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    • 2. 发明授权
    • Blended fluoropolymer compositions
    • 混合的含氟聚合物组合物
    • US08691344B2
    • 2014-04-08
    • US12468580
    • 2009-05-19
    • Leonard W. HarveyMichael CoatesJulie K. Wright
    • Leonard W. HarveyMichael CoatesJulie K. Wright
    • B05D3/02
    • C08L27/18C08J3/005C08J3/12C08J2327/18C08L27/12C08L27/24C08L29/10C08L2201/50C08L2205/02C08L2205/025C09D5/03C09D127/12C09D127/18C09D129/10Y10T428/2982C08L2666/04
    • Blended fluoropolymer compositions are provided. In one embodiment, a liquid dispersion of a first fluoropolymer is blended with a liquid dispersion of a second fluoropolymer. The first fluoropolymer may be polytetrafluoroethylene (PTFE), such as a low molecular weight PTFE (LPTFE) that has been polymerized via a dispersion or emulsion polymerization process, and which has not been agglomerated, irradiated, or thermally degraded. The LPTFE may be in the form of an aqueous dispersion, having a mean particle size of less than 1.0 microns (μm), with the LPTFE having a first melt temperature (Tm) of 332° C. or less. The second fluoropolymer may be a melt processible fluoropolymer (MPF), such as methylfluoroalkoxy (MFA), fluorinated ethylene propylene (FEP), or perfluoroalkoxy (PFA), for example, in the form of an aqueous dispersion, and having a mean particle size of less than 1.0 microns (μm). Blending of the dispersions facilitates interaction of the LPTFE and MPF on a submicron level to facilitate intimate blending such that, when the blended fluoropolymer composition is dried, a crystal structure representing a true alloy of the fluoropolymers is formed, having melt characteristics that differ from those of the individual fluoropolymers. The blended fluoropolymer composition may be used to provide a coating having improved impermeability, stain resistance, abrasion resistance, smoothness, and higher contact angles.
    • 提供混合的含氟聚合物组合物。 在一个实施方案中,将第一含氟聚合物的液体分散体与第二含氟聚合物的液体分散体共混。 第一含氟聚合物可以是聚四氟乙烯(PTFE),例如已经通过分散体或乳液聚合方法聚合并且未被聚集,照射或热降解的低分子量PTFE(LPTFE)。 LPTFE可以是水分散体的形式,其平均粒度小于1.0微米(μm),LPTFE的第一熔融温度(Tm)为332℃或更低。 第二含氟聚合物可以是可熔融加工的含氟聚合物(MPF),例如甲基氟代烷氧基(MFA),氟化乙烯丙烯(FEP)或全氟烷氧基(PFA),例如以水分散体的形式,并且具有平均粒径 小于1.0微米(μm)。 分散体的混合促进了LPTFE和MPF在亚微米级的相互作用,以促进紧密共混,使得当混合的含氟聚合物组合物被干燥时,形成表示含氟聚合物的真正合金的晶体结构,其熔体特性与那些 的各种含氟聚合物。 混合的含氟聚合物组合物可用于提供具有改进的不渗透性,耐污性,耐磨性,光滑度和更高接触角的涂层。
    • 4. 发明授权
    • Method of treating fluoropolymer particles and the products thereof
    • 氟聚合物颗粒及其制品的处理方法
    • US07811631B2
    • 2010-10-12
    • US11463498
    • 2006-08-09
    • Michael CoatesWes DemondeKurt Davidson
    • Michael CoatesWes DemondeKurt Davidson
    • B05D7/00
    • C08J3/28C08F8/00C08F14/18C08J3/12C08J2327/12C08F2/02C08F114/26C08F114/22C08F214/26C08F214/245
    • Fluoropolymer particles are subjected to high energy treatment so as to change the chemical functionality of the particle surfaces and thereby change the surface characteristics of the particles. These characteristics improve the usefulness of these particles and can make them highly dispersible, even in water. The surface treated fluoropolymer particles are subject to a chemical crosslinking process, or alternatively, are subject to a high energy treatment process, and may optionally be pretreated with a macromolecular chemical species prior to the foregoing processes. The high energy treatment can be used to both surface treat the fluoropolymer particles and in some embodiments, may also cause chain scission of the fluoropolymers to thereby reduce the molecular weight of the fluoropolymer particles. The surface treated fluoropolymer particles can be used to form fluoropolymer coatings on various substrates.
    • 对含氟聚合物颗粒进行高能量处理,以改变颗粒表面的化学官能度,从而改变颗粒的表面特性。 这些特性提高了这些颗粒的有用性,并使其高度分散,甚至在水中。 表面处理的含氟聚合物颗粒经历化学交联过程,或者可以进行高能量处理工艺,并且可以任选地在上述方法之前用大分子化学物质进行预处理。 高能量处理可以用于表面处理含氟聚合物颗粒,并且在一些实施方案中,还可能引起含氟聚合物的链断裂,从而降低含氟聚合物颗粒的分子量。 表面处理的含氟聚合物颗粒可用于在各种基材上形成含氟聚合物涂层。
    • 6. 发明申请
    • METHOD OF TREATING FLUOROPOLYMER PARTICLES AND THE PRODUCTS THEREOF
    • 处理氟聚合物颗粒的方法及其制备方法
    • US20070059445A1
    • 2007-03-15
    • US11463498
    • 2006-08-09
    • Michael CoatesWes DemondeKurt Davidson
    • Michael CoatesWes DemondeKurt Davidson
    • B05D7/00B29C71/04
    • C08J3/28C08F8/00C08F14/18C08J3/12C08J2327/12C08F2/02C08F114/26C08F114/22C08F214/26C08F214/245
    • Fluoropolymer particles are subjected to high energy treatment so as to change the chemical functionality of the particle surfaces and thereby change the surface characteristics of the particles. These characteristics improve the usefulness of these particles and can make them highly dispersible, even in water. The surface treated fluoropolymer particles are subject to a chemical crosslinking process, or alternatively, are subject to a high energy treatment process, and may optionally be pretreated with a macromolecular chemical species prior to the foregoing processes. The high energy treatment can be used to both surface treat the fluoropolymer particles and in some embodiments, may also cause chain scission of the fluoropolymers to thereby reduce the molecular weight of the fluoropolymer particles. The surface treated fluoropolymer particles can be used to form fluoropolymer coatings on various substrates.
    • 对含氟聚合物颗粒进行高能量处理,以改变颗粒表面的化学官能度,从而改变颗粒的表面特性。 这些特性提高了这些颗粒的有用性,并使其高度分散,甚至在水中。 表面处理的含氟聚合物颗粒经历化学交联过程,或者可以进行高能量处理工艺,并且可以任选地在上述方法之前用大分子化学物质进行预处理。 高能量处理可以用于表面处理含氟聚合物颗粒,并且在一些实施方案中,还可能引起含氟聚合物的链断裂,从而降低含氟聚合物颗粒的分子量。 表面处理的含氟聚合物颗粒可用于在各种基材上形成含氟聚合物涂层。