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    • 1. 发明授权
    • Photosensitive composition for volume hologram recording
    • 用于体积全息图记录的光敏组合物
    • US5665494A
    • 1997-09-09
    • US327551
    • 1994-10-24
    • Masami KawabataAkihiko SatoIwao Sumiyoshi
    • Masami KawabataAkihiko SatoIwao Sumiyoshi
    • G03F7/004C08F2/50G03F7/00G03F7/027G03F7/029G03F7/038G03H1/02G03C1/72
    • C08F2/50G03F7/001G03F7/029G03F7/038G03H2001/026G03H2260/12
    • Disclosed is a photosensitive composition for volume hologram recording which is used for recording an interference fringe produced by a laser beam or a light having excellent coherence, as fringes having different refractive index. The composition comprising:(a) a cationic polymerizable compound which is liquid at ambient temperature;(b) a radical polymerizable compound;(c) a radical photopolymerization initiator composition sensitized by a laser beam or a light having excellent coherence which has a specific wavelength to polymerize the ingredient (b); and(d) a cationic photopolymerization initiator composition which shows low photosensitivity to the light having a specific wavelength and is sensitized by a light having the other wavelength to polymerize the ingredient (a), wherein an average refractive index of the ingredient (a) is smaller than that of the ingredient (b). A process for producing the photosensitive composition is also disclosed.
    • 公开了一种用于体积全息记录的感光组合物,其用于记录由激光束产生的干涉条纹或具有优异相干性的光,作为折射率不同的条纹。 该组合物包含:(a)在室温下为液体的阳离子可聚合化合物; (b)可自由基聚合的化合物; (c)通过激光束或具有优异相干性的光敏化的自由基光聚合引发剂组合物,其具有特定波长以聚合成分(b); 和(d)阳离子光聚合引发剂组合物,其具有对具有特定波长的光的低光敏性,并且通过具有另一波长的光使其成分(a)聚合,其中成分(a)的平均折射率为 小于成分(b)的成分。 还公开了用于制备光敏组合物的方法。
    • 2. 发明授权
    • Photosensitive composition for volume hologram recording
    • 用于体积全息图记录的光敏组合物
    • US5453340A
    • 1995-09-26
    • US152094
    • 1993-11-15
    • Masami KawabataAkihiko SatoIwao Sumiyoshi
    • Masami KawabataAkihiko SatoIwao Sumiyoshi
    • G03F7/004C08F2/50G03F7/00G03F7/027G03F7/029G03F7/038G03H1/02
    • C08F2/50G03F7/001G03F7/029G03F7/038G03H2001/026G03H2260/12
    • Disclosed is a photosensitive composition for volume hologram recording which is used for recording an interference fringe produced by a laser beam or a light having excellent coherence, as fringes having different refractive index. The composition comprising:(a) a cationic polymerizable compound which is liquid at ambient temperature;(b) a radical polymerizable compound;(c) a radical photopolymerization initiator composition sensitized by a laser beam or a light having excellent coherence which has a specific wavelength to polymerize the ingredient (b); and(d) a cationic photopolymerization initiator composition which shows low photosensitivity to the light having a specific wavelength and is sensitized by a light having the other wavelength to polymerize the ingredient (a), wherein an average refractive index of the ingredient (a) is smaller than that of the ingredient (b). A process for producing the photosensitive composition is also disclosed.
    • 公开了一种用于体积全息记录的感光组合物,其用于记录由激光束产生的干涉条纹或具有优异相干性的光,作为折射率不同的条纹。 该组合物包含:(a)在室温下为液体的阳离子可聚合化合物; (b)可自由基聚合的化合物; (c)通过激光束或具有优异相干性的光敏化的自由基光聚合引发剂组合物,其具有特定波长以聚合成分(b); 和(d)阳离子光聚合引发剂组合物,其具有对具有特定波长的光的低光敏性,并且通过具有另一波长的光使其成分(a)聚合,其中成分(a)的平均折射率为 小于成分(b)的成分。 还公开了用于制备光敏组合物的方法。
    • 7. 发明授权
    • Photopolymerizable composition
    • 可光聚合组合物
    • US5368990A
    • 1994-11-29
    • US923977
    • 1992-11-05
    • Masami KawabataAkihiko SatoIwao Sumiyoshi
    • Masami KawabataAkihiko SatoIwao Sumiyoshi
    • C08F2/50G03F7/004G03F7/028G03F7/029G03F7/031G03H1/02G03C1/73
    • G03F7/031C08F2/50G03F7/029Y10S430/121
    • A photopolymerizable composition comprising an addition polymerizable compound having an ethylenically unsaturated double bond and a photopolymerization initiating composition, said photopolymerizable initiating composition comprising (a) a dye of the formula: ##STR1## [wherein R.sub.1 is H, an alkyl group having 1 to 3 carbon atoms, a phenyl group or a halogen atom; R.sub.2 is a methyl group, an ethyl group or (CH.sub.2).sub.p -Q (wherein Q is a carboxyl group, a sulfonyl group or salt thereof and p is an integer of 1 to 4); X.sub.1 and X.sub.2 are independently --O--, --S--, --CH.dbd.CH-- or >N--R.sub.2 ; Y.sub.1 and Y.sub.2 are independently H, an alkyl group having 1 to 3 carbon atoms, an alkoxy group having 1 to 3 carbon atoms, a phenyl group or a halogen atom; Z is --COO or --SO.sub.3 ; m is 0 or 1; and n is an integer of 1 to 4] and (b) diaryliodonium salt as a polymerization initiator.
    • PCT No.PCT / JP92 / 00044 Sec。 371日期:1992年11月5日 102(e)日期1992年11月5日PCT提交1992年1月22日PCT公布。 公开号WO92 / 13008 1.一种可光聚合组合物,其包含具有烯属不饱和双键的加聚聚合化合物和光聚合引发组合物,所述光聚合引发组合物包含(a)下式的染料:其中R 1 是H,具有1至3个碳原子的烷基,苯基或卤素原子; R2是甲基,乙基或(CH2)p-Q(其中Q是羧基,磺酰基或其盐,p是1至4的整数); X 1和X 2独立地是-O - , - S - , - CH = CH-或> N-R 2; Y1和Y2独立地为H,具有1至3个碳原子的烷基,具有1至3个碳原子的烷氧基,苯基或卤素原子; Z是-COO或-SO 3; m为0或1; n为1〜4的整数]和(b)二芳基碘鎓盐作为聚合引发剂。
    • 10. 发明授权
    • Photosensitive composition for volume hologram recording
    • 用于体积全息图记录的光敏组合物
    • US5858614A
    • 1999-01-12
    • US728031
    • 1996-10-09
    • Akihiko SatoMasami KawabataIwao Sumiyoshi
    • Akihiko SatoMasami KawabataIwao Sumiyoshi
    • G03F7/004G03F7/00G03F7/027G03F7/028G03F7/029G03H1/02G03H3/00
    • G03F7/001G03F7/027G03H1/0248G03H2260/12
    • A photosensitive composition for volume hologram recording used for recording an interference fringe produced by the interference of laser beams or lights having excellent coherence as a fringe having a different refractive index, the composition comprising:(a) a radical polymerizable compound having a 9,9-diarylfluorene skeleton, which is liquid at a normal temperature;(b) a compound having compatibility with the component (a), which is selected from the group consisting of a cationic polymerizable compound, a radical polymerizable compound having no 9,9-diarylfluorene skeleton and a plasticizer; and(c) a radical photopolymerization initiator which is sensitive to laser beam having a specific wavelength or light having a specific wavelength and excellent coherence to polymerize the component (a);wherein an average refractive index of the component (a) is larger than that of the component (b).
    • 一种用于体积全息图记录的感光组合物,用于记录由具有优异相干性的激光束或具有不同折射率的条纹的光束产生的干涉条纹,该组合物包含:(a)具有9,9 - 二芳基芴骨架,其在常温下为液体; (b)与选自阳离子聚合性化合物,不具有9,9-二芳基芴骨架的自由基聚合性化合物和增塑剂的组分(a)相容的化合物; 和(c)对具有特定波长的激光束或具有特定波长的光敏感的自由基光聚合引发剂和优异的相干性以使组分(a)聚合; 其中组分(a)的平均折射率大于组分(b)的平均折射率。