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1. 发明授权

US08134018B2 Process for the epoxidation of an olefin with improved energy balance 有权
标题翻译：具有改善的能量平衡的烯烃的环氧化方法
公开(公告)号：US08134018B2
公开(公告)日：2012-03-13
申请号：US11814110
申请日：2006-01-09
申请人： Hans-Georg Goebbel , Henning Schultz , Peter Schultz , Renate Patrascu , Malte Schulz , Meinolf Weidenbach
发明人： Hans-Georg Goebbel , Henning Schultz , Peter Schultz , Renate Patrascu , Malte Schulz , Meinolf Weidenbach
IPC分类号： C07D301/12
CPC分类号： C07D301/12 , Y02P20/582
摘要： The invention relates to a process for the epoxidation of an olefin comprising (a) reacting the olefin with hydrogen peroxide in the presence of methanol as solvent in at least two reaction stages to obtain a mixture (M-a) comprising olefin oxide, unreacted olefin, methanol and water, wherein between at least two reaction stages, olefin oxide is separated by distillation; (b) separating unreacted olefin from the mixture (M-a) by distillation to obtain a mixture (M-bi) comprising at least 80 wt.-% of olefin and a mixture (M-bii) comprising methanol, water and at least 7 wt.-% of olefin oxide; (c) separating olefin oxide from the mixture (M-bii) in at least one distillation stage to obtain a mixture (M-ci) comprising at least 99 wt.-% of olefin oxide and a mixture (M-cii) comprising water and at least 55 wt.-% of methanol; (d) separating methanol from the mixture (M-cii) in at least one distillation stage to obtain a mixture (M-di) comprising at least 85 wt.-% of methanol and up to 10 wt.-% of water, and a mixture (M-dii) comprising at least 90 wt.-% of water; wherein a vapor top stream (Td) obtained from at least one distillation column used in (d), said vapor top stream (Td) comprising at least 85 wt.-% methanol, is used to operate at least partially at least one vaporizer used in at least one distillation column used in at least one of stages (a), (b) and (c).
摘要翻译：本发明涉及烯烃的环氧化方法，其包括（a）在至少两个反应阶段中在甲醇作为溶剂的存在下使烯烃与过氧化氢反应，以获得包含烯烃氧化物，未反应的烯烃，甲醇的混合物（Ma）和水，其中在至少两个反应阶段之间，通过蒸馏分离烯烃氧化物; （b）通过蒸馏从混合物（Ma）中分离未反应的烯烃，得到包含至少80重量％的烯烃和包含甲醇，水和至少7重量％的烯烃的混合物（M-bii）的混合物（M-bi） .-％的烯烃氧化物; （c）在至少一个蒸馏阶段从所述混合物（M-bii）分离烯烃氧化物以获得包含至少99重量％的烯烃氧化物的混合物（M-ci）和包含水的混合物（M-cii）和至少55重量％的甲醇; （d）在至少一个蒸馏阶段中从混合物（M-cii）中分离甲醇以获得包含至少85重量％的甲醇和至多10重量％的水的混合物（M-di），以及包含至少90重量％的水的混合物（M-dii）其中从（d）中使用的至少一个蒸馏塔获得的蒸汽顶部流（Td），所述蒸气顶部流（Td）包含至少85重量％的甲醇，用于至少部分地使用至少一个使用的蒸发器在（a），（b）和（c）中的至少一个中使用的至少一个蒸馏塔中。

2. 发明授权

US07973183B2 Process for the preparation of an olefin oxide 有权
标题翻译：制备烯烃氧化物的方法
公开(公告)号：US07973183B2
公开(公告)日：2011-07-05
申请号：US12599395
申请日：2008-04-24
申请人： Hans-Georg Goebbel , Peter Bassler , Joaquim Henrique Teles , Peter Rudolf , Ulrich Mueller , Anna Forlin , Malte Schulz , Meinolf Weidenbach
发明人： Hans-Georg Goebbel , Peter Bassler , Joaquim Henrique Teles , Peter Rudolf , Ulrich Mueller , Anna Forlin , Malte Schulz , Meinolf Weidenbach
IPC分类号： C07D301/12
CPC分类号： C07D301/12 , Y02P20/584
摘要： The present invention relates to a continuous process for the preparation of an olefin oxide wherein an olefin is reacted with a hydroperoxidein the presence of a catalyst, and wherein the reaction which is carried out in at least three reactors operated in parallel is controlled by specifically adjusting the catalyst loads in the reactors.
摘要翻译：本发明涉及一种用于制备烯烃氧化物的连续方法，其中烯烃在催化剂存在下与氢过氧化物反应，并且其中在至少三个并联操作的反应器中进行的反应通过特别调节来控制反应器中的催化剂负载。

3. 发明授权

US08927745B2 Process for producing propylene oxide 有权
标题翻译：生产环氧丙烷的方法
公开(公告)号：US08927745B2
公开(公告)日：2015-01-06
申请号：US13319803
申请日：2010-05-05
申请人： Philip Kampe , Peter Resch , Soo Yin Chin , Peter Bassler , Ulrich Mueller , Goetz-Peter Schindler , Hans-Georg Goebbel , Joaquim Henrique Teles , Kai Gumlich , Thomas Grassler , Christian Bartosch , Richard Jacubinas , Meinolf Weidenbach
发明人： Philip Kampe , Peter Resch , Soo Yin Chin , Peter Bassler , Ulrich Mueller , Goetz-Peter Schindler , Hans-Georg Goebbel , Joaquim Henrique Teles , Kai Gumlich , Thomas Grassler , Christian Bartosch , Richard Jacubinas , Meinolf Weidenbach
IPC分类号： C07D301/12
CPC分类号： C07D301/12 , Y02P20/52
摘要： A process for producing propylene oxide comprising reacting propene with hydrogen peroxide in the presence of a catalyst to give a mixture (G1) comprising propylene oxide, unreacted propene, and oxygen; separating propylene oxide from mixture (G1) to give a mixture (GII) comprising propene and oxygen; and adding hydrogen to mixture (GII) and reducing the oxygen comprised in mixture (GII) at least partially by reaction with hydrogen in the presence of a catalyst comprising copper in elemental and/or oxidic form on a support, wherein copper is present on the support in an amount of 30 to 80 wt.-% based on the whole catalyst and calculated as CuO.
摘要翻译：一种生产环氧丙烷的方法，包括在催化剂存在下使丙烯与过氧化氢反应得到包含环氧丙烷，未反应的丙烯和氧的混合物（G1）从混合物（G1）中分离环氧丙烷以得到包含丙烯和氧的混合物（GII）; 并且在载体上含有元素和/或氧化形式的铜的催化剂的存在下，至少部分地通过与氢反应，将氢混合物（GII）加入到混合物（GII）中并且还原含氧物质，其中铜存在于以全部催化剂为基准，其用量为30-80重量％，以CuO计算。

4. 发明授权

US07692031B2 Separation of propylene oxide from a mixture comprising propylene oxide and methanol 有权
标题翻译：从包含环氧丙烷和甲醇的混合物中分离环氧丙烷
公开(公告)号：US07692031B2
公开(公告)日：2010-04-06
申请号：US11631843
申请日：2005-07-06
申请人： Hans-Georg Goebbel , Henning Schultz , Peter Schultz , Renate Patrascu , Malte Schulz , Meinolf Weidenbach
发明人： Hans-Georg Goebbel , Henning Schultz , Peter Schultz , Renate Patrascu , Malte Schulz , Meinolf Weidenbach
IPC分类号： C07D301/32
CPC分类号： C07D301/32 , C07D301/12
摘要： A method of separating propylene oxide from a mixture (M) comprising propylene oxide and methanol, said method comprising: (i) introducing said mixture (M) into an extractive distillation column; (ii) additionally introducing an extracting solvent into said extractive distillation column; (iii) distilling propylene oxide overhead from said extractive distillation column as top stream; (iv) withdrawing a bottoms stream from said extractive distillation column; (v) compressing the top stream obtained overhead in (iii) by means of at least one compressor to give a compressed vapor.
摘要翻译：一种从包含环氧丙烷和甲醇的混合物（M）中分离环氧丙烷的方法，所述方法包括：（i）将所述混合物（M）引入萃取蒸馏塔; （ii）另外将萃取溶剂引入所述萃取蒸馏塔中; （iii）从所述萃取蒸馏塔顶部馏出环氧丙烷作为顶部流; （iv）从所述萃取蒸馏塔中取出塔底物流; （v）通过至少一个压缩机压缩在（iii）中获得的塔顶馏出物的顶部流以产生压缩蒸汽。

5. 发明申请

US20070238888A1 Separation of Propylene Oxide from a Mixture Comprising Propylene Oxide and Methanol 审中-公开
标题翻译：从包含环氧丙烷和甲醇的混合物中分离出环氧丙烷
公开(公告)号：US20070238888A1
公开(公告)日：2007-10-11
申请号：US11631630
申请日：2005-07-06
申请人： Hans-Georg Goebbel , Henning Schultz , Peter Schultz , Renate Patrascu , Malte Schulz , Meinolf Weidenbach
发明人： Hans-Georg Goebbel , Henning Schultz , Peter Schultz , Renate Patrascu , Malte Schulz , Meinolf Weidenbach
IPC分类号： C07D301/32
CPC分类号： C07D301/32
摘要： A method of separating propylene oxide from a mixture (M) comprising 5 to 50 percent by weight propylene oxide and 50 to 85 percent by weight methanol, said method comprising (i) introducing said mixture (M) into an extractive distillation column; (ii) additionally introducing a polar solvent into said extractive distillation column; (iii) distilling propylene oxide overhead from said extractive distillation column at a bottoms temperature of from 40 to 70° C. and at a pressure of from 300 to 750 mbar.
摘要翻译：从包含5至50重量％的环氧丙烷和50至85重量％的甲醇的混合物（M）中分离环氧丙烷的方法，所述方法包括（i）将所述混合物（M）引入萃取蒸馏塔中; （ii）另外将极性溶剂引入所述萃取蒸馏塔中; （iii）在40至70℃的底部温度和300至750毫巴的压力下，从所述萃取蒸馏塔中蒸馏环氧丙烷塔顶馏出物。

6. 发明授权

US07223876B2 Method of separating an olefin from a gas stream 有权
标题翻译：从气流中分离烯烃的方法
公开(公告)号：US07223876B2
公开(公告)日：2007-05-29
申请号：US10828291
申请日：2004-04-21
申请人： Hans-Georg Göbbel , Henning Schultz , Peter Schultz , Renate Patrascu , Malte Schulz , Meinolf Weidenbach
发明人： Hans-Georg Göbbel , Henning Schultz , Peter Schultz , Renate Patrascu , Malte Schulz , Meinolf Weidenbach
IPC分类号： C07D301/12
CPC分类号： B01D53/1487 , Y02P20/582
摘要： The present invention relates to a method of separating an olefin from a gas stream, said gas stream comprising the olefin and at least one other component, said method comprising (i) compressing and cooling the gas stream; (ii) separating the olefin from the gas stream by absorbing the olefin in an absorbent; (iii) separating the olefin from the absorbent by desorption; wherein compressing or cooling or compressing and cooling in (i) is carried out at least twice.
摘要翻译：本发明涉及从气流中分离烯烃的方法，所述气流包含烯烃和至少一种其它组分，所述方法包括（i）压缩和冷却气流; （ii）通过吸收吸收剂中的烯烃从气流中分离烯烃; （iii）通过解吸从分离吸收剂中分离烯烃; 其中在（i）中压缩或冷却或压缩和冷却至少进行两次。

7. 发明授权

US08609879B2 Method for the separation of acetonitrile from water 有权
标题翻译：从水中分离乙腈的方法
公开(公告)号：US08609879B2
公开(公告)日：2013-12-17
申请号：US12837962
申请日：2010-07-16
申请人： Joaquim Henrique Teles , Hans-Georg Göbbel , Peter Baβler , Philip Kampe , Kai Gumlich , Christian Bartosch , Ulrich Müller , Richard Jacubinas , Natalia Trukhan , Meinolf Weidenbach , Martin Cogswell
发明人： Joaquim Henrique Teles , Hans-Georg Göbbel , Peter Baβler , Philip Kampe , Kai Gumlich , Christian Bartosch , Ulrich Müller , Richard Jacubinas , Natalia Trukhan , Meinolf Weidenbach , Martin Cogswell
IPC分类号： C07C255/00
CPC分类号： C07D301/12 , B01D17/0208 , B01D17/047 , Y02P20/582
摘要： A method for separating acetonitrile from water, comprising (i) providing a stream S1 containing at least 95 wt.-%, based on the total weight of S1, acetonitrile and water, wherein the weight ratio of acetonitrile: water is greater than 1; (ii) adding a stream P, comprising at least 95 wt.-% C3, based on the total weight of stream P, to S1 to obtain a mixed stream S2, C3 being propene optionally admixed with propane with a minimum weight ratio of propene: propane of 7:3; (iii) subjecting S2 to a temperature of 92° C. at most and a pressure of at least 10 bar, obtaining a first liquid phase L1 essentially consisting of C3, acetonitrile, and water, and a second liquid phase L2 essentially consisting of water and acetonitrile wherein the weight ratio of acetonitrile: water in L2 is less than 1; (iv) separating L1 from L2.
摘要翻译：一种从水中分离乙腈的方法，包括（i）提供基于S1的总重量，乙腈和水的至少95重量％的流S1，其中乙腈：水的重量比大于1; （ii）将基于流P的总重量的至少95重量％C 3的流P加入到S1中，以获得混合物流S2，将任选地与丙烷混合的丙烯以最小重量比的丙烯：丙烷7：3; （iii）使S2达到最多92℃的温度和至少10巴的压力，得到基本上由C3，乙腈和水组成的第一液相L1和基本上由水组成的第二液相L2 乙腈，其中乙腈：水的重量比小于1; （iv）将L1与L2分离。

8. 发明申请

US20120065413A1 PROCESS FOR PRODUCING PROPYLENE OXIDE 有权
标题翻译：生产丙烯氧化物的方法
公开(公告)号：US20120065413A1
公开(公告)日：2012-03-15
申请号：US13319803
申请日：2010-05-05
申请人： Philip Kampe , Peter Resch , Soo Yin Chin , Peter Bassler , Ulrich Mueller , Goetz-Peter Schindler , Hans-Georg Goebbel , Joaquim Henrique Teles , Kai Gumlich , Thomas Grassler , Christian Bartosch , Richard Jacubinas , Meinolf Weidenbach
发明人： Philip Kampe , Peter Resch , Soo Yin Chin , Peter Bassler , Ulrich Mueller , Goetz-Peter Schindler , Hans-Georg Goebbel , Joaquim Henrique Teles , Kai Gumlich , Thomas Grassler , Christian Bartosch , Richard Jacubinas , Meinolf Weidenbach
IPC分类号： C07D301/12
CPC分类号： C07D301/12 , Y02P20/52
摘要： A process for producing propylene oxide comprising reacting propene with hydrogen peroxide in the presence of a catalyst to give a mixture (G1) comprising propylene oxide, unreacted propene, and oxygen; separating propylene oxide from mixture (G1) to give a mixture (GII) comprising propene and oxygen; and adding hydrogen to mixture (GII) and reducing the oxygen comprised in mixture (GII) at least partially by reaction with hydrogen in the presence of a catalyst comprising copper in elemental and/or oxidic form on a support, wherein copper is present on the support in an amount of 30 to 80 wt.-% based on the whole catalyst and calculated as CuO.
摘要翻译：一种生产环氧丙烷的方法，包括在催化剂存在下使丙烯与过氧化氢反应得到包含环氧丙烷，未反应的丙烯和氧的混合物（G1）从混合物（G1）中分离环氧丙烷以得到包含丙烯和氧的混合物（GII）; 并且在载体上含有元素和/或氧化形式的铜的催化剂的存在下，至少部分地通过与氢反应，将氢混合物（GII）加入到混合物（GII）中并且还原含氧物质，其中铜存在于以全部催化剂为基准，其用量为30-80重量％，以CuO计算。

9. 发明申请

US20100081834A1 PROCESS FOR THE EPOXIDATION OF AN OLEFIN WITH IMPROVED ENERGY BALANCE 有权
标题翻译：具有改善能量平衡的烯烃的环氧化方法
公开(公告)号：US20100081834A1
公开(公告)日：2010-04-01
申请号：US11814110
申请日：2006-01-09
申请人： Hans-Georg Goebbel , Henning Schultz , Peter Schultz , Renate Patrascu , Malte Schulz , Meinolf Weidenbach
发明人： Hans-Georg Goebbel , Henning Schultz , Peter Schultz , Renate Patrascu , Malte Schulz , Meinolf Weidenbach
IPC分类号： C07D301/12
CPC分类号： C07D301/12 , Y02P20/582
摘要： The invention relates to a process for the epoxidation of an olefin comprising (a) reacting the olefin with hydrogen peroxide in the presence of methanol as solvent in at least two reaction stages to obtain a mixture (M-a) comprising olefin oxide, unreacted olefin, methanol and water, wherein between at least two reaction stages, olefin oxide is separated by distillation; (b) separating unreacted olefin from the mixture (M-a) by distillation to obtain a mixture (M-bi) comprising at least 80 wt.-% of olefin and a mixture (M-bii) comprising methanol, water and at least 7 wt.-% of olefin oxide; (c) separating olefin oxide from the mixture (M-bii) in at least one distillation stage to obtain a mixture (M-ci) comprising at least 99 wt.-% of olefin oxide and a mixture (M-cii) comprising water and at least 55 wt.-% of methanol; (d) separating methanol from the mixture (M-cii) in at least one distillation stage to obtain a mixture (M-di) comprising at least 85 wt.-% of methanol and up to 10 wt.-% of water, and a mixture (M-dii) comprising at least 90 wt.-% of water; wherein a vapor top stream (Td) obtained from at least one distillation column used in (d), said vapor top stream (Td) comprising at least 85 wt.-% methanol, is used to operate at least partially at least one vaporizer used in at least one distillation column used in at least one of stages (a), (b) and (c).
摘要翻译：本发明涉及烯烃的环氧化方法，其包括（a）在至少两个反应阶段中在甲醇作为溶剂的存在下使烯烃与过氧化氢反应，以获得包含烯烃氧化物，未反应的烯烃，甲醇的混合物（Ma）和水，其中在至少两个反应阶段之间，通过蒸馏分离烯烃氧化物; （b）通过蒸馏从混合物（Ma）中分离未反应的烯烃，得到包含至少80重量％的烯烃和包含甲醇，水和至少7重量％的烯烃的混合物（M-bii）的混合物（M-bi） .-％的烯烃氧化物; （c）在至少一个蒸馏阶段从所述混合物（M-bii）分离烯烃氧化物以获得包含至少99重量％的烯烃氧化物的混合物（M-ci）和包含水的混合物（M-cii）和至少55重量％的甲醇; （d）在至少一个蒸馏阶段中从混合物（M-cii）中分离甲醇以获得包含至少85重量％的甲醇和至多10重量％的水的混合物（M-di），以及包含至少90重量％的水的混合物（M-dii）其中从（d）中使用的至少一个蒸馏塔获得的蒸汽顶部流（Td），所述蒸气顶部流（Td）包含至少85重量％的甲醇，用于至少部分地使用至少一个使用的蒸发器在（a），（b）和（c）中的至少一个中使用的至少一个蒸馏塔中。

10. 发明申请

US20080306290A1 Process for Epoxidizing Propene 有权
标题翻译：丙烯环氧化工艺
公开(公告)号：US20080306290A1
公开(公告)日：2008-12-11
申请号：US12159404
申请日：2006-12-18
申请人： Hans-Georg Gobbel , Peter Bassler , Joaquim Henrique Teles , Peter Rudolf , Ulrich Muller , Anna Forlin , Malte Schulz , Meinolf Weidenbach
发明人： Hans-Georg Gobbel , Peter Bassler , Joaquim Henrique Teles , Peter Rudolf , Ulrich Muller , Anna Forlin , Malte Schulz , Meinolf Weidenbach
IPC分类号： C07D301/12
CPC分类号： C07D301/12
摘要： The present invention provides a process for the epoxidation of propene which comprises reacting propene with hydrogen peroxide in the presence of methanol as solvent and a titanium zeolite catalyst, the process further comprising separating propylene oxide from the reaction mixture to obtain a mixture comprising methanol, water, at least one carboxylic acid and at least one carbonyl compound, wherein the at least one carboxylic acid is at least partially neutralized, said process optionally comprising a hydrogenation stage.
摘要翻译：本发明提供丙烯环氧化方法，其包括在甲醇作为溶剂和钛沸石催化剂的存在下使丙烯与过氧化氢反应，该方法还包括从反应混合物中分离环氧丙烷以获得包含甲醇，水，至少一种羧酸和至少一种羰基化合物，其中所述至少一种羧酸被至少部分中和，所述方法任选地包含氢化阶段。

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