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1. 发明授权

US4389335A Catalyst for carbon monoxide conversion in sour gas 失效
标题翻译：酸性气体中一氧化碳转化催化剂
公开(公告)号：US4389335A
公开(公告)日：1983-06-21
申请号：US253941
申请日：1981-04-14
申请人： Jay S. Merriam , Cecil B. Hogg
发明人： Jay S. Merriam , Cecil B. Hogg
IPC分类号： C01B3/48 , B01J23/78 , B01J23/84 , B01J23/85 , B01J23/88 , B01J27/04 , B01J27/232 , C01B3/16 , C01B3/40 , B01J23/34
CPC分类号： B01J23/8872 , B01J23/78 , B01J23/84 , B01J23/85 , B01J23/8871 , B01J23/8898 , B01J35/006 , B01J35/1009 , B01J35/1014 , B01J35/1019 , C01B3/16 , Y02P20/52
摘要： A process is disclosed for the conversion of carbon monoxide in sour synthesis gas mixtures in the presence of a catalyst which is active in the presence of sulfur compounds. The catalyst comprises known sulfactive metal oxides or sulfides supported on a shaped carrier. The catalytically active oxides or sulfides are doubly promoted with an alkali metal compound and an oxide or sulfide or manganese. The two promoters combined in proper ratio provide a synergistic effect on the activity of the catalyst which is enhanced beyond that of the singly promoted catalyst. The catalysts are active at relatively low temperatures of less than 500.degree. F., even in the presence of sulfur compounds. The equilibrium for the conversion of steam and carbon monoxide to hydrogen and CO.sub.2 is favored at lower temperatures.
摘要翻译：公开了在硫化合物存在下在催化剂存在下，在酸性合成气混合物中转化一氧化碳的方法。催化剂包括已知的支撑在成形载体上的磺化金属氧化物或硫化物。催化活性氧化物或硫化物用碱金属化合物和氧化物或硫化物或锰双重促进。合适比例的两种促进剂对催化剂的活性提供协同效应，其比单一促进的催化剂的活性增强。催化剂在低于500°F的相对低的温度下是有活性的，即使在硫化合物的存在下也是如此。蒸汽和一氧化碳转化为氢气和二氧化碳的平衡在较低的温度下是有利的。

2. 发明授权

US4233187A Catalyst and process for steam-reforming of hydrocarbons 失效
标题翻译：碳氢化合物蒸汽重整的催化剂和方法
公开(公告)号：US4233187A
公开(公告)日：1980-11-11
申请号：US24005
申请日：1979-03-26
申请人： Kenton Atwood , James H. Wright , Jay S. Merriam
发明人： Kenton Atwood , James H. Wright , Jay S. Merriam
IPC分类号： B01J23/74 , B01J23/755 , B01J23/83 , B01J35/02 , B01J35/04 , C01B3/40 , B01J21/04
CPC分类号： B01J35/026 , B01J23/74 , B01J23/755 , B01J23/83 , B01J35/04 , C01B3/40 , B01J35/006 , C01B2203/1052 , Y02P20/52
摘要： An improved catalyst and an improved process for use of the catalyst in the steam-hydrocarbon reforming reaction is disclosed. The catalyst comprises a group VIII metal on a cylindrical ceramic support consisting essentially of alpha alumina and having a plurality of gas passages extending axially therethrough. These supported catalysts display a higher geometric surface area and a lower pressure drop than do standard rings.
摘要翻译：公开了改进的催化剂和在蒸汽 - 烃重整反应中使用催化剂的改进方法。该催化剂包含基本上由α氧化铝组成的圆柱形陶瓷载体上的第VIII族金属，并且具有多个沿其轴向延伸的气体通道。这些支持的催化剂显示比标准环更高的几何表面积和更低的压降。

3. 发明授权

US07622623B2 Catalytically inactive heat generator and improved dehydrogenation process 有权
标题翻译：催化惰性热发生器和改进的脱氢工艺
公开(公告)号：US07622623B2
公开(公告)日：2009-11-24
申请号：US11218949
申请日：2005-09-02
申请人： Vladimir Fridman , Jay S. Merriam , Michael A. Urbancic
发明人： Vladimir Fridman , Jay S. Merriam , Michael A. Urbancic
IPC分类号： C07C2/76 , C07C2/78 , C07C5/08 , C07C11/00 , C07C5/09 , C07C5/327 , B01J23/00 , B01J20/00
CPC分类号： B01J23/32 , B01J23/26 , B01J23/72 , B01J35/0006 , C07C5/322 , C07C2521/02 , C07C2521/04 , C07C2521/08 , C07C2521/10 , C07C2521/12 , C07C2523/02 , C07C2523/04 , C07C2523/06 , C07C2523/26 , C07C2523/34 , C07C2523/72 , C07C2523/889 , C07C2529/04 , Y02P20/52 , Y02P20/584 , C07C11/06
摘要： An improved dehydrogenation catalyst bed system for olefin production utilizing classical processing techniques is disclosed. The catalyst bed system comprises a dehydrogenation catalyst comprising an active component selected from an oxide of a metal of Group 4 or Group 5 or Group 6 and combinations thereof and a support selected from aluminum oxide, aluminas, alumina monohydrate, alumina trihydrate, alumina-silica, transition aluminas, alpha-alumina, silica, silicate, aluminates, calcined hydrotalcites, zeolites and combinations thereof mixed with a first inert material selected from any material that is catalytically inactive when subjected to reaction conditions that can effect dehydrogenation of olefins and that has a high density and high heat capacity and that is not capable of producing heat during any stage of the dehydrogenation process, and the dehydrogenation catalyst plus the first inert material then being physically mixed with a secondary component comprising a heat-generating inert material and a carrier capable of supporting the heat-generating inert material, wherein the secondary component is catalytically inert with respect to dehydrogenation reactions or to cracking or to coking and generates heat after being exposed to reducing and/or to oxidizing reaction conditions.
摘要翻译：公开了一种利用经典处理技术改进用于烯烃生产的脱氢催化剂床系统。催化剂床系统包括脱氢催化剂，其包含选自第4组或第5组或第6组金属的氧化物及其组合的活性组分和选自氧化铝，氧化铝，一水合氧化铝，三水合氧化铝，氧化铝 - 二氧化硅，过渡氧化铝，α-氧化铝，二氧化硅，硅酸盐，铝酸盐，煅烧水滑石，沸石及其混合物与第一惰性材料混合，所述第一惰性材料选自任何可能影响烯烃脱氢反应条件的催化无活性物质，高密度和高热容量，并且在脱氢过程的任何阶段都不能产生热量，然后脱氢催化剂加第一惰性材料与包含发热惰性材料和载体的次级组分物理混合支撑发热惰性材料，其中次要组分相对于脱氢反应是催化惰性的，或者在暴露于还原和/或氧化反应条件之后开裂或焦化并产生热量。

4. 发明授权

US4452854A Catalyst and process for carbon monoxide conversion in sour gas 失效
标题翻译：酸性气体中一氧化碳转化的催化剂和工艺
公开(公告)号：US4452854A
公开(公告)日：1984-06-05
申请号：US459031
申请日：1983-01-18
申请人： Jay S. Merriam , Cecil B. Hogg
发明人： Jay S. Merriam , Cecil B. Hogg
IPC分类号： B01J23/78 , B01J23/84 , B01J23/85 , B01J23/88 , C01B3/16 , C01B31/20 , B01J23/34 , C01B3/12
CPC分类号： B01J23/8872 , B01J23/78 , B01J23/84 , B01J23/85 , B01J23/8871 , B01J23/8898 , B01J35/006 , B01J35/1009 , B01J35/1014 , B01J35/1019 , C01B3/16 , Y02P20/52
摘要： A process is disclosed for the conversion of carbon monoxide in sour synthesis gas mixtures in the presence of a catalyst which is active in the presence of sulfur compounds. The catalyst comprises known sulfactive metal oxides or sulfides supported on a shaped carrier. The catalytically active oxides or sulfides are doubly promoted with an alkali metal compound and an oxide or sulfide of manganese. The two promoters combined in proper ratio provide a synergistic effect on the activity of the catalyst which is enhanced beyond that of the singly promoted catalyst. The catalysts are active at relatively low temperatures of less than 500.degree. F., even in the presence of sulfur compounds. The equilibrium for the conversion of steam and carbon monoxide to hydrogen and CO.sub.2 is favored at lower temperatures.
摘要翻译：公开了在硫化合物存在下在催化剂存在下，在酸性合成气混合物中转化一氧化碳的方法。催化剂包括已知的支撑在成形载体上的磺化金属氧化物或硫化物。催化活性氧化物或硫化物用碱金属化合物和锰的氧化物或硫化物双重促进。合适比例的两种促进剂对催化剂的活性提供协同效应，其比单一促进的催化剂的活性增强。催化剂在低于500°F的相对低的温度下是有活性的，即使在硫化合物的存在下也是如此。蒸汽和一氧化碳转化为氢气和二氧化碳的平衡在较低的温度下是有利的。

5. 发明授权

US4876402A Improved aldehyde hydrogenation process 失效
标题翻译：改进醛加氢工艺
公开(公告)号：US4876402A
公开(公告)日：1989-10-24
申请号：US186431
申请日：1988-04-26
申请人： John E. Logsdon , Richard A. Loke , Jay S. Merriam , Richard W. Voight
发明人： John E. Logsdon , Richard A. Loke , Jay S. Merriam , Richard W. Voight
IPC分类号： B01J23/80 , B01J37/02 , B01J37/03 , C07C29/141
CPC分类号： C07C29/141 , B01J23/80 , B01J37/0201 , B01J37/03
摘要： An improved vapor phase catalytic hydrogenation of aldehydes to the corresponding alcohols wherein the improvement comprises employing a copper oxide-zinc oxide catalyst impregnated with a selectivity enhancer selected from the group consisting of an alkali-metal, transition metal and mixtures thereof.
摘要翻译：改进的气相催化氢化醛到相应的醇，其中改进包括使用浸渍有选自碱金属，过渡金属及其混合物的选择性增强剂的氧化铜 - 氧化锌催化剂。

6. 发明授权

US4762817A Aldehyde hydrogenation catalyst 失效
标题翻译：醛加氢催化剂
公开(公告)号：US4762817A
公开(公告)日：1988-08-09
申请号：US926129
申请日：1986-11-03
申请人： John E. Logsdon , Richard A. Loke , Jay S. Merriam , Richard W. Voight
发明人： John E. Logsdon , Richard A. Loke , Jay S. Merriam , Richard W. Voight
IPC分类号： B01J23/78 , B01J23/80 , B01J37/02 , B01J37/03 , C07B61/00 , C07C27/00 , C07C29/14 , C07C29/141 , C07C31/02 , C07C31/10 , C07C31/12 , C07C31/125 , C07C67/00 , B01J23/72
CPC分类号： B01J23/80 , C07C29/141 , B01J37/0201 , B01J37/03
摘要： An aldehyde hydrogenation catalyst consisting essentially of a mixture of copper and zinc oxide impregnated with a minor selectivity improving amount of a selectvity enhancer comprising the combination of an alkali metal selectivity enhancer selected from the group consisting of sodium, potassium, lithium, cesium, and mixtures thereof and a transition metal selectivity enhancer selected from the group consisting of nickel, cobalt, and mixtures thereof.

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