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    • 2. 发明申请
    • LITHIUM AIR BATTERY CELL
    • 锂离子电池
    • US20140045078A1
    • 2014-02-13
    • US14113436
    • 2012-04-19
    • Johannes EicherJens OlschimkeMartin BomkampPlacido Garcia-Juan
    • Johannes EicherJens OlschimkeMartin BomkampPlacido Garcia-Juan
    • H01M8/22
    • H01M8/22H01M10/052H01M10/0567H01M10/0568H01M10/0569H01M12/08H01M2220/20H01M2300/0028H01M2300/0034Y02E60/122Y02E60/128Y02T10/7011
    • A lithium-air battery cell with an electrolyte composition comprising LiPO2F2 is described. The electrolyte composition comprises an electrolyte solvent, for example, one or more non-fluorinated solvents, e.g. ethylene carbonate, a dialkyl carbonate or propylene carbonate, and/or one or more fluorinated organic solvents, e.g. fluoroethylene carbonate, cis-difluoroethylene carbonate, trans-difluoroethylene carbonate, 4,4-di-fluoroethylene carbonate, trifluoroethylene carbonate, tetrafluoroethylene carbonate, 4-fluoro-4-methyl-1,3-dioxolane-2-one, 4-fluoro-4-ethyl-1,3-dioxolane-2-one, 2,2,2-tri-fluoroethyl-methyl carbonate, 2,2,2-trifluoroethyl-fluoromethyl carbonate are preferred. The solvent may further comprise other additives. Also described is a vehicle battery, especially a car battery constituted of a multitude of lithium-air battery cells of the invention. The battery can be used to provide electrical energy to consumers for electric current including an electric motor driving the vehicle.
    • 描述了具有包含LiPO2F2的电解质组成的锂空气电池单体。 电解质组合物包含电解质溶剂,例如一种或多种非氟化溶剂,例如, 碳酸亚乙酯,碳酸二烷基酯或碳酸亚丙酯,和/或一种或多种氟化有机溶剂,例如, 氟代亚乙基碳酸酯,顺式二氟亚乙基碳酸酯,反式二氟亚乙基碳酸酯,4,4-二氟亚乙基碳酸酯,三氟乙烯碳酸酯,四氟乙烯碳酸酯,4-氟-4-甲基-1,3-二氧戊环-2-酮, 4-乙基-1,3-二氧戊环-2-酮,2,2,2-三氟乙基甲基碳酸酯,2,2,2-三氟乙基 - 氟甲基碳酸酯。 溶剂可以进一步包含其它添加剂。 还描述了一种车辆电池,特别是由本发明的多个锂空气电池单元构成的汽车电池。 电池可以用于为消费者提供电能,包括驱动车辆的电动机的电流。
    • 8. 发明申请
    • Lithium sulfur battery
    • 锂硫电池
    • US20120214043A1
    • 2012-08-23
    • US13504094
    • 2010-10-26
    • Jens OlschimkeMartin BomkampJohannes Eicher
    • Jens OlschimkeMartin BomkampJohannes Eicher
    • H01M2/16H01M10/056C07C69/96
    • H01M12/08H01M4/134H01M4/38H01M4/381H01M4/382H01M10/05H01M10/052H01M10/0568H01M10/0569H01M2300/0025H01M2300/0068Y02E60/128Y02T10/7011
    • A lithium sulfur battery comprising an electrolyte solvent which comprises at least one fluorosubstituted compound is described. Preferred fluorosubstituted compounds which are predominantly solvents are notably selected from the group consisting of fluorosubstituted carboxylic acid esters, fluorosubstituted carboxylic acid amides, fluorosubstituted fluorinated ethers, fluorosubstituted carbamates, fluorosubstituted cyclic carbonates, fluorosubstituted acyclic carbonates, fluorosubstituted ethers, perfluoroalkyl phosphoranes, fluorosubstituted phosphites, fluorosubstituted phosphates, fluorosubstituted phosphonates, and fluorosubstituted heterocycles. Monofluoroethylene carbonate, cis-difluoroethylene carbonate, trans-difluoroethylene carbonate, 4,4-difluoroethylene carbonate, trifluoroethylene carbonate, tetrafluoroethylene carbonate, 4-fluoro-4-methyl-1,3-dioxolane-2-one, 4-fluoro-4-ethyl-1,3-dioxolane-2-one, 2,2,2-trifluoroethyl-methyl carbonate, 2,2,2-trifluoroethyl-fluoromethyl carbonate are preferred. The solvent may further comprise a non-fluorinated solvent, e.g., ethylene carbonate, a dialkyl carbonate, or propylene carbonate. Use of such fluorinated compound as additive for such batteries and specific electrolyte solutions.
    • 描述了包含至少一种氟取代化合物的电解质溶剂的锂硫电池。 主要是溶剂的优选氟取代的化合物特别选自氟取代的羧酸酯,氟取代的羧酸酰胺,氟取代的氟代醚,氟代取代的氨基甲酸酯,氟取代的环状碳酸酯,氟取代的无环碳酸酯,氟取代的醚,全氟烷基磷,氟取代的亚磷酸酯,氟取代的 磷酸酯,氟取代的膦酸酯和氟取代的杂环。 单氟代碳酸亚乙酯,顺式二氟亚乙基碳酸酯,反式二氟亚乙基碳酸酯,4,4-二氟亚乙基碳酸酯,三氟乙烯碳酸酯,四氟乙烯碳酸酯,4-氟-4-甲基-1,3-二氧戊环-2-酮,4-氟-4- 乙基-1,3-二氧戊环-2-酮,2,2,2-三氟乙基 - 甲基碳酸酯,2,2,2-三氟乙基 - 氟甲基碳酸酯。 溶剂还可以包含非氟化溶剂,例如碳酸亚乙酯,碳酸二烷基酯或碳酸亚丙酯。 使用这种氟化合物作为这种电池和特定电解质溶液的添加剂。