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1. 发明授权

US06825274B2 Melt processable, bleach resistant, durable fibers having high elastic recovery and low stress relaxation from polyurethane elastomers 有权
标题翻译：可熔融加工，耐漂白，耐久的纤维具有高弹性回复率和低聚氨酯弹性体的应力松弛
公开(公告)号：US06825274B2
公开(公告)日：2004-11-30
申请号：US10347910
申请日：2003-01-21
申请人： Lie Khong Djiauw , Michael A. Masse
发明人： Lie Khong Djiauw , Michael A. Masse
IPC分类号： C08G1832
CPC分类号： D01F6/70 , Y10T428/2913 , Y10T428/2967
摘要： The present invention provides melt processable, bleach resistant durable fibers having an elastic recovery above 50% after extension to 160% elongation and a stress relaxation below 50% after extension to 150% for 30 minuets which are formed from a soft polyurethane elastomer. This elastomer is comprised of (a) from 75 to 90% weight of a polydiene diol having up to about two terminal hydroxyl groups per molecule and a number average molecular weight between 500 and 20,000, (b) from 9 to 25% weight of a diisocyanate, and (c) from 0.8% to 5% weight of a chain extender which is a low molecular weight aliphatic diol, or a mixture of the low molecular weight aliphatic diol and from 0.1 to 4.0 mol % of a diamine wherein the hard segment content of the polyurethane elastomer is from about 10 to about 30% weight. The present invention further provides a polyurethane elastomer.
摘要翻译：本发明提供了可熔融加工的耐漂白耐久纤维，其在延伸至160％伸长率之后具有高于50％的弹性回复率，并且在由软聚氨酯弹性体形成的30分钟后延伸至150％后的应力松弛低于50％。该弹性体包含（a）75至90重量％的每分子具有至多约两个末端羟基的聚二烯二醇，数均分子量为500至20,000，（b）9至25重量％的二异氰酸酯和（c）0.8〜5重量％的作为低分子量脂肪族二醇的扩链剂，或低分子量脂肪族二醇和0.1〜4.0摩尔％的二胺的混合物，其中硬链段聚氨酯弹性体的含量为约10至约30重量％。本发明还提供一种聚氨酯弹性体。

2. 发明授权

US06537661B1 Melt processable, bleach resistant, durable fibers having high elastic recovery and low stress relaxation from polyurethane elastomers 有权
标题翻译：可熔融加工，耐漂白，耐久的纤维具有高弹性回复率和低聚氨酯弹性体的应力松弛
公开(公告)号：US06537661B1
公开(公告)日：2003-03-25
申请号：US10019626
申请日：2002-02-20
申请人： Lie Khong Djiauw , Michael A. Masse
发明人： Lie Khong Djiauw , Michael A. Masse
IPC分类号： D01F600
CPC分类号： D01F6/70 , Y10T428/2913 , Y10T428/2967
摘要： The present invention provides melt processable, bleach resistant durable fibers having an elastic recovery above 50% after extension to 160% elongation and a stress relaxation below 50% after extension to 150% for 30 minutes which are formed from a soft polyurethane elastomer. This elastomer is comprised of (a) from 75 to 90% weight of a polydiene diol having up to about two terminal hydroxyl groups per molecule and a number average molecular weight between 500 and 20,000, (b) from 9 to 25% weight of a diisocyanate, and (c) from 0.8 to 5% weight of a chain extender which is a low molecular weight aliphatic diol, or a mixture of the low molecular weight aliphatic diol and from 0.1 to 4.0 mol % of a diamine wherein the hard segment content of the polyurethane elastomer is from about 10 to about 30% weight. The present invention further provides a polyurethane elastomer.
摘要翻译：本发明提供了可熔融加工的耐漂白耐用纤维，其在延伸至160％伸长率之后具有高于50％的弹性回复率，并且由软质聚氨酯弹性体形成后延伸至150％30分钟后的应力松弛低于50％。该弹性体包含（a）75至90重量％的每分子具有至多约两个末端羟基的聚二烯二醇，数均分子量为500至20,000，（b）9至25重量％的二异氰酸酯和（c）0.8〜5重量％的低分子量脂肪族二醇的扩链剂，或低分子量脂肪族二醇和0.1〜4.0摩尔％的二胺的混合物，其中硬链段含量的聚氨酯弹性体的重量为约10至约30％。本发明还提供一种聚氨酯弹性体。

3. 发明授权

US5478885A Composition of epoxy resin, epoxidized block polydiene and curing agent 失效
标题翻译：环氧树脂，环氧化嵌段聚二烯和固化剂的组成
公开(公告)号：US5478885A
公开(公告)日：1995-12-26
申请号：US228324
申请日：1994-04-15
申请人： Michael A. Masse , Kailash Dangayach , James Erickson
发明人： Michael A. Masse , Kailash Dangayach , James Erickson
IPC分类号： C08C19/40 , C08G59/34 , C08G59/38 , C08L63/08 , C08L63/02
CPC分类号： C08G59/027 , C08C19/40 , C08G59/38 , C08L63/08
摘要： The present invention provides a toughened epoxy resin composition comprising:(a) a curable aromatic epoxy resin,(b) an epoxidized low viscosity polydiene polymer wherein the polymer contains from 1.0 to 7.0 milliequivalents of epoxy per gram of polymer, and(c) a curing agent.
摘要翻译：本发明提供一种增韧的环氧树脂组合物，其包含：（a）可固化的芳族环氧树脂，（b）环氧化的低粘度聚二烯烃聚合物，其中聚合物每克聚合物含有1.0-7.0毫当量的环氧树脂，和（c）固化剂。

4. 发明授权

US5356993A Coreactive conjugated diene polymer compositions which phase separate when cured 失效
标题翻译：固化时相分离的核心共轭二烯聚合物组合物
公开(公告)号：US5356993A
公开(公告)日：1994-10-18
申请号：US090855
申请日：1993-07-12
申请人： James R. Erickson , Michael A. Masse , Steven H. Dillman , Esther M. Zimmermann , Dale L. Handlin, Jr.
发明人： James R. Erickson , Michael A. Masse , Steven H. Dillman , Esther M. Zimmermann , Dale L. Handlin, Jr.
IPC分类号： C08L53/00 , C08L63/08 , C09D153/00 , C09J153/00 , C08F297/02
CPC分类号： C09D153/005 , C08L53/005 , C08L63/08 , C09J153/005
摘要： This invention provides a reactive conjugated diene polymer composition that forms a phase-separated adhesive, sealant, or coating. The composition comprises an epoxidized polymer of conjugated dienes, a second reactive component which is phase separated from the polymerized conjugated diene upon cure, and optionally a tackifying resin. The invention also encompasses adhesive, coating and sealant compositions made with the above composition.
摘要翻译：本发明提供形成相分离的粘合剂，密封剂或涂层的反应性共轭二烯聚合物组合物。该组合物包含共轭二烯的环氧化聚合物，在固化时与聚合的共轭二烯相分离的第二反应性组分，以及任选的增粘树脂。本发明还包括用上述组合物制备的粘合剂，涂料和密封剂组合物。

5. 发明授权

US5516824A Solvent-free laminating adhesive composition 失效
标题翻译：无溶剂层压粘合剂组合物
公开(公告)号：US5516824A
公开(公告)日：1996-05-14
申请号：US337714
申请日：1995-01-23
申请人： Michael A. Masse , Paul A. Mancinelli , James R. Erickson , Steven H. Dillman , Robert C. Bening , David R. Hansen
发明人： Michael A. Masse , Paul A. Mancinelli , James R. Erickson , Steven H. Dillman , Robert C. Bening , David R. Hansen
IPC分类号： B32B27/08 , C08G59/34 , C09J153/00 , C09J153/02 , C09J163/08 , C08K5/10 , C08L63/08
CPC分类号： C08G59/027 , B32B27/08 , C09J153/005 , C09J153/025 , C09J163/08 , Y10T428/31515
摘要： A laminating adhesive comprising an adhesive composition which comprises(a) An epoxidized block copolymer of the formula(A-B-A.sub.p).sub.n -Y.sub.r -(A.sub.q -B).sub.mwherein Y is a coupling agent or coupling monomers, andwherein A and B are polymer blocks which may be homopolymer blocks of conjugated diolefin monomers, copolymer blocks of conjugated diolefin monomers or copolymer blocks of conjugated diolefin monomers and monoalkenyl aromatic hydrocarbon monomers, andwherein the A blocks have a higher number of aliphatic double bonds between a tertiary carbon atom and either a primary, secondary, or tertiary carbon atom per unit of block mass than do the B blocks, andwherein the A blocks have a molecular weight from about 100 to about 3000 and the B blocks have a molecular weight from about 1000 to about 15,000, and wherein p and q are 0 or 1 and n>0, r is 0 or 1, m.gtoreq.0 and n+m ranges from 1 to 100; and(b) at least a significant amount of a tackifying resin compatible with the polymer of (a) up to 400 phr.The invention also relates to a laminate containing the adhesive.
摘要翻译：一种层压粘合剂，其包含粘合剂组合物，其包含（a）式（AB-Ap）n-Yr-（Aq-B）m的环氧化嵌段共聚物，其中Y为偶联剂或偶联单体，并且其中A和B为聚合物嵌段，其可以是共轭二烯烃单体的均聚物嵌段，共轭二烯单体的共聚物嵌段或共轭二烯烃单体的共聚物嵌段和单链烯基芳烃单体，并且其中所述A嵌段在叔碳原子和叔碳原子之间具有更高数量的脂族双键与B嵌段相比，每单位嵌段质量的伯，仲或叔碳原子，其中A嵌段的分子量为约100至约3000，B嵌段的分子量为约1000至约15,000 并且其中p和q为0或1且n> 0，r为0或1，m≥0和n + m的范围为1至100; 和（b）至少大量的与（a）多至400phr的聚合物相容的增粘树脂。本发明还涉及含有粘合剂的层压体。

6. 依法登记的发明

USH1517H Radiation curable printing ink composition 失效
标题翻译：可辐射固化印刷油墨组合物
公开(公告)号：USH1517H
公开(公告)日：1996-02-06
申请号：US91481
申请日：1993-07-12
申请人： James R. Erickson , Michael A. Masse , Steven H. Dillman , Esther M. Zimmermann
发明人： James R. Erickson , Michael A. Masse , Steven H. Dillman , Esther M. Zimmermann
IPC分类号： C09D11/10 , C08L61/02
CPC分类号： C09D11/101
摘要： The invention is a radiation curable printing ink composition comprising a liquid viscous epoxidized diene polymer and a pigment. Preferred diene polymers are block copolymers comprising at least interior and exterior diene blocks wherein the exterior diene blocks contain a greater concentration of di-, tri-, and tetrasubstituted olefinic epoxides than the interior blocks and wherein the copolymer contains from 0.1 to 3.0 Meq of olefinic epoxides per gram of copolymer and the peak molecular weights as determined by gel permeation chromatography of the exterior blocks of from 300 to 2000 and the peak molecular weights as determined by gel permeation chromatography of the interior blocks are from 2,000 to 10,000. In another preferred embodiment, the polymer is a star polymer having a random distribution of from 0.5 to 5 Meq of di-, tri-, and tetrasubstituted olefinic epoxides per gram of polymer and greater than four arms wherein the peak molecular weights as determined by gel permeation chromatography of the arms are from 1500 to 15,000.
摘要翻译：本发明是一种包含液体粘性环氧化二烯聚合物和颜料的可辐射固化印刷油墨组合物。优选的二烯聚合物是包含至少内部和外部二烯嵌段的嵌段共聚物，其中外部二烯嵌段含有比内部嵌段更大浓度的二，三和四取代烯属环氧化物，并且其中共聚物含有0.1至3.0Meq的烯属环氧化物/克共聚物和通过外部块的凝胶渗透色谱法测定的峰分子量为300至2000，并且通过内部块的凝胶渗透色谱测定的峰分子量为2,000至10,000。在另一个优选的实施方案中，聚合物是每克聚合物和大于四个臂的随机分布为0.5-5Meq的二，三和四取代的烯烃环氧化物的星形聚合物，其中由凝胶测定的峰分子量臂的渗透色谱法为1500至15,000。

7. 发明授权

US5446093A Method for producing statistically coupled asymmetric radial polymers 失效
标题翻译：统计耦合的不对称径向聚合物的制备方法
公开(公告)号：US5446093A
公开(公告)日：1995-08-29
申请号：US150929
申请日：1993-11-10
申请人： Ronald J. Hoxmeier , Bridget A. Spence , Steven S. Chin , Michael A. Masse
发明人： Ronald J. Hoxmeier , Bridget A. Spence , Steven S. Chin , Michael A. Masse
IPC分类号： C08G81/02 , C08L53/02 , C08F297/04
CPC分类号： C08G81/022
摘要： A process is disclosed for producing six-armed and eight-armed asymmetric radial block copolymers. The process comprises anionically polymerizing a diene and/or a vinyl aromatic hydrocarbon to create living polydiene and/or vinyl aromatic hydrocarbon arms, sequentially anionically polymerizing a vinyl aromatic hydrocarbon and a diene to create living block copolymer arms and coupling the two sets of arms together in one step with a coupling agent that will couple six or eight arms, wherein the molar ratio of the vinyl aromatic hydrocarbon-diene arms to the polydiene arms is sufficient to produce a statistical blend with less than 5 weight percent homopolydiene.
摘要翻译：公开了一种用于生产六臂和八臂不对称径向嵌段共聚物的方法。该方法包括阴离子聚合二烯和/或乙烯基芳烃以产生活性聚二烯和/或乙烯基芳族烃臂，依次阴离子聚合乙烯基芳族烃和二烯以产生活性嵌段共聚物臂并将两组臂结合在一起在一步中与偶联剂可以连接6或8个臂，其中乙烯基芳族烃 - 二烯臂与聚二烯臂的摩尔比足以产生具有小于5重量％均聚二烯的统计学共混物。

8. 发明授权

US5360875A Method for producing coupled asymmetric polymers 失效
标题翻译：偶联不对称聚合物的制备方法
公开(公告)号：US5360875A
公开(公告)日：1994-11-01
申请号：US120116
申请日：1993-09-10
申请人： Michael A. Masse , Steven S. Chin , Craig A. Stevens
发明人： Michael A. Masse , Steven S. Chin , Craig A. Stevens
IPC分类号： C08F8/42 , C08F297/02 , C08F297/04
CPC分类号： C08F297/044 , C08F297/046
摘要： A process for preparing a coupled asymmetric block copolymer of a vinyl aromatic hydrocarbon and a conjugated diene which comprises:(a) adding sufficient anionic polymerization initiator to the vinyl aromatic hydrocarbon monomer to start polymerization of the vinyl aromatic hydrocarbon,(b) polymerizing the vinyl aromatic hydrocarbon for a time sufficient to form a first set of vinyl aromatic hydrocarbon blocks having a desired molecular weight,(c) adding sufficient anionic polymerization initiator to start polymerization of a second set of vinyl aromatic hydrocarbon blocks,(d) completing the polymerization of the vinyl aromatic hydrocarbon for a time such that the first set of vinyl aromatic hydrocarbon blocks continues to grow to the desired molecular weight and the second set of vinyl aromatic hydrocarbon blocks grows to a desired smaller molecular weight,(e) adding a conjugated diene and polymerizing it on the ends of the vinyl aromatic hydrocarbon blocks for a time sufficient to form vinyl aromatic hydrocarbon-conjugated diene arms of the desired molecular weight, and(f) adding a coupling agent and coupling the arms to form the asymmetric block copolymer.
摘要翻译：一种制备乙烯基芳族烃和共轭二烯的偶联不对称嵌段共聚物的方法，其包括：（a）向乙烯基芳族烃单体加入足够的阴离子聚合引发剂以开始乙烯基芳烃的聚合，（b）芳烃在足以形成具有所需分子量的第一组乙烯基芳族烃嵌段的时间内，（c）加入足够的阴离子聚合引发剂以开始聚合第二组乙烯基芳族烃嵌段，（d）完成聚合反应乙烯基芳族烃一段时间，使得第一组乙烯基芳族烃嵌段继续生长至所需分子量，第二组乙烯基芳族烃嵌段生长至所需的较小分子量，（e）加入共轭二烯和在乙烯基芳族烃嵌段的末端聚合足够长的时间以形成所需分子量的乙烯基芳族烃 - 共轭二烯臂，和（f）加入偶联剂并偶联臂以形成不对称嵌段共聚物。

9. 发明授权

US5322895A Radiation cured adhesive composition 失效
标题翻译：辐射固化胶粘剂组成
公开(公告)号：US5322895A
公开(公告)日：1994-06-21
申请号：US84684
申请日：1993-06-29
申请人： Michael A. Masse , James R. Erickson
发明人： Michael A. Masse , James R. Erickson
IPC分类号： C09J153/02 , C08L53/02 , C08F297/04
CPC分类号： C09J153/02
摘要： The present invention is a cured adhesive composition with enhanced properties prepared by the high energy ionizing radiation initiated curing of a polymer composition. The polymer composition comprises from 1/3 to 2/3% by weight of the polymer composition of a block copolymer having the structure(D--A--B).sub.x --Y--C.sub.zwhere A is a polymer block of a vinyl aromatic hydrocarbon, B, C and D are polymer blocks of a conjugated diene, Y is a coupling agent or coupling monomers or initiator, x ranges from 3 to 30, z ranges from 0 to 10, the molecular weight of the A blocks ranges from 5,000 to 25,000, the molecular weights of the B and C blocks range from 15,000 to 100,000 and the molecular weight of the D blocks ranges from 500 to 5,000 in one embodiment and above 5000 to 50,000 in the other; and a tackifying resin.
摘要翻译：本发明是通过聚合物组合物的高能电离辐射引发固化制备的具有增强性能的固化的粘合剂组合物。聚合物组合物占聚合物组合物的1/3〜2/3重量％，具有结构（DAB）xY-Cz的嵌段共聚物，其中A为乙烯基芳烃的聚合物嵌段，B，C和D为共轭二烯的聚合物嵌段，Y是偶联剂或偶联单体或引发剂，x为3至30，z为0至10，A嵌段的分子量为5,000至25,000，分子量为 B和C嵌段的范围为15,000至100,000，D嵌段的分子量在一个实施方案中为500至5,000，另一个为5000至50,000; 和增粘树脂。

10. 发明授权

US5246987A Bitumen and halogenated vinyl aromatic-conjugated diolefin block copolymer compositions 失效
标题翻译：沥青和卤代乙烯基芳族共轭二烯嵌段共聚物组合物
公开(公告)号：US5246987A
公开(公告)日：1993-09-21
申请号：US882725
申请日：1992-05-14
申请人： Michael A. Masse , James H. Collins , Daniel B. England
发明人： Michael A. Masse , James H. Collins , Daniel B. England
IPC分类号： C08L95/00
CPC分类号： C08L95/00
摘要： A bitumen composition is provided which contains a block copolymer of one or more halogenated vinyl aromatic blocks and one or more conjugated diolefin blocks. The composition does not phase separate upon storage for five days at 160.degree. C. and has excellent ductility and elasticity. The utilization of halogenated block copolymers also results in improved high service temperature viscosity and moduli with excellent resistance to thermal cracking at low service temperatures. The block copolymer is preferably a hydrogenated block copolymer. The bitumen is preferably halogenated.
摘要翻译：提供了一种含有一种或多种卤代乙烯基芳族嵌段与一种或多种共轭二烯烃嵌段的嵌段共聚物的沥青组合物。该组合物在160℃储存5天并不相分离，具有优良的延展性和弹性。卤化嵌段共聚物的利用也导致改进的高使用温度粘度和模量，在低使用温度下具有优异的耐热裂纹性。嵌段共聚物优选为氢化嵌段共聚物。沥青优选为卤化。

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