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1. 发明授权

US4721732A Polymeric articles and methods of manufacture thereof 失效
标题翻译：聚合物及其制造方法
公开(公告)号：US4721732A
公开(公告)日：1988-01-26
申请号：US858484
申请日：1986-04-30
申请人： Robert S. Dubrow , Michael F. Froix
发明人： Robert S. Dubrow , Michael F. Froix
IPC分类号： B29C61/00 , C08J9/26
CPC分类号： C08J9/26 , B29C61/003 , B29K2105/04
摘要： This invention provides a method for the preparation of an article from a blend of at least two molecularly compatible polymers by treating the blend with a solvent which is a solvent for one of the polymers and a non-solvent for the other. The solvent can be removed while the article is restrained from undergoing substantial shrinkage, in which case a microporous article is obtained. Alternatively, the solvent can be removed while the article is permitted to shrink. In this case high shrinkage force (also referred to as recovery force) results which can be utilized to apply the article to a substrate. The final and intermediate articles are novel. In a preferred embodiment, the invention provides a microporous article having an average pore size of about 0.005 microns to about 1 micron.
摘要翻译：本发明提供了一种由至少两种分子相容的聚合物的共混物制备制品的方法，其通过用作为聚合物之一的溶剂的溶剂和另一种的非溶剂处理该共混物。可以在制品被抑制发生大量收缩的同时除去溶剂，在这种情况下获得微孔制品。或者，可以在允许制品收缩的同时除去溶剂。在这种情况下，可以将该物品应用于基材的高收缩力（也称为恢复力）。最后和中间的文章是新颖的。在优选的实施方案中，本发明提供了具有约0.005微米至约1微米的平均孔径的微孔制品。

2. 发明授权

US4276397A Blend of polyarylene sulfide and wholly aromatic polyester 失效
标题翻译：聚芳硫醚和全芳族聚酯的共混物
公开(公告)号：US4276397A
公开(公告)日：1981-06-30
申请号：US166631
申请日：1980-07-07
申请人： Michael F. Froix
发明人： Michael F. Froix
IPC分类号： C08L81/00 , C08L1/00 , C08L27/00 , C08L67/00 , C08L67/02 , C08L81/02
CPC分类号： C08L67/00 , C08L67/02 , C08L81/02
摘要： A polymer blend which is capable of exhibiting an anisotropic melt phase, improved processability characteristics, and the ability to form molded articles having satisfactory mechanical properties is provided. The polymer blend comprises approximately 5 to approximately 95 percent by weight, based upon the total weight of the blend, of a polyarylene sulfide and approximately 5 to approximately 95 percent by weight, based upon the total weight of the blend, of a melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase apart from the blend. Blend compositions containing high concentrations of wholly aromatic polyester (i.e., at least 60 percent by weight wholly aromatic polyester) can be used to form fibers and films.
摘要翻译：提供能够显示各向异性熔融相的聚合物共混物，改善的加工特性，以及形成具有令人满意的机械性能的成型制品的能力。聚合物共混物包含约5至约95重量％，基于共混物的总重量，聚芳硫醚和约5至约95重量％，基于共混物的总重量，可熔融加工的全部能够与共混物分离形成各向异性熔融相的芳族聚酯。含有高浓度全芳族聚酯（即至少60重量％的全芳族聚酯）的共混组合物可用于形成纤维和薄膜。

3. 发明授权

US4859715A Microporous poly (arylether ketone) article 失效
标题翻译：微孔聚（芳基醚酮）制品
公开(公告)号：US4859715A
公开(公告)日：1989-08-22
申请号：US119140
申请日：1987-11-10
申请人： Robert S. Dubrow , Michael F. Froix
发明人： Robert S. Dubrow , Michael F. Froix
IPC分类号： B29C61/00 , C08J9/26
CPC分类号： B29C61/003 , C08J9/26 , B29K2105/04 , Y10S525/928
摘要： This invention provides a method for the preparation of an article from a blend of at least two molecularly compatible polymers by treating the blend with a solvent which is a solvent for one of the polymers and a non-solvent for the other. The solvent can be removed while the article is restrained from undergoing substantial shrinkage, in which case a microporous article is obtained. Alternatively, the solvent can be removed while the article is permitted to shrink. In this case high shrinkage force (also referred to as recovery force) results which can be utilized to apply the article to a substrate. The final and intermediate articles are novel. In a preferred embodiment, the invention provides a microporous article having an average pore size of about 0.005 microns to about 1 micron.
摘要翻译：本发明提供了一种由至少两种分子相容的聚合物的共混物制备制品的方法，其通过用作为聚合物之一的溶剂的溶剂和另一种的非溶剂处理该共混物。可以在制品被抑制发生大量收缩的同时除去溶剂，在这种情况下获得微孔制品。或者，可以在允许制品收缩的同时除去溶剂。在这种情况下，可以将该物品应用于基材的高收缩力（也称为恢复力）。最后和中间的文章是新颖的。在优选的实施方案中，本发明提供了具有约0.005微米至约1微米的平均孔径的微孔制品。

4. 发明授权

US4409370A Thermoplastic blend of oxymethylene copolymers exhibiting improved impact resistance 失效
标题翻译：具有改善耐冲击性的甲醛共聚物的热塑性共混物
公开(公告)号：US4409370A
公开(公告)日：1983-10-11
申请号：US382215
申请日：1982-05-26
申请人： Michael F. Froix , Rajal M. Kusumgar
发明人： Michael F. Froix , Rajal M. Kusumgar
IPC分类号： C08G2/18 , C08L59/02 , C08L59/04
CPC分类号： C08G2/18 , C08L59/02
摘要： A polymer blend comprising a first copolymer and a second copolymer and having improved impact resistance is provided. The first copolymer has recurring units which consist essentially of oxymethylene groups having the formula --OCH.sub.2 --interspersed with ##STR1## groups, where each R.sub.1 and R.sub.2 is selected from the group consisting of hydrogen, lower alkyl radicals, and halogen-substituted lower alkyl radicals, each R.sub.3 is selected from the group consisting of methylene, oxymethylene, lower alkyl and haloalkyl substituted methylene, and lower alkyl and haloalkyl substituted oxymethylene radicals, and n is an integer from zero to three, each lower alkyl radical having one to two carbon atoms. The oxymethylene units comprise approximately 85 to approximately 99.9 mole percent of the recurring units of the first copolymer. The second copolymer has recurring units which consist essentially of oxymethylene groups having the formula--OCH.sub.2 --interspersed with ##STR2## groups where R.sub.1, R.sub.2, R.sub.3, and n have the same meanings as the corresponding symbols used with regard to the first copolymer and where the selections made with regard to the second copolymer are independent of the selections made with regard to the first copolymer, the oxymethylene groups of the second copolymer comprising approximately 50 to approximately 75 mole percent of the recurring units of the second copolymer. The second copolymer comprises approximately 1.5 to approximately 40 weight percent of the blend.
摘要翻译：提供了包含第一共聚物和第二共聚物并具有改善的耐冲击性的聚合物共混物。第一共聚物具有重复单元，其基本上由具有分子式为-OCH 2 - 的亚甲基基团组成，其中每个R 1和R 2选自氢，低级烷基和卤素取代的低级烷基每个R 3选自亚甲基，亚甲基，低级烷基和卤代烷基取代的亚甲基，低级烷基和卤代烷基取代的氧亚甲基，n为0至3的整数，每个低级烷基具有1至2个碳原子。甲醛单元包含第一共聚物的约85-约99.9摩尔％的重复单元。第二共聚物具有重复单元，其基本上由具有以下基团的亚甲基基团组成：-O 2 - 分别与其中R 1，R 2，R 3和n具有与用于第一共聚物的相应符号相同的含义，其中关于第二共聚物的选择与对第一共聚物的选择无关，第二共聚物的甲醛基包含约50-约75摩尔％的第二共聚物的重复单元。第二共聚物包含约1.5至约40重量％的共混物。

5. 发明授权

US4267289A Blend of wholly aromatic polyesters 失效
标题翻译：全芳香族聚酯的共混物
公开(公告)号：US4267289A
公开(公告)日：1981-05-12
申请号：US165534
申请日：1980-07-03
申请人： Michael F. Froix
发明人： Michael F. Froix
IPC分类号： C08G63/00 , C08G63/19 , C08G63/60 , C08L1/00 , C08L27/00 , C08L67/00
CPC分类号： C08L67/00
摘要： A polymer blend which is capable of exhibiting an anisotropic melt phase and which is capable of forming shaped articles which exhibit satisfactory mechanical properties is provided. The polymer blend comprises approximately 5 to approximately 95 percent by weight, based upon the total weight of the blend, of a first melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase apart from the blend and which comprises not less than approximately 10 mole percent of recurring units which include a naphthalene moiety, and approximately 5 to approximately 95 percent by weight, based upon the total weight of the blend, of a second melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase apart from the blend (as defined).
摘要翻译：提供能够显示各向异性熔融相并且能够形成表现出令人满意的机械性能的成形制品的聚合物共混物。聚合物共混物包含基于共混物总重量的约5至约95重量％的第一可熔融加工的全芳族聚酯，该第一可熔融加工的全芳族聚酯能够与共混物分开形成各向异性熔体相，并且包括不小于约 10摩尔％的包含萘部分的重复单元和基于共混物总重量的约5至约95重量％的能够形成各向异性熔融相的第二可熔融加工的全芳族聚酯，混合（定义）。

6. 发明授权

US4489190A Blend of polyalkylene terephthalate and wholly aromatic polyester 失效
标题翻译：聚对苯二甲酸亚烷基酯和全芳族聚酯的共混物
公开(公告)号：US4489190A
公开(公告)日：1984-12-18
申请号：US158547
申请日：1980-06-11
申请人： Michael F. Froix
发明人： Michael F. Froix
IPC分类号： C08L67/00 , C08L1/00 , C08L27/00 , C08L67/02
CPC分类号： C08L67/02
摘要： A polymer blend which is capable of exhibiting an anisotropic melt phase and the ability to form shaped articles having satisfactory mechanical properties is provided. The polymer blend comprises approximately 5 to approximately 75 percent by weight, based upon the total weight of the blend, of a polyalkylene terephthalate wherein the alkylene units contain 2 to 5 carbon atoms and approximately 25 to approximately 95 percent by weight, based upon the total weight of the blend, of a melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase apart from the blend.
摘要翻译：提供能够显示各向异性熔融相的聚合物共混物和形成具有令人满意的机械性能的成形制品的能力。基于共混物的总重量，聚合物共混物包含约5至约75重量％的聚对苯二甲酸亚烷基酯，其中亚烷基单元含有2至5个碳原子和约25至约95重量％，基于总计共混物的重量，可熔融加工的全芳族聚酯，其能够形成与共混物分离的各向异性熔融相。

7. 发明授权

US4460735A Blend of polycarbonate and wholly aromatic polyester 失效
标题翻译：聚碳酸酯和全芳族聚酯的共混物
公开(公告)号：US4460735A
公开(公告)日：1984-07-17
申请号：US165536
申请日：1980-07-03
申请人： Michael F. Froix
发明人： Michael F. Froix
IPC分类号： C08L67/00 , C08L69/00
CPC分类号： C08L67/00 , C08L69/00
摘要： A polymer blend which is capable of exhibiting an anisotropic melt phase and the ability to form shaped articles having improved mechanical properties is provided. The polymer blend comprises approximately 5 to approximately 75 percent by weight, based upon the total weight of the blend, of a polycarbonate and approximately 25 to approximately 95 percent by weight, based upon the total weight of the blend, of a melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase apart from the blend.
摘要翻译：提供能够显示各向异性熔融相的聚合物共混物和形成具有改善的机械性能的成形制品的能力。基于共混物的总重量，聚合物共混物包含约5至约75重量％的聚碳酸酯和约25至约95重量％，基于共混物的总重量，可熔融加工的全芳族能够与共混物分离形成各向异性熔融相的聚酯。

8. 发明授权

US4879338A Poly(aryl ether ketone) compositions 失效
标题翻译：聚（芳醚酮）组合物
公开(公告)号：US4879338A
公开(公告)日：1989-11-07
申请号：US701279
申请日：1985-02-13
申请人： Frank W. Mercer , Michael F. Froix , Tai C. Cheng
发明人： Frank W. Mercer , Michael F. Froix , Tai C. Cheng
IPC分类号： C08L71/00
CPC分类号： C08L71/00
摘要： This invention discloses novel composition comprising a blend of a poly(aryl ether ketone) and from about 1% to about 50% of poly(phenylene oxide). The blends have high use temperatures, abraision resistance and solvent resistance, and are extrudable. Further, the blends can be crosslinked.
摘要翻译：本发明公开了包含聚（芳基醚酮）和约1％至约50％的聚（苯醚）共混物的新型组合物。共混物具有高的使用温度，耐磨性和耐溶剂性，并且是可挤出的。此外，共混物可以是交联的。

9. 发明授权

US4460736A Blend of sulfone polymer and wholly aromatic polyester 失效
标题翻译：砜聚合物和全芳族聚酯的共混物
公开(公告)号：US4460736A
公开(公告)日：1984-07-17
申请号：US165532
申请日：1980-07-03
申请人： Michael F. Froix , Norman Trouw
发明人： Michael F. Froix , Norman Trouw
IPC分类号： C08L81/00 , C08L1/00 , C08L27/00 , C08L67/00 , C08L67/02 , C08L81/06
CPC分类号： C08L67/02 , C08L81/06 , Y10S525/906
摘要： A polymer blend which is capable of exhibiting an anisotropic melt phase, improved processability characteristics, and the ability to form shaped articles having satisfactory mechanical properties is provided. The polymer blend comprises approximately 5 to approximately 75 percent by weight, based upon the total weight of the blend, of a sulfone polymer which is selected from the group consisting of polyether sulfone having recurring units of the formula ##STR1## polysulfone having recurring units of the formula ##STR2## a mixture of the above sulfone polymers, and approximately 25 to approximately 95 percent by weight, based upon the total weight of the blend, of a melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase apart from the blend.
摘要翻译：提供能够显示各向异性熔融相，改进的加工特性以及形成具有令人满意的机械性能的成形制品的能力的聚合物共混物。聚合物共混物包含基于共混物总重量的约5至约75重量％的砜聚合物，所述砜聚合物选自具有下式的重复单元的聚醚砜：具有重复单元的重复单元上述砜聚合物的混合物，基于共混物的总重量为约25至约95重量％的可熔融加工的全芳族聚酯，其能够形成各向异性熔体相分离混合。

10. 发明授权

US4025541A Charge transfer complexes of ferrocenes having light filtering properties 失效
标题翻译：具有光过滤性能的二茂铁的电荷转移络合物
公开(公告)号：US4025541A
公开(公告)日：1977-05-24
申请号：US632925
申请日：1975-11-18
申请人： Michael F. Froix
发明人： Michael F. Froix
IPC分类号： C07F17/02 , G02B5/22 , G02B5/24
CPC分类号： G02B5/24 , C07F17/02 , G02B5/223
摘要： Ferrocene ionic charge complexes of benzoquinones having utility as optical filters capable of absorbing electromagnetic radiations within the range of 3500 - 6000 Angstrom. The active material can be utilized in a suitable optical system as a liquid filter in the form of a solution, emulsion, gel, etc., or as a film together with suitable light permeable backing or support members.
摘要翻译：具有作为滤光器使用的能够吸收3500-6000埃范围内的电磁辐射的苯醌的二茂铁离子电荷络合物。活性材料可以在合适的光学系统中用作溶液，乳液，凝胶等形式的液体过滤器，或者与合适的透光性背衬或支撑构件一起用作膜。

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