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1. 发明授权

US07262265B1 High temperature thermoset compositions 失效
标题翻译：高温热固性组合物
公开(公告)号：US07262265B1
公开(公告)日：2007-08-28
申请号：US10779207
申请日：2004-02-13
申请人： Farshad J. Motamedi , Matthew L. Marrocco, III
发明人： Farshad J. Motamedi , Matthew L. Marrocco, III
IPC分类号： C08G75/20 , C08G79/02
CPC分类号： C08G65/4006 , C08G75/20
摘要： A new family of high temperature thermoset resins having high glass transition temperatures and enhanced hygrothermal stability that are synthesized using inexpensive starting materials in essentially a single step process. A trifunctional aromatic, wherein at least one of the three functional groups comprises a halogen and the balance thereof comprises OH groups and wherein said aromatic has electron withdrawing properties, is polymerized using an excess of a diol.
摘要翻译：一系列高温热固性树脂，具有高玻璃化转变温度和增强的湿热稳定性，它们使用廉价的起始原料在基本上单一步骤中合成。三官能芳族化合物，其中三个官能团中的至少一个包含卤素，余量包含OH基团，并且其中所述芳族化合物具有吸电子性质，使用过量的二醇聚合。

2. 发明授权

US5539048A Macromonomers having reactive side groups 失效
公开(公告)号：US5539048A
公开(公告)日：1996-07-23
申请号：US458501
申请日：1995-06-02
申请人： Robert R. Gagn e , Matthew L. Marrocco, III , Mark S. Trimmer , Neil H. Hendricks
发明人： Robert R. Gagn e , Matthew L. Marrocco, III , Mark S. Trimmer , Neil H. Hendricks
IPC分类号： C08F299/02 , C07C45/46 , C07C45/68 , C07C49/798 , C07C49/83 , C07C59/84 , C07C69/017 , C07C69/76 , C07C225/22 , C07C251/24 , C08F290/00 , C08F290/12 , C08F290/14 , C08G59/42 , C08G61/00 , C08G61/10 , C08G61/12 , C08G69/16 , C08G69/26 , C08G85/00 , C08L63/00 , C08L101/00 , C08G6/00
CPC分类号： C08L63/00 , C07C225/22 , C07C251/24 , C07C45/46 , C07C45/68 , C07C49/798 , C07C49/83 , C07C59/84 , C07C69/017 , C07C69/76 , C08F290/124 , C08F290/14 , C08G59/4223 , C08G61/00 , C08G61/10 , C08G69/16 , C08G69/26 , C08G85/00 , C08L101/00 , C08G2261/312
摘要： Rigid-rod macromonomers, and methods for preparing such macromonomers, having a polyaromatic backbone, solubilizing side groups, and reactive side groups are provided. The macromonomers are chemically incorporated into polymer systems to provide stronger, stiffened polymers.

3. 发明授权

US4945257A Electrically settable resistance device 失效
标题翻译：电可设置电阻装置
公开(公告)号：US4945257A
公开(公告)日：1990-07-31
申请号：US274442
申请日：1988-11-18
申请人： Matthew L. Marrocco, III
发明人： Matthew L. Marrocco, III
IPC分类号： G11C13/02 , H01C10/02 , H01G9/22
CPC分类号： G11C13/0009 , B82Y10/00 , H01C10/025 , H01G11/02 , H01G11/08 , H01G11/10 , H01G11/56 , H01G11/76 , G11C2213/34 , Y02E60/13
摘要： A device provides an electrically settable resistance and comprises first and second electrodes. Each electrode comprises a redox active material. The device further comprises means defining an environment for each electrode such that the average redox state of the electrodes, taken together, remains substantially constant. The environment-defining means includes an electrolyte between the electrodes. The device further comprises a pair of terminals electrically connected to the first electrode at spaced-apart locations, the electrically settable resistance being defined between the pair of terminals and being a function of the oxidation state of the first electrode. The device further comprises means, including a terminal electrically connected to the second electrode, for defining a control circuit path, including the first and second electrodes and the electrolyte, to enable a control current flowing through the control circuit path to change the oxidation state of the first electrode so that control current flowing in one direction sets the resistance to a lower value and control current flowing in the opposite direction sets the resistance to a higher value.
摘要翻译：一种器件提供电可设置电阻并且包括第一和第二电极。每个电极包含氧化还原活性材料。该装置还包括限定每个电极的环境的装置，使得电极的平均氧化还原状态一起保持基本上恒定。环境限定装置包括电极之间的电解质。该装置还包括在间隔开的位置电连接到第一电极的一对端子，电可设定电阻限定在该对端子之间，并且是第一电极的氧化状态的函数。该装置还包括装置，其包括电连接到第二电极的端子，用于限定包括第一和第二电极和电解质的控制电路路径，以使得流过控制电路路径的控制电流能够改变氧化态第一电极使得在一个方向上流动的控制电流将电阻设置为较低的值，并且以相反方向流动的控制电流将电阻设置为较高的值。

4. 发明授权

US08308978B2 Polymer matrix electroluminescent materials and devices 有权
标题翻译：聚合物基质电致发光材料和器件
公开(公告)号：US08308978B2
公开(公告)日：2012-11-13
申请号：US10737220
申请日：2003-12-15
申请人： Matthew L. Marrocco, III , Farshad J. Motamedi
发明人： Matthew L. Marrocco, III , Farshad J. Motamedi
IPC分类号： H01J1/62 , H01L29/08 , H01L33/00 , C09K11/02 , C09K11/06
CPC分类号： H01L51/0039 , C08G61/10 , C08G61/12 , C08G61/122 , C08G61/124 , C08G61/125 , C08G61/126 , C08G73/18 , C08G73/22 , C08G2261/12 , C08G2261/1523 , C08G2261/312 , C08G2261/52 , C08G2261/95 , C08K3/24 , C08L65/00 , C08L79/04 , C09D5/22 , C09D5/24 , C09D165/00 , C09D165/02 , C09K11/06 , C09K2211/1416 , C09K2211/1425 , C09K2211/145 , C09K2211/1466 , C09K2211/182 , H01L51/0004 , H01L51/0035 , H01L51/0038 , H01L51/0043 , H01L51/0089 , H01L51/5008 , H01L51/5012 , H01L51/5016 , H01L51/5036 , H01L51/5056 , H01L51/5072 , H01L51/5206 , H01L51/5234 , H01L51/56 , H01L2251/306 , H05B33/14 , Y10T428/25
摘要： Photoluminescent and electroluminescent compositions are provided which comprise a matrix comprising aromatic repeat units and a luminescent metal ion or luminescent metal ion complex. Methods for producing such compositions, and the electroluminescent devices formed therefrom, are disclosed.
摘要翻译：提供了包含芳族重复单元和发光金属离子或发光金属离子络合物的基质的光致发光和电致发光组合物。公开了制备这种组合物的方法以及由其形成的电致发光器件。

5. 发明授权

US08206838B2 Polymer matrix electroluminescent materials and devices 有权
标题翻译：聚合物基质电致发光材料和器件
公开(公告)号：US08206838B2
公开(公告)日：2012-06-26
申请号：US10738143
申请日：2003-12-16
申请人： Matthew L. Marrocco, III , Farshad J. Motamedi , Feras Bashir Abdelrazzaq , Bashir Twfiq Abdelrazzaq, legal representative
发明人： Matthew L. Marrocco, III , Farshad J. Motamedi , Feras Bashir Abdelrazzaq
IPC分类号： C08G79/00 , H01L29/08 , C09K11/02 , H01J29/32
CPC分类号： H01L51/0043 , C08K3/24 , C08L65/00 , C08L79/04 , C08L101/005 , C08L101/12 , C09K11/02 , C09K11/06 , C09K11/773 , C09K11/7732 , C09K11/7745 , C09K11/7747 , C09K2211/1425 , C09K2211/1475 , C09K2211/182 , C09K2211/185 , H01L51/0035 , H01L51/0039 , H01L51/007 , H01L51/0084 , H01L51/0085 , H01L51/0087 , H01L51/5016 , H05B33/14 , Y10S428/917
摘要： Photoluminescent and electroluminescent compositions are provided which comprise a matrix comprising aromatic repeat units covalently coordinated to a phosphorescent or luminescent metal ion or metal ion complexes. Methods for producing such compositions, and the electroluminescent devices formed therefrom, are also disclosed.
摘要翻译：提供了包含与磷光或发光金属离子或金属离子络合物共价配位的芳族重复单元的基质的光致发光和电致发光组合物。还公开了制备这种组合物的方法及由其形成的电致发光器件。

6. 发明授权

US5858907A Nickel phosphite catalysts 失效
标题翻译：亚磷酸镍催化剂
公开(公告)号：US5858907A
公开(公告)日：1999-01-12
申请号：US715570
申请日：1996-09-18
申请人： Ying Wang , Matthew L. Marrocco, III , Mark S. Trimmer
发明人： Ying Wang , Matthew L. Marrocco, III , Mark S. Trimmer
IPC分类号： B01J31/18 , B01J37/16 , C08G61/10 , C08G61/12 , C08L61/12 , B01J27/185
CPC分类号： C08L61/12 , B01J31/185 , B01J37/16 , C08G61/10 , C08G61/12 , B01J2231/4205 , B01J2531/847
摘要： A catalyst is provided which is useful for coupling aryl halides or aryl sulfonates to produce biaryls or polyaryls. The catalyst composition is formed by mixing together in an anhydrous aprotic solvent a nickel compound or nickel complex, a phosphite ligand, and a reducing metal which can be aluminum, magnesium, or zinc or the like.
摘要翻译：提供了一种催化剂，其可用于偶合芳基卤化物或芳基磺酸盐以制备联芳基或多芳基。催化剂组合物通过在无水非质子溶剂中混合在一起形成，镍溶剂或镍络合物，亚磷酸酯配体和还原金属可以是铝，镁或锌等。

7. 发明授权

US5723573A Thermosetting polyquinolines 失效
标题翻译：热固性聚喹啉
公开(公告)号：US5723573A
公开(公告)日：1998-03-03
申请号：US632156
申请日：1996-04-15
申请人： Matthew L. Marrocco III , Lien-Chung Hsu
发明人： Matthew L. Marrocco III , Lien-Chung Hsu
IPC分类号： C07D215/12 , C07D215/14 , C08G73/06
CPC分类号： C07D215/14 , C07D215/12 , C08G73/0688
摘要： Thermosetting polyquinoline polymers, methods for preparing the polymers, and methods for curing the polymers are provided. The polymers incorporate quinoline repeat units and end groups which include a reactive acetylene functionality. On heat treatment, the reactive end groups form cross-links which render the polymer insoluble and extend the polymer's operating temperature.
摘要翻译：提供了热固性聚喹啉聚合物，聚合物的制备方法和固化聚合物的方法。聚合物包含喹啉重复单元和包括反应性乙炔官能团的端基。在热处理中，反应性端基形成交联，使得聚合物不溶解并延长聚合物的操作温度。

8. 发明授权

US5648448A Method of preparation of polyquinolines 失效
标题翻译：聚喹啉的制备方法
公开(公告)号：US5648448A
公开(公告)日：1997-07-15
申请号：US469993
申请日：1995-06-06
申请人： Matthew L. Marrocco, III , Ying Wang
发明人： Matthew L. Marrocco, III , Ying Wang
IPC分类号： C08J5/18 , C07D215/12 , C07D215/14 , C07D215/18 , C08G65/40 , C08G73/00 , C08G73/06 , D01F6/66 , H01G4/18 , C08G8/02 , C08G14/00
CPC分类号： C07D215/18 , C07D215/12 , C07D215/14 , C08G65/4006 , C08G73/0688 , C08G2650/48 , Y10S428/901 , Y10T428/249921 , Y10T428/2913
摘要： New polyquinoline polymers are provided, as well as new methods for preparing the polyquinoline polymers using a novel combination of monomers. The polyquinoline polymers comprise repeat units comprising at least one quinoline nucleus and at least one ether linkage and having as end groups either fluoro groups or hydroxy groups or a combination of fluoro and hydroxy groups. The polymers are formed by providing a monomer comprising two fluoro groups, where each such fluoro group is activated by a quinoline nucleus, a diol monomer provided in the form of its bis-oxide salt, or in the presence of a base capable of deprotonating the diol and reacting the difluoro and diol monomers together in a dipolar solvent to form the polyquinoline polymer. In an alternative embodiment, the polyquinoline polymers of the present invention are formed by reacting a fluoro hydroxy monomer comprising a quinoline nucleus containing one activated fluoro group and one hydroxy group in the presence of a base and a dipolar solvent to form said polymer. In yet another alternative embodiment, the polyquinoline polymer is formed by providing a monomer which comprises a quinoline nucleus containing one activated fluoro group and one hydroxy group and treating the monomer with a base to form an oxide salt and reacting the monomer salt in a dipolar solvent to form said polymer.
摘要翻译：提供了新的聚喹啉聚合物，以及使用单体的新型组合制备聚喹啉聚合物的新方法。聚喹啉聚合物包含包含至少一个喹啉核和至少一个醚键并且具有氟基或羟基的端基或氟和羟基的组合的重复单元。通过提供包含两个氟基团的单体形成聚合物，其中每个这样的氟基团被喹啉核激活，以双氧化物盐形式提供的二醇单体，或者在能够使质子交换反应并使二氟和二醇单体在偶极溶剂中反应形成聚喹啉聚合物。在替代实施方案中，本发明的聚喹啉聚合物通过在碱和偶极溶剂的存在下使含有一个活化氟基团的喹啉核和一个羟基的氟羟基单体反应形成所述聚合物而形成。在又一替代实施方案中，聚喹啉聚合物通过提供包含含有一个活化氟基团和一个羟基的喹啉核的单体形成，并用碱处理单体以形成氧化物盐，并使该单体盐在偶极溶剂以形成所述聚合物。

9. 发明授权

US5625010A Macromonomers having reactive side groups 失效
标题翻译：具有活性侧基的大分子单体
公开(公告)号：US5625010A
公开(公告)日：1997-04-29
申请号：US458758
申请日：1995-06-02
申请人： Robert R. Gagn e , Matthew L. Marrocco, III , Mark S. Trimmer , Neil H. Hendricks
发明人： Robert R. Gagn e , Matthew L. Marrocco, III , Mark S. Trimmer , Neil H. Hendricks
IPC分类号： C08F299/02 , C07C45/46 , C07C45/68 , C07C49/798 , C07C49/83 , C07C59/84 , C07C69/017 , C07C69/76 , C07C225/22 , C07C251/24 , C08F290/00 , C08F290/12 , C08F290/14 , C08G59/42 , C08G61/00 , C08G61/10 , C08G61/12 , C08G69/16 , C08G69/26 , C08G85/00 , C08L63/00 , C08L101/00 , C08L65/02
CPC分类号： C08L63/00 , C07C225/22 , C07C251/24 , C07C45/46 , C07C45/68 , C07C49/798 , C07C49/83 , C07C59/84 , C07C69/017 , C07C69/76 , C08F290/124 , C08F290/14 , C08G59/4223 , C08G61/00 , C08G61/10 , C08G69/16 , C08G69/26 , C08G85/00 , C08L101/00 , C08G2261/312
摘要： Rigid-rod macromonomers, and methods for preparing such macromonomers, having a polyaromatic backbone, solubilizing side groups, and reactive side groups are provided. The macromonomers are chemically incorporated into polymer systems to provide stronger, stiffened polymers.
摘要翻译：提供刚性大分子单体和制备这种大分子单体的方法，其具有多芳族主链，增溶侧基和反应性侧基。大分子单体化学地并入聚合物体系中以提供更强的加强的聚合物。

10. 发明授权

US5565543A Rigid-rod polymers 失效
标题翻译：刚性聚合物
公开(公告)号：US5565543A
公开(公告)日：1996-10-15
申请号：US289174
申请日：1994-08-11
申请人： Matthew L. Marrocco, III , Robert R. Gagne , Mark S. Trimmer
发明人： Matthew L. Marrocco, III , Robert R. Gagne , Mark S. Trimmer
IPC分类号： C08F8/00 , C08G61/00 , C08G61/02 , C08G61/10 , C08G61/12 , C08G75/32 , C08L23/02 , C08L23/10 , C08L25/06 , C08L27/04 , C08L65/00 , C08L67/02 , C08L69/00 , C08L71/00 , C08L71/12 , C08L101/00 , C08G69/26 , C08G73/10 , C08G73/22 , C08L65/02
CPC分类号： C08L101/00 , C08F8/00 , C08G61/00 , C08G61/02 , C08G61/10 , C08G61/12 , C08G75/32 , C08L23/02 , C08L65/00 , C08L67/02 , C08L69/00 , C08L71/123 , C08G2261/312 , C08L2205/14 , C08L23/10 , C08L25/06 , C08L27/04 , C08L71/00 , Y10T428/31721 , Y10T428/31725
摘要： High-performance polymers having a rigid-rod backbone comprising a chain length of at least 25 organic monomer units joined together by covalent bonds wherein at least about 95% of the bonds are substantially parallel; and solubilizing organic groups attached to at least 1% of the monomer units. The polymers are prepared in a solvent system which is a solvent for both the monomer starting materials and the rigid-rod polymer product.
摘要翻译：具有刚性棒主链的高性能聚合物，其包含通过共价键连接在一起的至少25个有机单体单元的链长，其中至少约95％的键基本上平行; 并溶解附着在至少1％单体单元上的有机基团。聚合物在溶剂体系中制备，溶剂体系是用于单体原料和刚性 - 棒状聚合物产物的溶剂。

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