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    • 4. 发明授权
    • Method for commercial preparation of conjugated linoleic acid
    • 共轭亚油酸的商业制备方法
    • US06420577B1
    • 2002-07-16
    • US09451710
    • 1999-12-01
    • Martin J. ReaneyYa-Dong LiuNeil D Westcott
    • Martin J. ReaneyYa-Dong LiuNeil D Westcott
    • C07C51347
    • C11C1/007C11C1/025C11C1/10C11C3/14
    • Methods for simultaneous saponification and quantitative isomerization of glyceride oils containing interrupted double bond systems, with alkali in water to yield soaps with conjugated double bond systems are disclosed. Novel methods of hydrolysis of the soap product with acid to form fatty acid-water emulsions and the breaking of those emulsions are also disclosed. The preferred embodiment uses a vegetable oil rich in linoleic acid such as sunflower or safflower oil, potassium hydroxide, phosphoric acid to neutralize the soaps, and an emulsion breaking compound which can include ethanol or other monohydric alcohol, tannins (either hydrolysable or condensed tannin) or polyethylene glycol. The reaction forms positional and geometric isomers of conjugated linoleic acid and the preferred isomer mixture is controlled by a combination of agitation, precisely controlled heating and rapid initiation and termination of the reaction. The reaction product composition may be enriched by crystallization.
    • 公开了含有间断双键体系的甘油酯油同时皂化和定量异构化的方法,其中碱在水中产生具有共轭双键体系的皂。 还公开了用酸水解皂产物以形成脂肪酸 - 水乳液和这些乳液的断裂的新方法。 优选的实施方案使用富含亚油酸的植物油,例如向日葵或红花油,氢氧化钾,磷酸中和皂,以及可包括乙醇或其它一元醇的破乳化合物,单宁(可水解或缩合的单宁) 或聚乙二醇。 该反应形成共轭亚油酸的位置和几何异构体,优选的异构体混合物通过搅拌,精确控制加热和快速引发和终止反应的组合来控制。 反应产物组合物可以通过结晶富集。
    • 6. 发明申请
    • RECOVERY OF MULTIPLE COMPOUNDS AND RECYCLABLE WATER FROM THIN STILLAGE
    • 多种化合物的回收和可再循环的水从轻微的沉淀
    • US20110130586A1
    • 2011-06-02
    • US12995660
    • 2009-06-02
    • Martin J. ReaneyYunhua JiaJianheng ShenKomsulee Ratanaparlyanuch
    • Martin J. ReaneyYunhua JiaJianheng ShenKomsulee Ratanaparlyanuch
    • C07F9/09C07C211/27
    • C12F3/10A23K10/38Y02P60/873
    • Methods for recovery of recyclable water and/or fermentation co-products from thin stillage process streams. Microbial metabolites and/or plant derivatives and/or plant extractives are removed from thin stillage after which, recyclable water is recovered from the processed thin stillage. Thin stillage is commingled with one or more polar organic solvents to react microbial metabolites and/or plant derivatives and/or plant extractives with the organic solvents. The reacted organic solvents are then separated from the processed thin stillage. Thin stillage may be commingled with an oil to re act with certain organic compounds, after which, the reacted oil is separated from the processed thin stillage is further extracted with one or more polar organic solvents. Alternatively, thin stillage may be first processed with one or more polar organic solvents, and then processed with an oil. Useful organic compounds may recovered from the reacted oil and from the reacted organic solvents.
    • 从稀酒糟过程流中回收可再循环水和/或发酵副产物的方法。 从稀浆中除去微生物代谢物和/或植物衍生物和/或植物提取物,之后从经处理的薄釜中回收可再循环水。 与一种或多种极性有机溶剂混合使稀薄的釜渣与有机溶剂反应微生物代谢物和/或植物衍生物和/或植物提取物。 然后将反应的有机溶剂从处理的薄釜中分离。 稀浆可以与油混合以与某些有机化合物反应,之后将反应后的油与加工的薄釜分离,进一步用一种或多种极性有机溶剂萃取。 或者,可以用一种或多种极性有机溶剂首先处理薄的釜渣,然后用油处理。 有用的有机化合物可以从反应的油和反应的有机溶剂中回收。
    • 8. 发明授权
    • Recovery of multiple compounds and recyclable water from thin stillage
    • 从稀酒糟中回收多种化合物和可回收的水
    • US08835665B2
    • 2014-09-16
    • US12995660
    • 2009-06-02
    • Martin J. ReaneyYunhua JiaJianheng ShenKomsulee Ratanapariyanuch
    • Martin J. ReaneyYunhua JiaJianheng ShenKomsulee Ratanapariyanuch
    • C07F9/09C07C211/27A23K1/06C12F3/10
    • C12F3/10A23K10/38Y02P60/873
    • Methods for recovery of recyclable water and/or fermentation co-products from thin stillage process streams. Microbial metabolites plant derivatives and/or plant extractives are removed from thin stillage after which water is recovered and recycled. Thin stillage is commingled with polar organic solvents or with oil to react microbial metabolites, plant derivatives and/or plant extractives. The reacted organic solvents are then separated from the processed thin stillage. Thin stillage may be commingled with an oil to re act with certain organic compounds, after which, the reacted oil is separated from the processed thin stillage is further extracted with one or more polar organic solvents. Alternatively, thin stillage may be first processed with one or more polar organic solvents, and then processed with an oil. Useful organic compounds may be recovered from the reacted oil and reacted organic solvents.
    • 从稀酒糟过程流中回收可再循环水和/或发酵副产物的方法。 微生物代谢物植物衍生物和/或植物提取物从薄的釜中除去,之后回收和回收水。 稀碱化物与极性有机溶剂或油混合以反应微生物代谢物,植物衍生物和/或植物提取物。 然后将反应的有机溶剂从处理的薄釜中分离。 稀浆可以与油混合以与某些有机化合物反应,之后将反应后的油与加工的薄釜分离,进一步用一种或多种极性有机溶剂萃取。 或者,可以用一种或多种极性有机溶剂首先处理薄的釜渣,然后用油处理。 可以从反应的油和反应的有机溶剂中回收有用的有机化合物。