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    • 4. 发明授权
    • Pretreatment method of a silicon wafer using nitric acid
    • 使用硝酸的硅片的预处理方法
    • US6090726A
    • 2000-07-18
    • US93072
    • 1998-06-08
    • Ming-Kwei Lee
    • Ming-Kwei Lee
    • H01L21/316H01L21/02B05D3/10
    • H01L21/316Y10S438/905
    • LPD (Liquid Phase Oxide Deposition) technology is a newly developed approach to deposit SiO.sub.2 on silicon wafers. LPD-SO.sub.2 film was deposited by immersing the wafer in hydrofluosilicic acid (H.sub.2 SiF.sub.6) solution supersaturated with silica gel at low temperature (about 40.degree. C.). LPD-SiO.sub.2, also the deformation of wafers is avoided so the method can be applied to the fabrication of integrated circuits. Moreover, this method has high potential to replace the CVD-SiO.sub.2. However, it is very hard to deposit LPD-SiO.sub.2 on very clean silicon wafer (e.g., without any oxide) because of no nucleation seed. In this study, the LPD-SiO.sub.2 was deposited on silicon wafer with a plasma-enhanced chemical vapor deposition oxide, a thermal oxide, an atmospheric pressure chemical vapor deposition oxide, and a nitric acid pretreatment oxide. The nitric acid pretreatment enhances the LPD-SiO.sub.2 growth rate and reduce the stress in the LPD-SiO.sub.2 film. In addition, it has a smaller dielectric constant and it can reduce the parasitic capacitance in integrated circuits.
    • LPD(液相氧化物沉积)技术是一种新开发的在硅晶片上沉积SiO 2的方法。 将晶片浸入硅胶在低温(约40℃)过饱和的氢氟硅酸(H2SiF6)溶液中沉积LPD-SO2膜。 LPD-SiO2,也避免了晶片的变形,因此该方法可以应用于集成电路的制造。 此外,该方法具有取代CVD-SiO 2的高潜力。 然而,由于没有成核种子,很难将LPD-SiO 2沉积在非常干净的硅晶片上(例如,没有任何氧化物)。 在这项研究中,LPD-SiO2用等离子体增强化学气相沉积氧化物,热氧化物,大气压化学气相沉积氧化物和硝酸预处理氧化物沉积在硅晶片上。 硝酸预处理提高了LPD-SiO2的生长速率,降低了LPD-SiO2膜的应力。 此外,它具有较小的介电常数,并且可以降低集成电路中的寄生电容。
    • 5. 发明授权
    • Method for manufacturing porous blue light emitting diode
    • 多孔蓝色发光二极管的制造方法
    • US5705047A
    • 1998-01-06
    • US631271
    • 1996-04-12
    • Ming-Kwei Lee
    • Ming-Kwei Lee
    • H01L33/34H01L33/00C25D11/02
    • H01L33/346Y10S438/96
    • A method for manufacturing a porous blue light emitting diode comprising the steps of preparing a silicon substrate having a back surface, applying a conducting layer on the back surface, annealing the substrate coated with the conducting layer in an inert gas atmosphere, applying an anti-corrosion layer on the conducting layer, immersing the anti-corrosion layer-applied substrate in a hydrofluoric acid aqueous solution with a concentration of about 5% by volume, applying a voltage to the resulting layers for eroding the anti-corrosion layer-applied substrate to form a porous layer having Si wires on a top surface of the substrate, and oxidizing the porous layer for making sizes of the Si wires small enough for emitting light having a peak occuring at a wavelength shorter than about 520 nm. This method offers a simple and feasible way to fabricate a porous blue light emitting diode.
    • 一种制造多孔蓝色发光二极管的方法,包括以下步骤:制备具有背面的硅衬底,在背面上施加导电层,在惰性气体气氛中退火涂覆有导电层的衬底, 将导电层上的腐蚀层浸渍在具有约5体积%的浓度的氢氟酸水溶液中,将所施加的防腐蚀层的基板浸渍在所得到的层中,以将防腐蚀层施加的基板侵蚀到 在衬底的顶表面上形成具有Si线的多孔层,并且氧化多孔层以使Si线的尺寸足够小以发射出现在波长短于约520nm的峰的光。 该方法提供了制造多孔蓝色发光二极管的简单且可行的方法。
    • 6. 发明授权
    • Method for manufacturing a photodetector for sensing light having a
wavelength within a wide range
    • 一种光检测器的制造方法,用于感测波长在宽范围内的光
    • US5665423A
    • 1997-09-09
    • US386960
    • 1995-02-10
    • Ming-Kwei Lee
    • Ming-Kwei Lee
    • H01L31/028B05D5/12H01L31/18
    • H01L31/028Y02E10/547Y10S438/96
    • The present invention is related to a method for manufacturing a photodetector which comprises the steps of: (a) preparing a substrate having a back surface; (b) applying a first conducting layer on the back surface; (c) annealing the substrate coated with the first conducting layer in an inert gas atmosphere; (d) applying a anti-corrosion layer on the first conducting layer; (e) immersing the anti-corrosion layer-applied substrate in a hydrofluoric acid aqueous solution with a concentration of 5%.about.10%; (f) eroding the anti-corrosion layer-applied substrate under a current density of about 12.5.about.25 mA/cm.sup.2 for about 5.about.40 minutes to obtain a porous layer therereon; and (g) applying a thin film layer of a second conducting layer to an upper surface of the porous layer to obtain the photodetector. The present photodetector has a wider frequency band and a higher sensitivity than conventional ones and the present manufacturing method is simple and economical.
    • 本发明涉及一种用于制造光电探测器的方法,该方法包括以下步骤:(a)制备具有背面的衬底; (b)在所述背面施加第一导电层; (c)在惰性气体气氛中退火涂有第一导电层的基材; (d)在第一导电层上施加防腐蚀层; (e)将防腐蚀层施加的基材浸渍在浓度为5%的浓度的10%的氢氟酸水溶液中; (f)在约25分钟/分钟的电流密度下,在约25℃/分钟的电流密度下腐蚀所述防腐蚀层的衬底,约40分钟,以获得多孔层; 和(g)将第二导电层的薄膜层施加到多孔层的上表面以获得光电检测器。 本发明的光电检测器具有比常规的更宽的频带和更高的灵敏度,并且本发明的制造方法简单且经济。