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1. 发明申请

US20130211162A1 METHOD AND SYSTEM FOR PURIFYING AN ETHYLENE-CONTAINING GAS STREAM 有权
标题翻译：用于净化含乙烯气体流的方法和系统
公开(公告)号：US20130211162A1
公开(公告)日：2013-08-15
申请号：US13396714
申请日：2012-02-15
申请人： Mingyong Sun , Steven A. Blankenship , Michael A. Urbancic , Richard Paul Zoldak
发明人： Mingyong Sun , Steven A. Blankenship , Michael A. Urbancic , Richard Paul Zoldak
IPC分类号： C07C7/167 , B01J19/00 , C07C7/00
CPC分类号： C07C7/167 , B01J23/462 , B01J23/50 , B01J35/0006 , B01J35/1009 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J37/0201 , C07C7/14841 , C10G70/00 , C10G70/02 , Y02P20/52 , C07C11/04
摘要： A two catalyst system is described having separate catalyst beds for the selective conversion of acetylene to ethylene which reduces the concentration of acetylene, dienes, O2, and NOx is disclosed. An ethylene containing gas stream, such as an off-gas stream from a refinery catalytic cracking unit used in the production of fuels and gas oils, is treated by first contacting the gas stream with a silver catalyst supported on a metal oxide and subsequently contacting the gas stream with a ruthenium catalyst supported on metal oxide. The two catalysts are contained within contiguous continuous reactors or reactor compartments.
摘要翻译：描述了两种催化剂体系，其具有用于乙炔选择性转化为乙烯的单独的催化剂床，其中公开了降低乙炔，二烯，O 2和NO x的浓度。通过首先使气流与负载在金属氧化物上的银催化剂接触，然后接触含有乙烯的气流，例如来自用于生产燃料和瓦斯油的炼油催化裂化装置的废气流，气流与钌催化剂负载在金属氧化物上。两个催化剂包含在连续的连续反应器或反应器隔室内。

2. 发明授权

US08426660B2 Process for purification of ethylene-containing feedstreams 有权
标题翻译：纯化含乙烯进料流的方法
公开(公告)号：US08426660B2
公开(公告)日：2013-04-23
申请号：US12195678
申请日：2008-08-21
申请人： Mingyong Sun , Martin Byran , Steven A. Blankenship , Michael A. Urbancic
发明人： Mingyong Sun , Martin Byran , Steven A. Blankenship , Michael A. Urbancic
IPC分类号： C07C5/08
CPC分类号： C07C7/167 , B01J23/462 , B01J23/48 , B01J23/60 , B01J23/62 , B01J23/6447 , B01J23/8926 , B01J35/008 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J37/20 , Y02P20/52 , C07C11/04
摘要： A method for purification of ethylene-containing feedstreams from steam crackers or fluid catalytic crackers (FCC), wherein the feedstreams further comprises hydrogen, carbon monoxide, acetylenes, oxygen, nitric oxides, is disclosed. The method comprises contacting an ethylene-comprising gas stream with a Ru-based catalyst at reaction temperatures of at least 120°C. The process results in an ethylene-containing feedstream wherein the ethylene is essentially free of acetylenes, nitric oxides and oxygen. The purifying of the feedstream occurs with minimal loss of ethylene.
摘要翻译：公开了一种用于从蒸气裂化器或流化催化裂化器（FCC）中纯化含乙烯进料流的方法，其中进料流还包含氢气，一氧化碳，乙炔，氧气，一氧化氮。该方法包括在至少120℃的反应温度下使含乙烯的气流与Ru-基催化剂接触。该方法产生含乙烯的进料流，其中乙烯基本上不含乙炔，一氧化氮和氧。进料流的纯化以最小的乙烯损失发生。

3. 发明授权

US08188328B2 Endothermic hydrocarbon conversion process 有权
标题翻译：吸热烃转化过程
公开(公告)号：US08188328B2
公开(公告)日：2012-05-29
申请号：US13169157
申请日：2011-06-27
申请人： Vladimir Fridman , Michael A. Urbancic
发明人： Vladimir Fridman , Michael A. Urbancic
IPC分类号： C07C2/76 , C07C2/78 , C07C5/08 , C07C11/00 , C07C5/09 , C07C5/327 , B01J20/00 , B01J23/00
CPC分类号： B01J23/26 , B01J23/32 , B01J23/72 , B01J35/0006 , C07C5/3332 , C07C2521/02 , C07C2521/04 , C07C2521/08 , C07C2521/10 , C07C2521/12 , C07C2523/02 , C07C2523/04 , C07C2523/06 , C07C2523/26 , C07C2523/34 , C07C2523/72 , C07C2523/889 , C07C2529/04 , Y02P20/52 , C07C11/06 , C07C11/09
摘要： The present invention is an improved cyclic, endothermic hydrocarbon conversion process and a catalyst bed system for accomplishing the same. Specifically, the improved process comprises reacting a hydrocarbon with a multi-component catalyst bed in such a manner that the temperature within the catalyst bed remains within controlled temperature ranges throughout all stages of the process. The multi-component catalyst bed comprises a reaction-specific catalyst physically mixed with a heat-generating material.
摘要翻译：本发明是一种改进的循环，吸热烃转化方法和用于实现它的催化剂床系统。具体地，改进的方法包括使烃与多组分催化剂床反应，使得催化剂床内的温度在整个过程的所有阶段都保持在受控温度范围内。多组分催化剂床包括与发热材料物理混合的反应特异性催化剂。

4. 发明申请

US20110251448A1 ENDOTHERMIC HYDROCARBON CONVERSION PROCESS 有权
标题翻译：内热转化碳转化过程
公开(公告)号：US20110251448A1
公开(公告)日：2011-10-13
申请号：US13169157
申请日：2011-06-27
申请人： Vladimir Fridman , Michael A. Urbancic
发明人： Vladimir Fridman , Michael A. Urbancic
IPC分类号： C07C5/42 , B01J19/00
CPC分类号： B01J23/26 , B01J23/32 , B01J23/72 , B01J35/0006 , C07C5/3332 , C07C2521/02 , C07C2521/04 , C07C2521/08 , C07C2521/10 , C07C2521/12 , C07C2523/02 , C07C2523/04 , C07C2523/06 , C07C2523/26 , C07C2523/34 , C07C2523/72 , C07C2523/889 , C07C2529/04 , Y02P20/52 , C07C11/06 , C07C11/09
摘要： The present invention is an improved cyclic, endothermic hydrocarbon conversion process and a catalyst bed system for accomplishing the same. Specifically, the improved process comprises reacting a hydrocarbon with a multi-component catalyst bed in such a manner that the temperature within the catalyst bed remains within controlled temperature ranges throughout all stages of the process. The multi-component catalyst bed comprises a reaction-specific catalyst physically mixed with a heat-generating material.
摘要翻译：本发明是一种改进的循环，吸热烃转化方法和用于实现它的催化剂床系统。具体地，改进的方法包括使烃与多组分催化剂床反应，使得催化剂床内的温度在整个过程的所有阶段都保持在受控温度范围内。多组分催化剂床包括与发热材料物理混合的反应特异性催化剂。

5. 发明授权

US09670115B2 Method and system for purifying an ethylene-containing gas stream 有权
公开(公告)号：US09670115B2
公开(公告)日：2017-06-06
申请号：US13396714
申请日：2012-02-15
申请人： Mingyong Sun , Steven A. Blankenship , Michael A. Urbancic , Richard Paul Zoldak
发明人： Mingyong Sun , Steven A. Blankenship , Michael A. Urbancic , Richard Paul Zoldak
IPC分类号： C07C7/167 , C07C7/163 , B01J23/50 , C07C7/148 , B01J35/00 , B01J23/46 , B01J35/10 , B01J37/02 , C10G70/00 , C10G70/02
CPC分类号： C07C7/167 , B01J23/462 , B01J23/50 , B01J35/0006 , B01J35/1009 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J37/0201 , C07C7/14841 , C10G70/00 , C10G70/02 , Y02P20/52 , C07C11/04
摘要： A two catalyst system is described having separate catalyst beds for the selective conversion of acetylene to ethylene which reduces the concentration of acetylene, dienes, O2, and NOx is disclosed. An ethylene containing gas stream, such as an off-gas stream from a refinery catalytic cracking unit used in the production of fuels and gas oils, is treated by first contacting the gas stream with a silver catalyst supported on a metal oxide and subsequently contacting the gas stream with a ruthenium catalyst supported on metal oxide. The two catalysts are contained within contiguous continuous reactors or reactor compartments.

6. 发明授权

US07973207B2 Endothermic hydrocarbon conversion process 有权
标题翻译：吸热烃转化过程
公开(公告)号：US07973207B2
公开(公告)日：2011-07-05
申请号：US11873367
申请日：2007-10-16
申请人： Vladimir Fridman , Michael A. Urbancic
发明人： Vladimir Fridman , Michael A. Urbancic
IPC分类号： C07C2/76 , C07C2/78 , C07C5/08 , C07C11/00 , C07C5/09 , C07C5/327 , B01J20/00 , B01J23/00
CPC分类号： B01J23/26 , B01J23/32 , B01J23/72 , B01J35/0006 , C07C5/3332 , C07C2521/02 , C07C2521/04 , C07C2521/08 , C07C2521/10 , C07C2521/12 , C07C2523/02 , C07C2523/04 , C07C2523/06 , C07C2523/26 , C07C2523/34 , C07C2523/72 , C07C2523/889 , C07C2529/04 , Y02P20/52 , C07C11/06 , C07C11/09
摘要： The present invention is an improved cyclic, endothermic hydrocarbon conversion process and a catalyst bed system for accomplishing the same. Specifically, the improved process comprises reacting a hydrocarbon with a multi-component catalyst bed in such a manner that the temperature within the catalyst bed remains within controlled temperature ranges throughout all stages of the process. The multi-component catalyst bed comprises a reaction-specific catalyst physically mixed with a heat-generating material.
摘要翻译：本发明是一种改进的循环，吸热烃转化方法和用于实现它的催化剂床系统。具体地，改进的方法包括使烃与多组分催化剂床反应，使得催化剂床内的温度在整个过程的所有阶段都保持在受控温度范围内。多组分催化剂床包括与发热材料物理混合的反应特异性催化剂。

7. 发明申请

US20100048972A1 Process for Purification of Ethylene-Containing Feedstreams 有权
标题翻译：纯化含乙烯原料流的方法
公开(公告)号：US20100048972A1
公开(公告)日：2010-02-25
申请号：US12195678
申请日：2008-08-21
申请人： Mingyong Sun , Martin Byran , Steven A. Blankenship , Michael A. Urbancic
发明人： Mingyong Sun , Martin Byran , Steven A. Blankenship , Michael A. Urbancic
IPC分类号： C07C7/12
CPC分类号： C07C7/167 , B01J23/462 , B01J23/48 , B01J23/60 , B01J23/62 , B01J23/6447 , B01J23/8926 , B01J35/008 , B01J35/1009 , B01J35/1014 , B01J35/1019 , B01J37/20 , Y02P20/52 , C07C11/04
摘要： A method for purification of ethylene-containing feedstreams from steam crackers or fluid catalytic crackers (FCC), wherein the feedstreams further comprises hydrogen, carbon monoxide, acetylenes, oxygen, nitric oxides, is disclosed. The method comprises contacting an ethylene-comprising gas stream with a Ru-based catalyst at reaction temperatures of at least 120°C. The process results in an ethylene-containing feedstream wherein the ethylene is essentially free of acetylenes, nitric oxides and oxygen. The purifying of the feedstream occurs with minimal loss of ethylene.
摘要翻译：公开了一种用于从蒸气裂化器或流化催化裂化器（FCC）中纯化含乙烯进料流的方法，其中进料流还包含氢气，一氧化碳，乙炔，氧气，一氧化氮。该方法包括在至少120℃的反应温度下使含乙烯的气流与Ru-基催化剂接触。该方法产生含乙烯的进料流，其中乙烯基本上不含乙炔，一氧化氮和氧。进料流的纯化以最小的乙烯损失发生。

8. 发明授权

US07622623B2 Catalytically inactive heat generator and improved dehydrogenation process 有权
标题翻译：催化惰性热发生器和改进的脱氢工艺
公开(公告)号：US07622623B2
公开(公告)日：2009-11-24
申请号：US11218949
申请日：2005-09-02
申请人： Vladimir Fridman , Jay S. Merriam , Michael A. Urbancic
发明人： Vladimir Fridman , Jay S. Merriam , Michael A. Urbancic
IPC分类号： C07C2/76 , C07C2/78 , C07C5/08 , C07C11/00 , C07C5/09 , C07C5/327 , B01J23/00 , B01J20/00
CPC分类号： B01J23/32 , B01J23/26 , B01J23/72 , B01J35/0006 , C07C5/322 , C07C2521/02 , C07C2521/04 , C07C2521/08 , C07C2521/10 , C07C2521/12 , C07C2523/02 , C07C2523/04 , C07C2523/06 , C07C2523/26 , C07C2523/34 , C07C2523/72 , C07C2523/889 , C07C2529/04 , Y02P20/52 , Y02P20/584 , C07C11/06
摘要： An improved dehydrogenation catalyst bed system for olefin production utilizing classical processing techniques is disclosed. The catalyst bed system comprises a dehydrogenation catalyst comprising an active component selected from an oxide of a metal of Group 4 or Group 5 or Group 6 and combinations thereof and a support selected from aluminum oxide, aluminas, alumina monohydrate, alumina trihydrate, alumina-silica, transition aluminas, alpha-alumina, silica, silicate, aluminates, calcined hydrotalcites, zeolites and combinations thereof mixed with a first inert material selected from any material that is catalytically inactive when subjected to reaction conditions that can effect dehydrogenation of olefins and that has a high density and high heat capacity and that is not capable of producing heat during any stage of the dehydrogenation process, and the dehydrogenation catalyst plus the first inert material then being physically mixed with a secondary component comprising a heat-generating inert material and a carrier capable of supporting the heat-generating inert material, wherein the secondary component is catalytically inert with respect to dehydrogenation reactions or to cracking or to coking and generates heat after being exposed to reducing and/or to oxidizing reaction conditions.
摘要翻译：公开了一种利用经典处理技术改进用于烯烃生产的脱氢催化剂床系统。催化剂床系统包括脱氢催化剂，其包含选自第4组或第5组或第6组金属的氧化物及其组合的活性组分和选自氧化铝，氧化铝，一水合氧化铝，三水合氧化铝，氧化铝 - 二氧化硅，过渡氧化铝，α-氧化铝，二氧化硅，硅酸盐，铝酸盐，煅烧水滑石，沸石及其混合物与第一惰性材料混合，所述第一惰性材料选自任何可能影响烯烃脱氢反应条件的催化无活性物质，高密度和高热容量，并且在脱氢过程的任何阶段都不能产生热量，然后脱氢催化剂加第一惰性材料与包含发热惰性材料和载体的次级组分物理混合支撑发热惰性材料，其中次要组分相对于脱氢反应是催化惰性的，或者在暴露于还原和/或氧化反应条件之后开裂或焦化并产生热量。

9. 发明授权

US07271307B2 Method for improving the performance of a dehydrogenation catalyst 有权
标题翻译：改善脱氢催化剂性能的方法
公开(公告)号：US07271307B2
公开(公告)日：2007-09-18
申请号：US10695372
申请日：2003-10-28
申请人： Michael A. Urbancic , Michael W. Balakos , Robert J. Gartside , Robert J. Brummer
发明人： Michael A. Urbancic , Michael W. Balakos , Robert J. Gartside , Robert J. Brummer
IPC分类号： C07C5/327 , C07V5/333
CPC分类号： C07C5/3332 , Y02P20/52 , Y02P20/584 , C07C11/06 , C07C11/02
摘要： The present development relates to a modification of the Houdry process for the dehydrogenation of aliphatic hydrocarbons, whereby the dehydrogenation cycle is extended, or lengthened, and hydrogen gas is added into the reaction. The combination of the extended cycle with the hydrogen introduction results in a surprising stabilization of the production rate in the dehydrogenation process. The hydrogen gas may be introduced through a recycle step. The process of the present development is demonstrated for the dehydrogenation of propane to propylene.
摘要翻译：本发明涉及用于脂族烃脱氢的Houdry工艺的改进，从而使脱氢循环延长或延长，并将氢气加入到反应中。扩展循环与氢气引入的结合导致脱氢过程中生产速率的惊人稳定。可以通过再循环步骤引入氢气。本发明的过程证明了丙烷脱氢成丙烯。

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