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1. 发明授权

US07638199B2 Glass substrate having primer layer formed thereon and anti-fogging article 失效
标题翻译：具有底涂层的玻璃基板和防雾物品
公开(公告)号：US07638199B2
公开(公告)日：2009-12-29
申请号：US10582362
申请日：2004-11-25
申请人： Toshihiro Hirano , Toru Hirotsu , Noboru Murata , Masahiro Hirukawa , Nobuyuki Itakura
发明人： Toshihiro Hirano , Toru Hirotsu , Noboru Murata , Masahiro Hirukawa , Nobuyuki Itakura
IPC分类号： B32B15/00 , B05D1/36 , B05D7/00
CPC分类号： C09D185/00 , C03C17/34 , C03C17/42 , C08G77/58 , C09D4/00 , Y10T428/31645 , Y10T428/31663 , Y10T428/31667 , Y10T428/31855 , C08G77/00
摘要： The present invention relates to a glass substrate which is characterized in that it has a primer layer that is formed thereon and includes a hydrolysis product of a hydrolysable silicon compound having an alkylene group and a hydrolysis product of a hydrolysable zirconium compound or hydrolysable titanium compound, and that, in the primer layer, zirconium is in an amount by weight ratio of 0.0002 times to 0.0025 times that of silicon, or titanium is in an amount by weight ratio of 0.0005 times to 0.0045 times that of silicon. Furthermore, the present invention relates to an anti-fogging article having a resin film that exhibits water-absorptive property and/or hydrophilic property and is formed on the primer layer of the glass substrate.
摘要翻译：本发明涉及一种玻璃基板，其特征在于，其具有底涂层，其上形成有包含具有亚烷基的可水解硅化合物和可水解锆化合物或可水解钛化合物的水解产物的水解产物，并且在底涂层中，锆的重量比为硅的0.0002倍至0.0025倍，或钛的重量比为硅的0.0005倍至0.0045倍。此外，本发明涉及具有显示吸水性和/或亲水性的树脂膜并形成在玻璃基板的底漆层上的防雾物品。

2. 发明授权

US5731060A Holographic laminate 失效
标题翻译：全息层压板
公开(公告)号：US5731060A
公开(公告)日：1998-03-24
申请号：US579616
申请日：1996-02-12
申请人： Masahiro Hirukawa , Takashi Yamate
发明人： Masahiro Hirukawa , Takashi Yamate
IPC分类号： G02B5/32 , G03H1/02 , G03H1/04 , B32B3/00
CPC分类号： G03H1/0256 , G03H2001/0055 , G03H2250/10 , G03H2250/37 , Y10T428/24364 , Y10T428/24802 , Y10T428/2486 , Y10T428/252 , Y10T428/31504 , Y10T428/31786 , Y10T428/31855 , Y10T428/31928
摘要： A holographic laminate to be used in a vehicular windshield or windowpane and an architectural window glass in order to display a variety of images for the expressive and decorative purposes. The holographic laminate comprises a transparent plate on which a hologram is mounted. An ultraviolet ray absorbing film is disposed on a side of the hologram through which side sunlight enter the hologram. A layer of an adhesive is disposed to secure the hologram to the transparent plate layer. A barrier film is disposed between the hologram and the adhesive layer to protect the hologram from being chemically affected by the adhesive layer.
摘要翻译：用于车辆挡风玻璃或窗玻璃和建筑窗玻璃中的全息层压板，以便展示用于表现和装饰目的的各种图像。全息层压板包括其上安装有全息图的透明板。紫外线吸收膜设置在全息图的侧面，通过侧面太阳光进入全息图。设置粘合剂层以将全息图固定到透明板层。在全息图和粘合剂层之间设置阻挡膜，以保护全息图免受粘合剂层的化学影响。

3. 发明授权

US5013788A Liquid coating composition and coating method for forming hard-coat film on plastics 失效
标题翻译：液体涂料组合物和在塑料上形成硬涂膜的涂布方法
公开(公告)号：US5013788A
公开(公告)日：1991-05-07
申请号：US450811
申请日：1989-12-14
申请人： Toshikazu Nagashima , Haruki Kuramashi , Yoshihiro Nishida , Masahiro Hirukawa
发明人： Toshikazu Nagashima , Haruki Kuramashi , Yoshihiro Nishida , Masahiro Hirukawa
IPC分类号： B32B27/00 , C08J7/04 , C09D1/00 , C09D4/00 , C09D183/06
CPC分类号： C08J7/047 , C09D183/06 , C09D4/00 , C08J2483/00
摘要： The invention provides a liquid coating composition for forming a transparent and hard coating film on a plastic member such as a polycarbonate or polymethyl methacrylate plate. The liquid composition comprises 100 parts by weight of an organotrialkoxysilane R.sup.1 Si(OR.sup.2).sub.3, where R.sup.1 is a C.sub.1 - or C.sub.2 -alkyl group and R.sup.2 is a C.sub.1 -, C.sub.2 - or C.sub.3 -alkyl group, 5-20 parts by weight of an organotrialkoxysilane R.sup.3 Si(OR.sup.2).sub.3, where R.sup.3 is an organic group containing epoxy group, 50-200 parts by weight of an aqueous colloidal silica sol in which the content of SiO.sub.2 is 10-40 wt %, and 0.5-3 parts by weight of a dicarboxylic acid (CF.sub.2).sub.n (COOH).sub.2, where n is an integer from 1 to 5, preferably hexafluoroglutaric acid. On a surface of a plastic member a coating film of this composition is partially cured at 70.degree.-150.degree. C. to turn into a fairly hard but still pliable film. Then the plastic member can be shaped so as to bend the coated surface without suffering from cracking or peeling of the partially cured film. After that the film is treated with an aqueous alkali solution and then further cured at 80.degree.-150.degree. C.
摘要翻译：本发明提供一种用于在诸如聚碳酸酯或聚甲基丙烯酸甲酯板的塑料部件上形成透明和硬涂层的液体涂料组合物。液体组合物包含100重量份的有机三烷氧基硅烷R1Si（OR2）3，其中R1是C1-或C2-烷基，R2是C1-，C2-或C3-烷基，5-20重量份的有机三烷氧基硅烷R3Si（OR2）3，其中R3是含环氧基的有机基团，50-200重量份SiO 2含量为10-40重量％的胶体硅溶胶水溶液和0.5-3重量份的二羧酸（CF 2）n（COOH）2，其中n是1至5的整数，优选六氟戊酸。在塑料构件的表面上，该组合物的涂膜在70-150℃下部分固化，变成相当硬但仍柔软的膜。然后可以将塑料构件成形为使得涂覆的表面弯曲，而不会部分固化的膜的开裂或剥离。之后，用碱水溶液处理该膜，然后在80-150℃进一步固化。

4. 发明申请

US20080160187A1 Antifog Article, Method for Producing Same, and Coating Material for Forming Antifog Coating Film 审中-公开
标题翻译：防雾用品，其制造方法以及形成防雾涂膜的涂料
公开(公告)号：US20080160187A1
公开(公告)日：2008-07-03
申请号：US11666550
申请日：2005-12-16
申请人： Noboru Murata , Masahiro Hirukawa , Toshihiro Hirano
发明人： Noboru Murata , Masahiro Hirukawa , Toshihiro Hirano
IPC分类号： B05D5/06 , C08G18/00
CPC分类号： C08G18/4063 , C03C17/28 , C03C17/322 , C08G18/0828 , C08G18/6529 , C08G18/7831 , C08G2290/00 , C08L75/12 , C09D7/65 , C09D175/12
摘要： The present invention relates to a coating agent for forming an antifogging film on a substrate. This coating agent is formed of a solvent and a mixture containing: (A) an organic isocyanate; (B) a water-absorbing polyol; (C) an acryl polyol; and (D) a surface active agent having an active hydrogen group.
摘要翻译：本发明涉及在基材上形成防雾膜的涂布剂。该涂料由溶剂和混合物形成，该混合物含有：（A）有机异氰酸酯; （B）吸水多元醇; （C）丙烯酸多元醇; 和（D）具有活性氢基团的表面活性剂。

5. 发明申请

US20070099000A1 Glass substrate having primer layer formed thereon and anti-fogging article 失效
标题翻译：具有底涂层的玻璃基板和防雾物品
公开(公告)号：US20070099000A1
公开(公告)日：2007-05-03
申请号：US10582362
申请日：2004-11-25
申请人： Toshihiro Hirano , Toru Hirotsu , Noboru Murata , Masahiro Hirukawa , Nobuyuki Itakura
发明人： Toshihiro Hirano , Toru Hirotsu , Noboru Murata , Masahiro Hirukawa , Nobuyuki Itakura
IPC分类号： C04B41/50
CPC分类号： C09D185/00 , C03C17/34 , C03C17/42 , C08G77/58 , C09D4/00 , Y10T428/31645 , Y10T428/31663 , Y10T428/31667 , Y10T428/31855 , C08G77/00
摘要： The present invention relates to a glass substrate which is characterized in that it has a primer layer that is formed thereon and includes a hydrolysis product of a hydrolysable silicon compound having an alkylene group and a hydrolysis product of a hydrolysable zirconium compound or hydrolysable titanium compound, and that, in the primer layer, zirconium is in an amount by weight ratio of 0.0002 times to 0.0025 times that of silicon, or titanium is in an amount by weight ratio of 0.0005 times to 0.0045 times that of silicon. Furthermore, the present invention relates to an anti-fogging article having a resin film that exhibits water-absorptive property and/or hydrophilic property and is formed on the primer layer of the glass substrate.
摘要翻译：本发明涉及一种玻璃基板，其特征在于，其具有底涂层，其上形成有包含具有亚烷基的可水解硅化合物和可水解锆化合物或可水解钛化合物的水解产物的水解产物，并且在底涂层中，锆的重量比为硅的0.0002倍至0.0025倍，或钛的重量比为硅的0.0005倍至0.0045倍。此外，本发明涉及具有显示吸水性和/或亲水性的树脂膜并形成在玻璃基板的底漆层上的防雾物品。

6. 发明申请

US20060047064A1 Coating agent for forming antifogging film and method for forming antifogging film using same 审中-公开
标题翻译：用于形成防雾膜的涂布剂和使用其形成防雾膜的方法
公开(公告)号：US20060047064A1
公开(公告)日：2006-03-02
申请号：US10513680
申请日：2003-07-29
申请人： Noboru Murata , Masahiro Hirukawa , Hiroshi Honjo , Toshiro Matsuura , Seiji Yamazaki
发明人： Noboru Murata , Masahiro Hirukawa , Hiroshi Honjo , Toshiro Matsuura , Seiji Yamazaki
IPC分类号： C08G18/08
CPC分类号： C08G18/7831 , C03C17/322 , C08G18/0828 , C08G18/4018 , C08G18/44 , C08G18/6607 , C08G2290/00 , C09D175/04
摘要： The invention relates to a two-package coating agent for forming an antifogging film. This coating agent contains a first coating agent comprising an isocyanate containing an isocyanate group; and a second coating agent comprising (a) a polyol component comprising at least a water-absorbing polyol and a hydrophobic polyol and (b) a surfactant comprising a group that is reactive with the isocyanate group. It is possible to form an antifogging film by a method including the steps of mixing the first and second coating agents together to prepare a coating agent; applying the coating agent to the substrate to form a precursory film on the substrate; and hardening the precursory film under room temperature or heating into the antifogging film.
摘要翻译：本发明涉及一种用于形成防雾膜的双层包衣剂。该涂料含有含有异氰酸酯基的异氰酸酯基的第一包衣剂; 和包含（a）至少包含吸水多元醇和疏水多元醇的多元醇组分的第二涂料，和（b）包含与异氰酸酯基反应的基团的表面活性剂。可以通过以下方法形成防雾膜，该方法包括将第一和第二涂布剂混合在一起以制备涂布剂; 将涂布剂施加到基材上以在基材上形成前体膜; 并在室温下硬化前体膜或加热到防雾膜中。

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