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1. 发明授权

US06243254B1 Dielectric ceramic composition and laminated ceramic capacitor using the same 有权
标题翻译：介电陶瓷组合物和使用其的层压陶瓷电容器
公开(公告)号：US06243254B1
公开(公告)日：2001-06-05
申请号：US09369988
申请日：1999-08-06
申请人： Nobuyuki Wada , Masamitsu Shibata , Takashi Hiramatsu , Yukio Hamaji
发明人： Nobuyuki Wada , Masamitsu Shibata , Takashi Hiramatsu , Yukio Hamaji
IPC分类号： H01G406
CPC分类号： C04B35/4684 , C04B35/465 , H01G4/1227
摘要： Provided is a highly reliable laminated ceramic capacitor in which decrease of dielectric constant under a high electric field is small and which satisfies the B-grade and X7R grade characteristics, using Ni for the inner electrodes, wherein the dielectric material contains about 0.2 to 5.0 parts by weight of Li2O—(Si, Ti)2—MO oxides (MO is at least one of the compounds of Al2O3 and ZrO2) or SiO2—TiO2—XO oxides (XO is at least one of the compounds of BaO, CaO, SrO, MgO, ZnO and MnO) relative to 100 parts by weight of a principal component represented by (Ba1−xCaxO)mTiO2+&agr;Re2O3+&bgr;MgO+&ggr;MnO (Re2O3 represents at least one of Y2O3, Gd2O3, Tb2O3, Dy2O3, Ho2O3, Er2O3 and Yb2O3).
摘要翻译：提供了一种高度可靠的层叠陶瓷电容器，其中使用Ni作为内部电极，其中高电场下介电常数的降低小且满足B级和X7R等级特性，其中介电材料含有约0.2至5.0份的Li2O-（Si，Ti）2-MO氧化物（MO是Al2O3和ZrO2的化合物中的至少一种）或SiO 2 -TiO 2 -XO氧化物（XO是BaO，CaO，SrO的化合物中的至少一种，MgO，ZnO和MnO）相对于100重量份由（Ba1-xCaxO）mTiO2 +αRe2O3+βMgO+γMnO表示的主成分（Re2O3表示Y2O3，Gd2O3，Tb2O3，Dy2O3，Ho2O3，Er2O3和Dy2O3中的至少一种） Yb2O3）。

2. 发明授权

US5432136A Dielectric ceramic compositions 失效
标题翻译：介电陶瓷组合物
公开(公告)号：US5432136A
公开(公告)日：1995-07-11
申请号：US278620
申请日：1994-07-21
申请人： Masamitsu Shibata , Yukio Hamaji
发明人： Masamitsu Shibata , Yukio Hamaji
IPC分类号： C04B35/468 , H01B3/12 , H01G4/12 , C04B35/46
CPC分类号： C04B35/4684 , H01B3/12 , H01G4/1227
摘要： The present invention is directed to a dielectric ceramic composition composed of, 97.5 to 99.95 wt. % of main component represented by, {100-(a+b+c+d)} (Ba.sub.100-x Pb.sub.x) TiO.sub.3 +aZnO+bBi.sub.2 O.sub.3 +cNb.sub.2 O.sub.5 +dRe.sub.2 O.sub.3 (0.5.ltoreq.a.ltoreq.4.5, 0.5.ltoreq.b.ltoreq.4.5, 0.5.ltoreq.c.ltoreq.4.5, 0.5.ltoreq.d.ltoreq.5.5 and 0
摘要翻译：本发明涉及一种电介质陶瓷组合物，其组成为97.5至99.95wt。由（{100-（a + b + c + d）}（Ba100-x Pbx）TiO3 + aZnO + bBi2O3 + cNb2O5 + dRe2O3（0.5≤a≤4.5,0.5）表示的主要成分的％ b =4.5,0.5≤c=4.5,0.5≤d≤5.5和0

3. 发明授权

US5635435A Dielectric ceramic compositions 失效
标题翻译：介电陶瓷组合物
公开(公告)号：US5635435A
公开(公告)日：1997-06-03
申请号：US634150
申请日：1996-04-19
申请人： Masamitsu Shibata
发明人： Masamitsu Shibata
IPC分类号： C04B35/46 , C04B35/468 , H01B3/12 , H01G4/12 , C03C14/00
CPC分类号： C04B35/468 , H01B3/12 , H01G4/1227
摘要： A dielectric ceramic composition having about 97.5 to 99.95 wt % of a main component and 0.05 to 2.5 wt % of a first subcomponent, the main component having the following general formula:{100-(a+b+c+d+e)}BaTiO.sub.3 +aBi.sub.2 O.sub.3 +bNb.sub.2 O.sub.5 +cMxO+dMyO.sub.2 +eMz,wherein Mx is at least one element selected from the group consisting of Mg, Ca and Zn; My is at least one element selected from the group consisting of Ti, Sn and Zr; Mz is at least one oxide of an element selected from the group consisting of Y, La, Ce, Pr, Nd, Sm, Dy, Ho and Er; and a, b, c, d, and e are mole % and are in the following ranges: 1.0.ltoreq.a.ltoreq.6.0, 0.5.ltoreq.b.ltoreq.4.5, 0.ltoreq.c.ltoreq.4.0, 1.5.ltoreq.d.ltoreq.15.0, and 0.5.ltoreq.e.ltoreq.5.5; and the first subcomponent comprising a glass mainly containing SiO.sub.2. The composition can be subjected to firing at 1,160.degree. C. or less; satisfies the X8R characteristic of the EIA standard in spite of a high dielectric constant of 1,000 or more; and exhibits a small change rate of the electrostatic capacitance toward the temperature when a bias dc voltage is applied thereto.
摘要翻译：主要成分为主成分为97.5〜99.95重量％，第一副成分为0.05〜2.5重量％的电介质陶瓷组合物，其主成分具有以下通式：{100-（a + b + c + d + e）} BaTiO3 + aBi2O3 + bNb2O5 + cMxO + dMyO2 + eMz，其中Mx是选自Mg，Ca和Zn中的至少一种元素; 我是选自Ti，Sn和Zr中的至少一种元素; Mz是选自Y，La，Ce，Pr，Nd，Sm，Dy，Ho和Er中的元素的至少一种氧化物; 和a，b，c，d和e是摩尔％，并且在以下范围内：1.0

4. 外观设计

USD275390S Video tape recorder 失效
公开(公告)号：USD275390S
公开(公告)日：1984-09-04
申请号：US374762
申请日：1982-05-04
申请人： Masamitsu Shibata , Hiroshi Yamamoto
设计人： Masamitsu Shibata , Hiroshi Yamamoto

5. 发明授权

US5612268A Dielectric ceramic composition 失效
标题翻译：介电陶瓷组合物
公开(公告)号：US5612268A
公开(公告)日：1997-03-18
申请号：US447234
申请日：1995-05-22
申请人： Sakiko Iwamoto , Masamitsu Shibata , Yukio Hamaji
发明人： Sakiko Iwamoto , Masamitsu Shibata , Yukio Hamaji
IPC分类号： C04B35/468 , H01B3/12 , H01G4/12 , C04B35/462 , C04B35/475 , C04B35/495
CPC分类号： C04B35/4682 , H01B3/12 , H01G4/1227
摘要： The present invention relates to a dielectric ceramic composition, comprising from 97.5 to 99.95% by weight of{100-(a+b+c+d)}BaTiO.sub.3 +aZnO+b(2Bi.sub.2 O.sub.3.3AO.sub.2)+cTa.sub.2 O.sub.5 +dRe.sub.2 O.sub.3as main component and from 0.05 to 2.5% by weight of glass mainly comprising SiO.sub.2, and possibly also containing from 0.01 to 0.5% by weight of at least one oxides of Cr, Mn, Fe, Co, and/or Ni. A represents Zr or Sn; Re represents at least one of La, Pr, Nd, Sm, Dy and Er; and {100-(a+b+c+d)}, a, b, c, and d represent molar percent which satisfy the following relationships:______________________________________ 0.5 .ltoreq. a .ltoreq. 4.5 0.5 .ltoreq. b .ltoreq. 4.5 0.5 .ltoreq. c .ltoreq. 4.5 0.5 .ltoreq. d .ltoreq. 5.5. ______________________________________
摘要翻译：本发明涉及一种电介质陶瓷组合物，其包含97.5-99.95重量％的{100-（a + b + c + d）} BaTiO3 + aZnO + b（2Bi2O3.3AO2）+ cTa2O5 + dRe2O3为主要成分， 0.05-2.5重量％的主要包含SiO 2的玻璃，并且还可能含有0.01-0.5重量％的至少一种Cr，Mn，Fe，Co和/或Ni的氧化物。 A表示Zr或Sn; Re表示La，Pr，Nd，Sm，Dy和Er中的至少一种; 和{100-（a + b + c + d）}，a，b，c和d表示满足以下关系的摩尔百分比：-0.5

6. 外观设计

USD285683S Combined video tape recorder and video camera 失效
公开(公告)号：USD285683S
公开(公告)日：1986-09-16
申请号：US582231
申请日：1984-02-21
申请人： Masamitsu Shibata
设计人： Masamitsu Shibata

7. 外观设计

USD272062S Video tape cassette 失效
公开(公告)号：USD272062S
公开(公告)日：1984-01-03
申请号：US289976
申请日：1981-08-04
申请人： Masamitsu Shibata , Haruki Ogata
设计人： Masamitsu Shibata , Haruki Ogata

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