organopolysiloxane having the following formula: ##STR1## wherein R.sup.1 represents a phenyl group, R.sup.2 and R.sup.3 each represent a monovalent hydrocarbon group having 1 to 10 carbon atoms, and n is 1 or 2.The composition can form a vulcanized molded item having excellent properties such as excellent storage stability, heat resistance, and fire resistance without causing blooming.
摘要翻译：本发明的硅橡胶组合物的特征在于使用平均聚合度为3,000〜30,000的二有机聚硅氧烷与具有下式的低分子量含苯基的有机聚硅氧烷的组合：其中R1表示苯基，R2和R3各自表示碳原子数为1〜10的一价烃基，n为1或2.该组合物可以形成具有优异的储存稳定性，耐热性和耐火性等优异性能的硫化成型品不会引起开花。

5. 发明授权

US5221784A Silicone rubber composition 失效
标题翻译：硅橡胶组合物
公开(公告)号：US5221784A
公开(公告)日：1993-06-22
申请号：US823382
申请日：1992-01-21
申请人： Yoshio Inoue , Naoki Omura
发明人： Yoshio Inoue , Naoki Omura
IPC分类号： C08K3/36 , C08K5/544 , C08L83/04 , C08L83/07 , C08L83/14
CPC分类号： C08L83/04 , C08K5/544 , C08G77/12 , C08G77/20
摘要： A silicone rubber composition that will be cured using as catalyst a platinum family metal and an organic peroxide, comprising as its constituent component an organosilizane compound represented by the following general formula:(R.sup.2).sub.3 SiNH(R.sup.3 R.sup.4 SiO).sub.n R.sup.3 R.sup.4 SiNHSi(R.sup.2).sub.3wherein R.sup.2 represents a substituted or unsubstituted monovalent hydrocarbon group, R.sup.3 and R.sup.4, which may be the same or different, each represent a hydrogen atom or a substituted or unsubstituted monovalent hydrocarbon group, and n is an integer of 2 to 20. Even if a large amount of a silica filler is blended in this silicone rubber composition, the silicone rubber composition is excellent in that it has suitable plasticity and is low in crepe hardening and good in workability such as rollability and extrudability.
摘要翻译：将作为催化剂的铂族金属和有机过氧化物固化的硅橡胶组合物，其包含作为其组成成分的由以下通式表示的有机硅烷化合物：（R2）3SiNH（R3R4SiO）nR3R4SiNHSi（R2）3，其中R2表示取代或未取代的一价烃基，R 3和R 4可以相同或不同，分别表示氢原子或取代或未取代的一价烃基，n为2〜20的整数。即使大量在该硅橡胶组合物中掺入二氧化硅填料，硅橡胶组合物具有优异的可塑性，绉纹硬化性低，可加工性，挤出性好等优异性。

6. 发明授权

US5959034A Curable silicone composition 失效
标题翻译：可固化硅酮组合物
公开(公告)号：US5959034A
公开(公告)日：1999-09-28
申请号：US61263
申请日：1998-04-17
申请人： Masahiko Ogawa , Naoki Omura , Shunji Aoki
发明人： Masahiko Ogawa , Naoki Omura , Shunji Aoki
IPC分类号： C08K5/16 , C08G18/61 , C08G77/38 , C08L83/06 , C08L83/07 , C08F8/00
CPC分类号： C08G77/38 , C08G18/61
摘要： A curable silicone composition having high compatibility with organic polymers, which comprises (a) 100 parts by weight of a hydroxyl group-containing organopolysiloxane represented by the following formula (I) and (b) 1-50 parts by weight of an isocyanate compound having at least two isocyanate groups per molecule, wherein the number of the hydroxyl groups per molecule in the component (a) plus the number of the isocyanate groups per molecule in the component (b) is at least 5: ##STR1## wherein R.sup.1 is a monovalent saturated hydrocarbon group; R.sup.2 is a phenyl-substituted alkyl group represented by C.sub.6 H.sub.5 --(CH.sub.2).sub.p --CH(R.sup.4)--CH.sub.2 --; R.sup.3 is a hydroxyl-substituted alkyl group represented by --CH.sub.2 --CH.sub.2 --CH.sub.2 --O--(C.sub.2 H.sub.4 O).sub.q --H; two R groups are the same group or different groups selected from the groups represented by R.sup.1, R.sup.2 or R.sup.3 ; R.sup.4 is a hydrogen atom or the same group as R.sub.1 ; l is 0 or a positive number, m is a positive number and n is a positive number of no less than 2, provided that 0.10.ltoreq.m/(l+m+n).ltoreq.0.70 and 5.ltoreq.l+m+n.ltoreq.100; p is an integer of from 0 to 5; and q is an integer of from 1 to 3.
摘要翻译：一种与有机聚合物具有高相容性的可固化硅氧烷组合物，其包含（a）100重量份由下式（I）表示的含羟基的有机聚硅氧烷和（b）1-50重量份的具有每分子至少两个异氰酸酯基团，其中组分（a）中每分子的羟基数与组分（b）中每个分子的异氰酸酯基团数目至少为5：其中R1是一价饱和烃组; R2是由C6H5-（CH2）p-CH（R4）-CH2-表示的苯基取代的烷基; R3是由-CH2-CH2-CH2-O-（C2H4O）q-H表示的羟基取代的烷基; 两个R基团是选自由R 1，R 2或R 3表示的基团的相同基团或不同基团; R4是氢原子或与R1相同的基团; l是0或正数，m是正数，n是不小于2的正数，条件是0.10≤m/（1 + m + n）≤0.70和5≤1 + m + n

7. 发明授权

US5506287A Acrylic rubber composition 失效
公开(公告)号：US5506287A
公开(公告)日：1996-04-09
申请号：US353386
申请日：1994-12-02
申请人： Masaharu Takahashi , Naoki Omura
发明人： Masaharu Takahashi , Naoki Omura
IPC分类号： C08K3/04 , C08K3/00 , C08K3/36 , C08L33/04 , C08L33/06 , C08L43/04 , C08L83/04 , C08K5/24
CPC分类号： C08K3/0033 , C08L43/04 , C08L83/04
摘要： An improvement is proposed for an acrylic rubber composition to decrease the stickiness of the rubber composition under processing and shaped and vulcanized articles of the composition to a metallic surface with which the rubber article is kept in contact at an elevated temperature under compression as is the case in packings, gaskets and O-rings as automobile parts. The improvement can be obtained by compounding the rubber composition consisting of an acrylic rubbery polymer, which can be substituted by organosilicon groups, and a reinforcing filler with a limited amount of a specific diorganopolysiloxane, e.g., dimethyl polysiloxane, of which from 5 to 50% in number of the organic groups bonded to the silicon atoms are phenyl groups.

8. 发明授权

US5504234A Method for the preparation of (meth)acryloxyalkyl group-containing linear organopolysiloxane 失效
标题翻译：制备（甲基）丙烯酰氧基烷基的线性有机聚硅氧烷的方法
公开(公告)号：US5504234A
公开(公告)日：1996-04-02
申请号：US451143
申请日：1995-05-26
申请人： Naoki Omura , Toshio Ohba , Shinji Irifune
发明人： Naoki Omura , Toshio Ohba , Shinji Irifune
IPC分类号： C08G77/08 , C08G77/20 , C08G77/22 , C07F7/08
CPC分类号： C08G77/20 , C08G77/08
摘要： A novel method is disclosed for the preparation of a (meth)acryloxyalkyl group-containing organopolysiloxane having a linear structure by the ring-opening siloxane rearrangement polymerization reaction of a (meth)acryloxyalkyl group-containing cyclic organopolysiloxane oligomer either alone or in combination with a cyclic organopolysiloxane oligomer having no (meth)acryloxyalkyl groups. Different from conventional acidic catalyst, the reaction can be promoted by the use of a cation-exchange resin in the H.sup.+ form which can be readily removed from the polymerization mixture after completion of the polymerization reaction leaving no acidic matter which influences on the stability of the product. The catalytic efficiency of the cation-exchange resin can be further enhanced when the resin is, prior to contacting with the cyclic organopolysiloxane oligomer(s), impregnated or swollen with a polar organic solvent such as tetrahydrofuran.
摘要翻译：公开了通过单独或与（甲基）丙烯酰氧基烷基的环状有机聚硅氧烷低聚物的开环硅氧烷重排聚合反应制备具有线性结构的（甲基）丙烯酰氧基烷基的有机聚硅氧烷的新方法，没有（甲基）丙烯酰氧基烷基的环状有机聚硅氧烷低聚物。与常规酸性催化剂不同，可以通过使用H +形式的阳离子交换树脂来促进反应，其可以在聚合反应完成后容易地从聚合混合物中除去，而不产生影响稳定性的酸性物质产品。在与极性有机溶剂如四氢呋喃浸渍或溶胀的环状有机聚硅氧烷低聚物接触之前，可以进一步提高阳离子交换树脂的催化效率。

9. 发明授权

US5408837A Method and apparatus of controlling air conditioner 失效
标题翻译：空调控制方法及装置
公开(公告)号：US5408837A
公开(公告)日：1995-04-25
申请号：US113641
申请日：1993-08-31
申请人： Naoki Omura
发明人： Naoki Omura
IPC分类号： F24F11/02 , F24F11/00 , F25B49/02 , G05D23/19 , F25D17/00
CPC分类号： F25B49/027 , F24F11/00 , G05D23/1931 , F24F2011/0013 , F24F2011/0073 , F25B2600/111 , Y02B30/743
摘要： Outside air temperature detected by an outside air temperature sensor (13) is given to an outside air temperature memory (14), a comparator (15) and a fan volume control section (16), respectively. The fan volume control section (16) drives an outside fan motor (18) at a revolution speed determined by outside air temperature and revolution speed of a compressor. The outside air temperature memory (14) is activated in response to an operation start command to store the outside air temperature detected at the operation start therein. Further, a timer (17) is activated in response to the same operation start command, and a time-up signal (e.g., after 18 min has elapsed) is outputted from the timer to activate the comparator (15). The comparator (15) compares the outside air temperature detected at the operation start with that detected in response to the timer-up signal to check whether air short circuit occurs or not. In case of the air short circuit, the fan volume control section (16) outputs a detection signal of the short circuit to the outside fan motor ( 18), so that the outside fan motor (18) is driven at a speed higher than that determined under the ordinary conditions.
摘要翻译：外部空气温度传感器（13）检测到的外部空气温度分别被提供给外部空气温度存储器（14），比较器（15）和风扇容积控制部（16）。风扇容积控制部16以由外部空气温度和压缩机的转速决定的转速驱动外部风扇电动机18。外部空气温度存储器（14）响应于操作开始命令被激活以存储在其中的操作开始时检测到的外部空气温度。此外，定时器（17）响应于相同的操作开始命令被激活，并且从定时器输出时间信号（例如，经过18分钟之后）以激活比较器（15）。比较器（15）将在操作开始时检测到的外部空气温度与响应于定时器向上信号检测到的外部空气温度进行比较，以检查是否发生空气短路。在空气短路的情况下，风扇容积控制部16向外部风扇电动机18输出短路检测信号，从而外部风扇电动机18的驱动速度高于外部风扇电动机18。在普通条件下确定。

10. 发明授权

US5405908A Acrylic rubber composition 失效
标题翻译：丙烯酸橡胶组合物
公开(公告)号：US5405908A
公开(公告)日：1995-04-11
申请号：US178972
申请日：1994-01-07
申请人： Masaharu Takahashi , Naoki Omura
发明人： Masaharu Takahashi , Naoki Omura
IPC分类号： C08K3/04 , C08K3/00 , C08K3/36 , C08L33/04 , C08L33/06 , C08L43/04 , C08L83/04 , C08K3/34
CPC分类号： C08K3/0033 , C08L43/04 , C08L83/04
摘要： An improvement is proposed for an acrylic rubber composition to decrease the stickiness of the rubber composition under processing and shaped and vulcanized articles of the composition to a metallic surface with which the rubber article is kept in contact at an elevated temperature under compression as is the case in packings, gaskets and O-rings as automobile parts. The improvement can be obtained by compounding the rubber composition consisting of an acrylic rubbery polymer, which can be substituted by organosilicon groups, and a reinforcing filler with a limited amount of a specific diorganopolysiloxane, e.g., dimethyl polysiloxane, of which from 5 to 50% in number of the organic groups bonded to the silicon atoms are phenyl groups.
摘要翻译：提出了一种丙烯酸类橡胶组合物的改进，以降低加工中的橡胶组合物的粘性，并将该组合物的成型和硫化制品与金属表面接触，在该金属表面处，橡胶制品在高压下在压缩下保持接触，如填料，垫圈和O形圈作为汽车零件。可以通过将由可被有机硅基团取代的丙烯酸橡胶状聚合物组成的橡胶组合物和具有有限量的特定二有机基聚硅氧烷（例如二甲基聚硅氧烷）的增强填料混合而获得，其中5至50％与硅原子键合的有机基团的数量是苯基。

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